Volume 48
Main Index

Issue 1

Influence of a Pendant Amine in the Second Coordination Sphere on Proton Transfer at a Dissymmetrically Disubstituted Diiron System Related to the [2Fe]H Subsite of [FeFe]H2ase Salah Ezzaher, Jean-Franois Capon, Frdric Gloaguen, Franois Y. Ptillon, Philippe Schollhammer and Jean Talarmin, Nelly Kervarec pp 2–4 DOI: 10.1021/ic801369u Supporting Info

Base-Mediated Conversion of Hydrazine to Diazene and Dinitrogen at an Iron Center Leslie D. Field, Hsiu L. Li and Alison M. Magill pp 5–7 DOI: 10.1021/ic801856q Supporting Info

Pentaarylfullerenes as Noncoordinating Cyclopentadienyl Anions Marco W. Bouwkamp and Auke Meetsma pp 8–9 DOI: 10.1021/ic802034m Supporting Info

Construction of a Three-Dimensional Polynuclear Zinc Compound Based on Unique Metallophthalocyanine-like Subunits Kui-Zhan Shao, Ya-Hui Zhao, Xin-Long Wang, Ya-Qian Lan, De-Jun Wang, Zhong-Min Su and Rong-Shun Wang pp 10–12 DOI: 10.1021/ic801439q Supporting Info

Heteroleptic Dipyrrin/Bipyridine Complexes of Ruthenium(II) Serena J. Smalley, Mark R. Waterland and Shane G. Telfer pp 13–15 DOI: 10.1021/ic8016497 Supporting Info

Strong Coordination of Tetraphenylborate Anion to Copper(I) Bipyridine and Phenanthroline-Based Complexes and Its Effect on Catalytic Activity in the Cyclopropanation of Styrene Carolynne Ricardo, Lauren M. Matosziuk, Jeffrey D. Evanseck and Tomislav Pintauer pp 16–18 DOI: 10.1021/ic801783r Supporting Info

Linker-Dependent Metal-Sensitized Photoswitching of Dithienylethenes Matthew N. Roberts, Jeffrey K. Nagle, Jeremy G. Finden, Neil R. Branda and Michael O. Wolf pp 19–21 DOI: 10.1021/ic801619v Supporting Info

Photoswitchable Heterotrimetallic Chain Based on Octacyanomolybdate, Copper, and Nickel: Synthesis, Characterization, and Photomagnetic Properties Jrme Long, Lise-Marie Chamoreau, Corine Mathonire and Valrie Marvaud pp 22–24 DOI: 10.1021/ic801901j Supporting Info

Oxotechnetium(V) Complexes with a Novel Class of Tridentate Thiosemicarbazide Ligands Hung Huy Nguyen, Pedro I. da S. Maia, Victor M. Deflon and Ulrich Abram pp 25–27 DOI: 10.1021/ic802044r Supporting Info

Identification of the Reactive cis,mer Isomer of [Ir(CO)2I3Me]−: Relation to the Mechanism of Iridium-Catalyzed Methanol Carbonylation Anthony Haynes, Anthony J. H. M. Meijer, James R. Lyons and Harry Adams pp 28–35 DOI: 10.1021/ic8017858 Supporting Info

Molecular Construction, Characterization, and Photophysical Properties of Supramolecular Lanthanide−Calix[4]arene Covalently Bonded Hybrid Systems Bing Yan, Qian-Ming Wang and Dong-Jie Ma pp 36–44 DOI: 10.1021/ic8004954 Supporting Info

Design, Synthesis, Characterization, and OFET Properties of Amphiphilic Heteroleptic Tris(phthalocyaninato) Europium(III) Complexes. The Effect of Crown Ether Hydrophilic Substituents Yingning Gao, Pan Ma, Yanli Chen, Ying Zhang, Yongzhong Bian, Xiyou Li, Jianzhuang Jiang and Changqin Ma pp 45–54 DOI: 10.1021/ic801040z Supporting Info

Magnetic Frustration and Spin Disorder in Isostructural M(μ-OH2)2[Au(CN)2]2 (M = Mn, Fe, Co) Coordination Polymers Containing Double Aqua-Bridged Chains: SQUID and μSR Studies Julie Lefebvre, Pooja Tyagi, Simon Trudel, Vighen Pacradouni, Christina Kaiser, Jeff E. Sonier and Daniel B. Leznoff pp 55–67 DOI: 10.1021/ic801094m Supporting Info

Ruthenium(II) Complexes Incorporating 2-(2′-Pyridyl)pyrimidine-4-carboxylic Acid Nickita Nickita, Gilles Gasser, Pauline Pearson, Matthew J. Belousoff, Lai Y. Goh, Alan M. Bond, Glen B. Deacon and Leone Spiccia pp 68–81 DOI: 10.1021/ic800972x Supporting Info

A Cobalt(II) Hexafluoroacetylacetonate Ethylenediamine Complex As a CVD Molecular Source of Cobalt Oxide Nanostructures Giuliano Bandoli, Davide Barreca, Alberto Gasparotto, Chiara Maccato, Roberta Seraglia, Eugenio Tondello, Anjana Devi, Roland A. Fischer and Manuela Winter pp 82–89 DOI: 10.1021/ic801212v Supporting Info

Synthesis and Coordination Properties of Chelating Dithiophenolate Ligands Joachim Ballmann, Michael G. G. Fuchs, Sebastian Dechert, Michael John and Franc Meyer pp 90–99 DOI: 10.1021/ic801285u Supporting Info

Assemblies of Copper Bis(triazole) Coordination Polymers Using the Same Keggin Polyoxometalate Template Ai-xiang Tian, Jun Ying, Jun Peng, Jing-quan Sha, Hai-jun Pang, Peng-peng Zhang, Yuan Chen, Min Zhu and Zhong-min Su pp 100–110 DOI: 10.1021/ic801338b Supporting Info

Structural Consequences of Anionic Host−Cationic Guest Interactions in a Supramolecular Assembly Michael D. Pluth, Darren W. Johnson, Gza Szigethy, Anna V. Davis, Simon J. Teat, Allen G. Oliver, Robert G. Bergman and Kenneth N. Raymond pp 111–120 DOI: 10.1021/ic8012848 Supporting Info

Synthesis and Application of DNA−CdS Nanowires within a Minute using Microwave Irradiation Subrata Kundu, Hyungoo Lee and Hong Liang pp 121–127 DOI: 10.1021/ic801791u Supporting Info

Single-Ion Anisotropy and Exchange Interactions in the Cyano-Bridged Trimers MnIII2MIII(CN)6 (MIII = Co, Cr, Fe) Species Incorporating [Mn(5-Brsalen)]+ Units: An Inelastic Neutron Scattering and Magnetic Susceptibility Study Philip L. W. Tregenna-Piggott, Denis Sheptyakov, Lukas Keller, Sophia I. Klokishner, Sergei M. Ostrovsky, Andrei V. Palii, Oleg S. Reu, Jesper Bendix, Theis Brock-Nannestad, Kasper Pedersen, Høgni Weihe and Hannu Mutka pp 128–137 DOI: 10.1021/ic801727p Supporting Info

Structure and Magnetism of [n-BuNH3]12[Cu4(GeW9O34)2]·14H2O Sandwiching a Rhomblike Cu48+ Tetragon through α-Keggin Linkage Toshihiro Yamase, Hiroko Abe, Eri Ishikawa, Hiroyuki Nojiri and Yuhgo Ohshima pp 138–148 DOI: 10.1021/ic8013267 Supporting Info

Stable and Highly Persistent Quinoxaline-Centered Metalloorganic Radical Anions: Preparation, Structural, Spectroscopic, and Computational Investigations Sylvie Choua, Jean-Pierre Djukic, Jrme Dallry, Andr Bieber, Richard Welter, Jean-Paul Gisselbrecht, Philippe Turek and Louis Ricard pp 149–163 DOI: 10.1021/ic801434h Supporting Info

Synthesis and Spectroscopic and Electrochemical Studies of Pyrazine- or Pyridine-Ring-Fused Tetraazachlorins, Bacteriochlorins, and Isobacteriochlorins Elena A. Makarova, Ekaterina V. Dzyuina, Takamitsu Fukuda, Hironori Kaneko, Naoaki Hashimoto, Yuu Kikukawa, Nagao Kobayashi and Evgeny A. Lukyanets pp 164–173 DOI: 10.1021/ic801552u Supporting Info

Photoluminescence of 1-D Copper(I) Cyanide Chains: A Theoretical Description Craig A. Bayse, Timothy P. Brewster and Robert D. Pike pp 174–182 DOI: 10.1021/ic801509t Supporting Info

Di-, Tri-, Tetra-, and Hexanuclear Copper(II) Mono-organophosphates: Structure and Nuclearity Dependence on the Choice of Phosphorus Substituents and Auxiliary N-Donor Ligands Ramaswamy Murugavel, Subramaniam Kuppuswamy, Amarendra Nath Maity and Mayank Pratap Singh pp 183–192 DOI: 10.1021/ic801532y Supporting Info

Facile Access of Stable Divalent Tin Compounds with Terminal Methyl, Amide, Fluoride, and Iodide Substituents Anukul Jana, Herbert W. Roesky, Carola Schulzke, Alexander Dring, Tobias Beck, Aritra Pal and Regine Herbst-Irmer pp 193–197 DOI: 10.1021/ic8015639 Supporting Info

Syntheses and Characterizations of Transition-Metal-Substituted Aluminophosphate Molecular Sieves |(C3N2H5)8|[M8Al16P24O96] (M = Co, Mn, Zn) with Zeotype LAU Topology Xiaowei Song, Jiyang Li, Yanan Guo, Qinhe Pan, Lin Gan, Jihong Yu and Ruren Xu pp 198–203 DOI: 10.1021/ic801405e Supporting Info

New A2/3−xRh2O4 Compounds with the CaFe2O4 Structure Where A Is a Rare Earth or Bi Hiroshi Mizoguchi, L. N. Zakharov, A. P. Ramirez, W. J. Marshall, A. W. Sleight and M. A. Subramanian pp 204–208 DOI: 10.1021/ic801603t Supporting Info

Investigation of the [Cp*Mo(PMe3)3H]n+ (n = 0, 1) Redox Pair: Dynamic Processes on Very Different Time Scales Miguel Baya, Pavel A. Dub, Jennifer Houghton, Jean-Claude Daran, Natalia V. Belkova, Elena S. Shubina, Lina M. Epstein, Agust Lleds and Rinaldo Poli pp 209–220 DOI: 10.1021/ic801676n Supporting Info

Lanthanide(III) and Actinide(III) Complexes [M(BH4)2(THF)5][BPh4] and [M(BH4)2(18-crown-6)][BPh4] (M = Nd, Ce, U): Synthesis, Crystal Structure, and Density Functional Theory Investigation of the Covalent Contribution to Metal-Borohydride Bonding Thrse Arliguie, Lotfi Belkhiri, Salah-Eddine Bouaoud, Pierre Thury, Claude Villiers, Abdou Boucekkine and Michel Ephritikhine pp 221–230 DOI: 10.1021/ic801685v Supporting Info

Flash and Continuous Photolysis Studies of the Thionitrosyl Complex Cr(CH3CN)5(NS)2+ and the Nitric Oxide Analogs: Reactions of Nitrogen Monosulfide in Solution Johannes W. Dethlefsen, Erik D. Hedegrd, R. Dale Rimmer, Peter C. Ford and Anders Døssing pp 231–238 DOI: 10.1021/ic8016936 Supporting Info

Reactions of Tertiary Phosphines with Alcohols in Aqueous Media Dmitry V. Moiseev, Brian O. Patrick and Brian R. James pp 239–245 DOI: 10.1021/ic801657g Supporting Info

Comparison of Two Tetrapodal N,O Ligands: Impact of the Softness of the Heterocyclic N-Donors Pyridine and Pyrazine on the Selectivity for Am(III) over Eu(III) Marie Heitzmann, Florence Bravard, Christelle Gateau, Nathalie Boubals, Claude Berthon, Jacques Pcaut, Marie-Christine Charbonnel and Pascale Delangle pp 246–256 DOI: 10.1021/ic8017024 Supporting Info

Facile Conversion of Layered Ruddlesden−Popper-Related Structure Y2O3-Doped Sr2CeO4 into Fast Oxide Ion-Conducting Fluorite-Type Y2O3-Doped CeO2 Ryan Georg Gerlach, Surinderjit Singh Bhella and Venkataraman Thangadurai pp 257–266 DOI: 10.1021/ic801729x

On the Nature of the Reversibility of HydrationDehydration on the Crystal Structure and Magnetism of the Ferrimagnet [MnII(enH)(H2O)][CrIII(CN)6]·H2O Yusuke Yoshida, Katsuya Inoue and Mohamedally Kurmoo pp 267–276 DOI: 10.1021/ic801734x Supporting Info

1,2-Hydroxypyridonate/Terephthalamide Complexes of Gadolinium(III): Synthesis, Stability, Relaxivity, and Water Exchange Properties Eric J. Werner, Julia Kozhukh, Mauro Botta, Evan G. Moore, Stefano Avedano, Silvio Aime and Kenneth N. Raymond pp 277–286 DOI: 10.1021/ic801730u Supporting Info

Guest Inclusion and Interpenetration Tuning of Cd(II)/Mn(II) Coordination Grid Networks Assembled from a Rigid Linear Diimidazole Schiff Base Ligand Qing Wang, Jianyong Zhang, Chun-Feng Zhuang, Yu Tang and Cheng-Yong Su pp 287–295 DOI: 10.1021/ic801770n Supporting Info

Accessing Postsynthetic Modification in a Series of Metal-Organic Frameworks and the Influence of Framework Topology on Reactivity Zhenqiang Wang, Kristine K. Tanabe and Seth M. Cohen pp 296–306 DOI: 10.1021/ic801837t Supporting Info

Radical Formation in the [MeReO3]-Catalyzed Aqueous Peroxidative Oxidation of Alkanes: A Theoretical Mechanistic Study Maxim L. Kuznetsov and Armando J. L. Pombeiro pp 307–318 DOI: 10.1021/ic801753t Supporting Info

A Synthetically Simple, Click-Generated Cyclam-Based Zinc(II) Sensor Emiliano Tamanini, Arna Katewa, Lisa M. Sedger, Matthew H. Todd and Michael Watkinson pp 319–324 DOI: 10.1021/ic8017634 Supporting Info

Syntheses and Structures of Alkaline Earth−Transition Metal Bimetallic Complexes As Heterogeneous Hydrodechlorination Catalyst Precursors Errun Ding, Matthew R. Sturgeon, Aaron Rath, Xuenian Chen, Mark A. Keane and Sheldon G. Shore pp 325–330 DOI: 10.1021/ic801912x Supporting Info

Stability of the Heme Fe−N-Terminal Amino Group Coordination Bond in Denatured Cytochrome c Hulin Tai, Toratane Munegumi and Yasuhiko Yamamoto pp 331–338 DOI: 10.1021/ic801202d Supporting Info

Anaerobic Photocleavage of DNA in Red Light by Dicopper(II) Complexes of 3,3′-Dithiodipropionic Acid Debojyoti Lahiri, Tuhin Bhowmick, Biswarup Pathak, Oottikkal Shameema, Ashis K. Patra, Suryanarayanarao Ramakumar and Akhil R. Chakravarty pp 339–349 DOI: 10.1021/ic800806j Supporting Info

Crystal Structures and Vibrational Spectroscopy of Copper(I) Thiourea Complexes Graham A. Bowmaker, John V. Hanna, Chaveng Pakawatchai, Brian W. Skelton, Yupa Thanyasirikul and Allan H. White pp 350–368 DOI: 10.1021/ic801310r

Preparation and Solid State Structures of Tetra(amino)silane Organolithium Compounds Containing a Li8 Core Forming a Johnson Solid J26 and a Li4 Core Tina Maria Konrad, Katrin R. Grnwald, Ferdinand Belaj and Nadia C. Msch-Zanetti pp 369–374 DOI: 10.1021/ic801493b

Ru(II) Complexes of New Tridentate Ligands: Unexpected High Yield of Sensitized 1O2 Yao Liu, Richard Hammitt, Daniel A. Lutterman, Lauren E. Joyce, Randolph P. Thummel and Claudia Turro pp 375–385 DOI: 10.1021/ic801636u Supporting Info

Stereoselective Hydrogenation of Aromatic Alkynes Using Water, Triethylsilane, or Methanol, Mediated and Catalyzed by Ni(0) Complexes Rigoberto Barrios-Francisco and Juventino J. Garca pp 386–393 DOI: 10.1021/ic801823x Supporting Info

Alkyl-Substituted Amides as Ligands in Homometallic and Heterobimetallic Calcium Complexes Carsten Glock, Helmar Grls and Matthias Westerhausen pp 394–399 DOI: 10.1021/ic801857m Supporting Info

Kinetics and Mechanism of the Oxidation of Ascorbic Acid in Aqueous Solutions by a trans-Dioxoruthenium(VI) Complex Yi-Ning Wang, Kai-Chung Lau, William W. Y. Lam, Wai-Lun Man, Chi-Fai Leung and Tai-Chu Lau pp 400–406 DOI: 10.1021/ic8015904 Supporting Info

Issue 2

Metallohelical Triangles for Selective Detection of Adenosine Triphosphate in Aqueous Media Hongmei Wu, Cheng He, Zhihua Lin, Yang Liu and Chunying Duan pp 408–410 DOI: 10.1021/ic801350h Supporting Info

Organoantimony-Containing Polyoxometalate: [{PhSbOH}3(A-α-PW9O34)2]9− Luis F. Piedra-Garza, Michael H. Dickman, Ovidiu Moldovan, Hans Joachim Breunig and Ulrich Kortz pp 411–413 DOI: 10.1021/ic8021694 Supporting Info

Crystal Growth of Novel Lanthanide-Containing Platinates K4[Ln6Pt2O15] (Ln = La, Pr, Nd, Sm) with a Unique Framework Structure Hans-Conrad zur Loye, Tara J. Hansen, Qingbiao Zhao, Samuel J. Mugavero, III, Ray L. Withers and Mark D. Smith pp 414–416 DOI: 10.1021/ic801789e Supporting Info

Targeted Synthesis of a Prototype MOF Based on Zn4(O)(O2C)6 Units and a Nonlinear Dicarboxylate Ligand Hyungphil Chun and Heejin Jung pp 417–419 DOI: 10.1021/ic801906e Supporting Info

A Novel Supramolecular Tetrahedron Assembled from Tetranuclear Copper(I) Cluster Molecules via Aryl Embrace Interactions Wei Wei, Mingyan Wu, Qiang Gao, Qingfu Zhang, Yougui Huang, Feilong Jiang and Maochun Hong pp 420–422 DOI: 10.1021/ic801972e Supporting Info

Gold(I) Chloride Coordinated 3-Hexyne Jiang Wu, Peter Kroll and H. V. Rasika Dias pp 423–425 DOI: 10.1021/ic8020854 Supporting Info

Pillared Porphyrin Homologous Series: Intergrowth in Metal−Organic Frameworks Eun-Young Choi, Paul M. Barron, Richard W. Novotny, Hyun-Tak Son, Chunhua Hu and Wonyoung Choe pp 426–428 DOI: 10.1021/ic801677y Supporting Info

Initial Use of Dioximate Ligands in 3d/4f Cluster Chemistry: Synthesis, Structure, and Magnetic Studies of an Unusual [GdIII2MnIVO]8+ Complex Christos Lampropoulos, Theocharis C. Stamatatos, Khalil A. Abboud and George Christou pp 429–431 DOI: 10.1021/ic802005a Supporting Info

Synthesis and Characterization of Transition Metal Complexes of Dimeric N-Confused Porphyrin Linked by an o-Xylene Fragment Piotr J. Chmielewski pp 432–445 DOI: 10.1021/ic800591n Supporting Info

Conjugated Organometallic Polymer Containing a Redox-Active Center Daniel Fortin, Sbastien Clment, Karl Gagnon, Jean-Franois Brub, Michael P. Stewart, William E. Geiger and Pierre D. Harvey pp 446–454 DOI: 10.1021/ic800857v Supporting Info

Pyridine-N-oxide Analogues of DOTA and Their Gadolinium(III) Complexes Endowed with a Fast Water Exchange on the Square-Antiprismatic Isomer Miloslav Polek, Miroslava edinov, Jan Kotek, Luce Vander Elst, Robert N. Muller, Petr Hermann and Ivan Luke pp 455–465 DOI: 10.1021/ic801596v Supporting Info

Lanthanide(III) Complexes of Pyridine-N-Oxide Analogues of DOTA in Solution and in the Solid State. A New Kind of Isomerism in Complexes of DOTA-like Ligands Miloslav Polek, Jan Kotek, Petr Hermann, Ivana Csaov, Koen Binnemans and Ivan Luke pp 466–475 DOI: 10.1021/ic801597z Supporting Info

Aqueous V(V)-Peroxo-Amino Acid Chemistry. Synthesis, Structural and Spectroscopic Characterization of Unusual Ternary Dinuclear Tetraperoxo Vanadium(V)-Glycine Complexes C. Gabriel, M. Kaliva, J. Venetis, P. Baran, I. Rodriguez-Escudero, G. Voyiatzis, M. Zervou and A. Salifoglou pp 476–487 DOI: 10.1021/ic801427b Supporting Info

Manganese Catalysts with Molecular Recognition Functionality for Selective Alkene Epoxidation Jonathan F. Hull, Effiette L. O. Sauer, Christopher D. Incarvito, J. W. Faller, Gary W. Brudvig and Robert H. Crabtree pp 488–495 DOI: 10.1021/ic8013464 Supporting Info

Discrete Polyoxovanadate Cluster into an Organic Free Metal-Oxide-Based Material: Syntheses, Crystal Structures, and Magnetic Properties of a New Series of Lanthanide Linked-POV Compounds [{Ln(H2O)6}2As8V14O42(SO3)]·8H2O (Ln = La3+, Sm3+, and Ce3+) T. Arumuganathan and Samar K. Das pp 496–507 DOI: 10.1021/ic8002383 Supporting Info

Effects of ZSM-5 Zeolite Confinement on Reaction Intermediates during Dioxygen Activation by Enclosed Dicopper Cations Takashi Yumura, Mina Takeuchi, Hisayoshi Kobayashi and Yasushige Kuroda pp 508–517 DOI: 10.1021/ic8010184 Supporting Info

Very Fast Single-Step Photoinduced Charge Separation in Zinc Porphyrin Bridged to a Gold Porphyrin by a Bisethynyl Quaterthiophene Jrme Fortage, Julien Boixel, Errol Blart, Hans Christian Becker and Fabrice Odobel pp 518–526 DOI: 10.1021/ic800727e Supporting Info

Generation of Ferryl Species through Dioxygen Activation in Iron/EDTA Systems: A Computational Study Leonardo Bernasconi and Evert Jan Baerends pp 527–540 DOI: 10.1021/ic800998n

Quantum Chemical Studies on High-Valent Metal Nitrido Derivatives of Keggin-Type Polyoxometalates ([PW11O39{MVIN}]4− (M = Ru, Os, Re)): MVI−N Bonding and Electronic Structures Chun-Guang Liu, Zhong-Min Su, Wei Guan and Li-Kai Yan pp 541–548 DOI: 10.1021/ic8012443 Supporting Info

Design, Synthesis, and Characterizations of a Series of Pt4 Macrocycles and Fluorescent Sensing of Fe3+/Cu2+/Ni2+ Through Metal Coordination Sushobhan Ghosh, Rajesh Chakrabarty and Partha Sarathi Mukherjee pp 549–556 DOI: 10.1021/ic801381p Supporting Info

Luminescent and Structural Properties of (Sr1−x,Bax)3MgSi2O8:Eu2+: Effects of Ba Content on the Eu2+ Site Preference for Thermal Stability Won Bin Im, Yong-Il Kim, Hyoung Sun Yoo and Duk Young Jeon pp 557–564 DOI: 10.1021/ic8012798

All-trans-[ClRuII(py)4(NC)RuII(py)4(CN)RuII(py)4(NO)](PF6)4: A Redox-Active 2-Donor/1-Acceptor System Based on the Electrophilic {RuNO}6 Motif Ariel G. De Candia, Priti Singh, Wolfgang Kaim and Leonardo D. Slep pp 565–573 DOI: 10.1021/ic801347d Supporting Info

Kinetics of Coloration in Photochromic Organoammonium Polyoxomolybdates Rmi Dessapt, Mathieu Collet, Violaine Cou, Martine Bujoli-Doeuff, Stphane Jobic, Changhoon Lee and Myung-Hwan Whangbo pp 574–580 DOI: 10.1021/ic8013865 Supporting Info

Structural Stability and Elastic and Electronic Properties of Rhenium Borides: First Principle Investigations Huiyang Gou, Zhibin Wang, Jingwu Zhang, Shuting Yan and Faming Gao pp 581–587 DOI: 10.1021/ic8019606

Fast Substitution Reactions of Pt(II) in Different Ionic Liquids. Reactivity Control by Anionic Components Peter Illner, Svetlana Begel, Simon Kern, Ralph Puchta and Rudi van Eldik pp 588–597 DOI: 10.1021/ic801561x Supporting Info

Gas-Phase Fragmentation of Polyoxotungstate Anions Michelle T. Ma, Tom Waters, Karin Beyer, Rosemary Palamarczuk, Peter J. S. Richardt, Richard A. J. O’Hair and Anthony G. Wedd pp 598–606 DOI: 10.1021/ic8016326 Supporting Info

Exchange Interactions and Zero-Field Splittings in C3-Symmetric MnIII6FeIII: Using Molecular Recognition for the Construction of a Series of High Spin Complexes Based on the Triplesalen Ligand Thorsten Glaser, Maik Heidemeier, Erich Krickemeyer, Hartmut Bgge, Anja Stammler, Roland Frhlich, Eckhard Bill and Jrgen Schnack pp 607–620 DOI: 10.1021/ic8016529 Supporting Info

A Series of Mononuclear Quasi-Two-Coordinate Copper(I) Complexes Employing a Sterically Demanding Thiolate Ligand Stanislav Groysman and R. H. Holm pp 621–627 DOI: 10.1021/ic801836k Supporting Info

Syntheses and Crystal Structures of Novel Manganese(II) or Cadmium(II) Arsonates with Dinuclear Clusters or 1D Arrays Fei-Yan Yi, Na Zhao, Wei Wu and Jiang-Gao Mao pp 628–637 DOI: 10.1021/ic8016535 Supporting Info

Redox Activation of Alkene Ligands in Platinum Complexes with Non-innocent Ligands Julie L. Boyer, Thomas R. Cundari, Nathan J. DeYonker, Thomas B. Rauchfuss and Scott R. Wilson pp 638–645 DOI: 10.1021/ic8017248 Supporting Info

Tetra- and Decanuclear Iron(III) Phosphonates: Observance of a Rare P−C Bond Cleavage in a Homogeneous Medium Ramaswamy Murugavel, Nayanmoni Gogoi and Rodolphe Clrac pp 646–651 DOI: 10.1021/ic8017562 Supporting Info

Transformations and Reactions of Re2(CO)8(μ-SbPh2)(μ-H) Induced by the Addition of a Platinum(tri-t-butylphosphine) Group Richard D. Adams, Michael B. Hall, William C. Pearl, Jr. and Xinzheng Yang pp 652–662 DOI: 10.1021/ic801876s Supporting Info

Para-Hydrogen Induced Polarization without Incorporation of Para-Hydrogen into the Analyte Kevin D. Atkinson, Michael J. Cowley, Simon B. Duckett, Paul I. P. Elliott, Gary G. R. Green, Joaqun Lpez-Serrano, Iman G. Khazal and Adrian C. Whitwood pp 663–670 DOI: 10.1021/ic8020029 Supporting Info

Tunneling Barrier Effects on Photoinduced Charge Transfer through Covalent Rigid Rod-Like Bridges David Hanss and Oliver S. Wenger pp 671–680 DOI: 10.1021/ic801841k

Template-Based Fabrication of SrTiO3 and BaTiO3 Nanotubes Ying-Yu Chen, Bang-Ying Yu, Jung-Hui Wang, Rebecca E. Cochran and Jing-Jong Shyue pp 681–686 DOI: 10.1021/ic8018887

Predicting Efficient Antenna Ligands for Tb(III) Emission Amanda P. S. Samuel, Jide Xu and Kenneth N. Raymond pp 687–698 DOI: 10.1021/ic801904s Supporting Info

Preparation and Magnetic Properties of Iron(3+) Spin-Crossover Complexes Bearing a Thiophene Substituent: Toward Multifunctional Metallopolymers Brandon Djukic, Paul A. Dube, Fereidoon Razavi, Takele Seda, Hilary A. Jenkins, James F. Britten and Martin T. Lemaire pp 699–707 DOI: 10.1021/ic801233x Supporting Info

Luminescent Cyclometalated Iridium(III) Polypyridine Indole ComplexesSynthesis, Photophysics, Electrochemistry, Protein-Binding Properties, Cytotoxicity, and Cellular Uptake Jason Shing-Yip Lau, Pui-Kei Lee, Keith Hing-Kit Tsang, Cyrus Ho-Cheong Ng, Yun-Wah Lam, Shuk-Han Cheng and Kenneth Kam-Wing Lo pp 708–718 DOI: 10.1021/ic801818x

Correlation of Relaxivity with Coordination Number in Six-, Seven-, and Eight-Coordinate Mn(II) Complexes of Pendant-Arm Cyclen Derivatives Sen Wang and T. David Westmoreland pp 719–727 DOI: 10.1021/ic8003068 Supporting Info

Preparation, Characterization, and Catalytic Studies of Magnesium Complexes Supported by NNO-Tridentate Schiff-Base Ligands Wen-Chou Hung and Chu-Chieh Lin pp 728–734 DOI: 10.1021/ic801397t Supporting Info

Synthesis and Characterization of Iron(II) Complexes with Tetradentate Diiminodiphosphine or Diaminodiphosphine Ligands as Precatalysts for the Hydrogenation of Acetophenone Christine Sui-Seng, F. Nipa Haque, Alen Hadzovic, Anna-Maria Ptz, Valerie Reuss, Nils Meyer, Alan J. Lough, Marco Zimmer-De Iuliis and Robert H. Morris pp 735–743 DOI: 10.1021/ic801518h Supporting Info

Bridged Bis(amidinate) Ytterbium Alkoxide and Phenoxide: Syntheses, Structures, and Their High Activity for Controlled Polymerization of l-Lactide and ε-Caprolactone Junfeng Wang, Yingming Yao, Yong Zhang and Qi Shen pp 744–751 DOI: 10.1021/ic801189j Supporting Info

The Unique Decomposition Behavior of the Dimeric Dialkylaluminum Hydrazide [(Me3C)2Al−N(H)−N(H)−Me]2−Butane versus Ammonia Elimination Werner Uhl, Thomas Abel, Alexander Hepp, Tom Nilges, Friedhelm Rogel, Ernst-Ulrich Wrthwein and Nugzar Ghavtadze pp 752–759 DOI: 10.1021/ic8016134 Supporting Info

Synthesis, Molecular, and Electronic Structure of (η8-C8H8)Ln(scorpionate) Half-Sandwich Complexes: An Experimental Key to a Better Understanding of f-Element-Cyclooctatetraenyl Bonding Hanns-Dieter Amberger, Frank T. Edelmann, Jochen Gottfriedsen, Regine Herbst-Irmer, Stefan Jank, Ulrike Kilimann, Mathias Noltemeyer, Hauke Reddmann and Martina Schfer pp 760–772 DOI: 10.1021/ic801765n Supporting Info

Core Expansion Reactions of Cyanamido/Carbodiimido-Bridged Polynuclear Iridium Complexes Makoto Imaji, Yoshiaki Tanabe, Yuichiro Mutoh and Youichi Ishii pp 773–780 DOI: 10.1021/ic8017503 Supporting Info

Solvent Effects on Uranium(VI) Fluoride and Hydroxide Complexes Studied by EXAFS and Quantum Chemistry Valrie Vallet, Ulf Wahlgren, Bernd Schimmelpfennig, Henry Moll, Zoltn Szab and Ingmar Grenthe p 781 DOI: 10.1021/ic801638p

Metallacarboranes as Building Blocks for Polyanionic Polyarmed Aryl-Ether Materials Pau Farrs, Francesc Teixidor, Raikko Kiveks, Reijo Sillanp, Clara Vias, Bohumir Grner and Ivana Cisarova p 782 DOI: 10.1021/ic8022997

Issue 3

Calibration of Modern Density Functional Theory Methods for the Prediction of 57Fe Mssbauer Isomer Shifts: Meta-GGA and Double-Hybrid Functionals Michael Rmelt, Shengfa Ye and Frank Neese pp 784–785 DOI: 10.1021/ic801535v Supporting Info

A Strategy for Synthesis of Ionic Metal-Organic Frameworks Lijun Han, Suojiang Zhang, Yibo Wang, Xingjuan Yan and Xingmei Lu pp 786–788 DOI: 10.1021/ic800632r Supporting Info

Unprecedented Self-Catenated Eight-Connected Network Based on Novel Azide-Bridged Tetramanganese(II) Clusters Yan-Qin Wang, Jian-Yong Zhang, Qin-Xiang Jia, En-Qing Gao and Cai-Ming Liu pp 789–791 DOI: 10.1021/ic801968x Supporting Info

Ferromagnetic Disklike MnIVMnII3NaI3 Heptanuclear Complex with a S = 9 Ground State Cai-Ming Liu, De-Qing Zhang and Dao-Ben Zhu pp 792–794 DOI: 10.1021/ic8018474 Supporting Info

Double Cleavage of sp2 C−H and sp3 C−H Bonds on One Metal Center: DMF-Appended Cyclometalated Platinum(II) and -(IV) Porphyrins Shigeru Yamaguchi, Hiroshi Shinokubo and Atsuhiro Osuka pp 795–797 DOI: 10.1021/ic8019149 Supporting Info

Cleavage of a N−H Bond of Ammonia at Room Temperature by a Germylene Anukul Jana, Ina Objartel, Herbert W. Roesky and Dietmar Stalke pp 798–800 DOI: 10.1021/ic801964u Supporting Info

Mechanism of the Iron-Mediated Alkene Aziridination Reaction: Experimental and Computational Investigations Katie L. Klotz, Luke M. Slominski, Miranda E. Riemer, James A. Phillips and Jason A. Halfen pp 801–803 DOI: 10.1021/ic8020244 Supporting Info

Vanadium-Induced Nucleophilic IPSO Substitutions in a Coordinated Tetrachlorosemiquinone Ring: Formation of the Chloranilate Anion as a Bridging Ligand Pabitra Baran Chatterjee, Kisholoy Bhattacharya, Nabanita Kundu, Ki-Young Choi, Rodolphe Clrac and Muktimoy Chaudhury pp 804–806 DOI: 10.1021/ic801985g Supporting Info

{Mn6}n Single-Chain Magnet Bearing Azides and Di-2-pyridylketone-Derived Ligands Theocharis C. Stamatatos, Khalil A. Abboud, Wolfgang Wernsdorfer and George Christou pp 807–809 DOI: 10.1021/ic8020645 Supporting Info

Zero-Dimensional Units of Ligand-Bridged Gallium-Sulfide Supertetrahedra Paz Vaqueiro and M. Lucia Romero pp 810–812 DOI: 10.1021/ic8020723 Supporting Info

A Nontwisted, Ferromagnetically Coupled MnIII3O Triangular Complex from the Use of 2,6-Bis(hydroxymethyl)-p-cresol Christos Lampropoulos, Khalil A. Abboud, Theocharis C. Stamatatos and George Christou pp 813–815 DOI: 10.1021/ic802084h Supporting Info

Cyanide-Bridged One-Dimensional Ferromagnetic RuIIIMnIII Coordination Polymer Exhibiting a Field-Induced Magnetic Phase Transition Jung Hee Yoon, Houng Sik Yoo, Hyoung Chan Kim, Sung Won Yoon, Byoung Jin Suh and Chang Seop Hong pp 816–818 DOI: 10.1021/ic802186z Supporting Info

Metal Tetraphosphonate “Wires” and Their Corrosion Inhibiting Passive Films Konstantinos D. Demadis, Eleni Barouda, Raphael G. Raptis and Hong Zhao pp 819–821 DOI: 10.1021/ic802032y Supporting Info

Multicomponent Assembly of Heterometallic Isosceles Triangles Michael Schmittel and Kingsuk Mahata pp 822–824 DOI: 10.1021/ic8021084 Supporting Info

Uranyl-Lanthanide Heterometallic Complexes with Cucurbit[6]uril and Perrhenate Ligands Pierre Thury pp 825–827 DOI: 10.1021/ic802270n Supporting Info

Theoretical and Spectroscopic Investigations of the Bonding and Reactivity of (RO)3MN Molecules, where M = Cr, Mo, and W Shentan Chen, Malcolm H. Chisholm, Ernest R. Davidson, Jason B. English and Dennis L. Lichtenberger pp 828–837 DOI: 10.1021/ic801786u

Comparison of the Reactivity of Bis(μ-oxo)CuIICuIII and CuIIICuIII Species to Methane Yoshihito Shiota and Kazunari Yoshizawa pp 838–845 DOI: 10.1021/ic8003933 Supporting Info

Isolation and Structural Characterization of a Binuclear Intermediate Species Pertinent to Transmetalation of Zn(salphen) Complexes and the Formation of Polynuclear Salen Structures Leire San Felices, Eduardo C. Escudero-Adn, Jordi Benet-Buchholz and Arjan W. Kleij pp 846–853 DOI: 10.1021/ic8018265 Supporting Info

CoII Molecular Square with Single-Molecule Magnet Properties Dayu Wu, Dong Guo, You Song, Wei Huang, Chunying Duan, Qingjin Meng and Osamu Sato pp 854–860 DOI: 10.1021/ic8012188 Supporting Info

Theoretical Studies of N2 Reduction to Ammonia in Fe(dmpe)2N2 Robert B. Yelle, Justin L. Crossland, Nathaniel K. Szymczak and David R. Tyler pp 861–871 DOI: 10.1021/ic800930t Supporting Info

A Bioaccumulative Cyclometalated Platinum(II) Complex with Two-Photon-Induced Emission for Live Cell Imaging Chi-Kin Koo, Ka-Leung Wong, Cornelia Wing-Yin Man, Yun-Wah Lam, Leo King-Yan So, Hoi-Lam Tam, Sai-Wah Tsao, Kok-Wai Cheah, Kai-Chung Lau, Yang-Yi Yang, Jin-Can Chen and Michael Hon-Wah Lam pp 872–878 DOI: 10.1021/ic801261h

α- to β-(dmes)BiI5 (dmes = Dimethyl(2-ethylammonium)sulfonium Dication): Umbrella Reversal of Sulfonium in the Solid State and Short I···I Interchain ContactsCrystal Structures, Optical Properties, and Theoretical Investigations of 1D Iodobismuthates Nicolas Louvain, Nicolas Mercier and Florent Boucher pp 879–888 DOI: 10.1021/ic801900r Supporting Info

Ionic Liquids Containing Boron Cluster Anions Mark Nieuwenhuyzen, Kenneth R. Seddon, Francesc Teixidor, Alberto V. Puga and Clara Vias pp 889–901 DOI: 10.1021/ic801448w Supporting Info

Geometric Isomerism in Pentacoordinate Cu2+ Complexes: Equilibrium, Kinetic, and Density Functional Theory Studies Reveal the Existence of Equilibrium between Square Pyramidal and Trigonal Bipyramidal Forms for a Tren-Derived Ligand Andrs G. Algarra, Manuel G. Basallote, Carmen E. Castillo, M. Paz Clares, Armando Ferrer, Enrique Garca-Espaa, Jos M. Llinares, M. Angeles Mez and Conxa Soriano pp 902–914 DOI: 10.1021/ic8013078 Supporting Info

Self-Assembly of a Series of Cobalt(II) Coordination Polymers Constructed from H2tbip and Dipyridyl-Based Ligands Lu-Fang Ma, Li-Ya Wang, Yao-Yu Wang, Stuart R. Batten and Jian-Ge Wang pp 915–924 DOI: 10.1021/ic801278j Supporting Info

From Simple Diols to Carbohydrate Derivatives of Phenylarsonic Acid Richard Betz and Peter Klfers pp 925–935 DOI: 10.1021/ic8014018 Supporting Info

Mononuclear Metallacyclic Silver(I) Complexes of Third Generation Bis(1-pyrazolyl)methane Ligands Daniel L. Reger, Elizabeth A. Foley and Mark D. Smith pp 936–945 DOI: 10.1021/ic801594q Supporting Info

Dimensionally Modulated, Single-Crystalline LiMPO4 (M= Mn, Fe, Co, and Ni) with Nano-Thumblike Shapes for High-Power Energy Storage A. Vadivel Murugan, T. Muraliganth, P. J. Ferreira and A. Manthiram pp 946–952 DOI: 10.1021/ic8015723

The Hydrothermal and Structural Chemistry of Oxovanadium−Arylphosphonate Networks and Frameworks Wayne Ouellette, Guangbin Wang, Hongxue Liu, Gordon T. Yee, Charles J. O’Connor and Jon Zubieta pp 953–963 DOI: 10.1021/ic801450m Supporting Info

Complexation of Lanthanides with Nitrate at Variable Temperatures: Thermodynamics and Coordination Modes Linfeng Rao and Guoxin Tian pp 964–970 DOI: 10.1021/ic801604f

Tetragonal to TriclinicA Phase Change for [Fe(TPP)(NO)] Nathan J. Silvernail, Marilyn M. Olmstead, Bruce C. Noll and W. Robert Scheidt pp 971–977 DOI: 10.1021/ic801617q Supporting Info

Mixed-Metal Assemblies Involving Ferrocene−Naphthyridine Hybrids Nabanita Sadhukhan and Jitendra K. Bera pp 978–990 DOI: 10.1021/ic801586d Supporting Info

Dithienylcyclopentenes-Containing Transition Metal Bisterpyridine Complexes Directed toward Molecular Electronic Applications Yu-Wu Zhong, Neus Vila, Jay C. Henderson and Hctor D. Abrua pp 991–999 DOI: 10.1021/ic801588y Supporting Info

Peculiar High-Pressure Behavior of BiMnO3 Alexei A. Belik, Hitoshi Yusa, Naohisa Hirao, Yasuo Ohishi and Eiji Takayama-Muromachi pp 1000–1004 DOI: 10.1021/ic8015996 Supporting Info

Supersilylated Tetraphosphene Derivatives M2[t-Bu3SiPPPPSi-t-Bu3] (M = Li, Na, Rb, Cs) and Ba[t-Bu3SiPPPPSi-t-Bu3]: Reactivity and Cis−Trans Isomerization Andreas Lorbach, Andor Nadj, Sandor Tüllmann, Franz Dornhaus, Frauke Schdel, Inge Snger, Gnter Margraf, Jan W. Bats, Michael Bolte, Max C. Holthausen, Matthias Wagner and Hans-Wolfram Lerner pp 1005–1017 DOI: 10.1021/ic8016003 Supporting Info

Gas-Phase Reactions of Sulfur Hexafluoride with Transition Metal and Main Group Atomic Cations: Room-Temperature Kinetics and Periodicities in Reactivity Ping Cheng, Alireza Shayesteh and Diethard K. Bohme pp 1018–1029 DOI: 10.1021/ic801625z

Blue Phosphorescent Ir(III) Complex with High Color Purity: fac-Tris(2′,6′-difluoro-2,3′-bipyridinato-N,C4′)iridium(III) Seok Jong Lee, Ki-Min Park, Kiyull Yang and Youngjin Kang pp 1030–1037 DOI: 10.1021/ic801643p Supporting Info

Effects of Hyperconjugation on the Electronic Structure and Photoreactivity of Organic Sulfonyl Chlorides Vlad Martin-Diaconescu and Pierre Kennepohl pp 1038–1044 DOI: 10.1021/ic801665f Supporting Info

Molecular Recognition of Redox-Switchable Bis-Crown Moieties Assembled on a Dicobalt Complex Hisashi Shimakoshi, Kaori Shibata and Yoshio Hisaeda pp 1045–1052 DOI: 10.1021/ic801708v Supporting Info

Strategy for the Stereochemical Assignment of Tris-Heteroleptic Ru(II) Complexes by NMR Spectroscopy Xiulan Xie, Seann P. Mulcahy and Eric Meggers pp 1053–1061 DOI: 10.1021/ic801744a Supporting Info

3-D Lanthanide Metal-Organic Frameworks: Structure, Photoluminescence, and Magnetism Cory A. Black, Jos Snchez Costa, Wen Tian Fu, Chiara Massera, Olivier Roubeau, Simon J. Teat, Guillem Arom, Patrick Gamez and Jan Reedijk pp 1062–1068 DOI: 10.1021/ic8017826 Supporting Info

Oligomerization and Autocatalysis of NH2BH2 with Ammonia−Borane Paul M. Zimmerman, Ankan Paul, Zhiyong Zhang and Charles B. Musgrave pp 1069–1081 DOI: 10.1021/ic801731s Supporting Info

Hierarchical FeWO4 Microcrystals: Solvothermal Synthesis and Their Photocatalytic and Magnetic Properties Yu-Xue Zhou, Hong-Bin Yao, Qiao Zhang, Jun-Yan Gong, Shu-Juan Liu and Shu-Hong Yu pp 1082–1090 DOI: 10.1021/ic801806r Supporting Info

Getting a Clue to the Hydrolytic Activation of White Phosphorus: The Generation and Stabilization of P(OH)2PHPHPH(OH) at Ruthenium Centers Pierluigi Barbaro, Massimo Di Vaira, Maurizio Peruzzini, Stefano Seniori Costantini and Piero Stoppioni pp 1091–1096 DOI: 10.1021/ic801859z Supporting Info

Exploring a Series of Isostructural Dodecanuclear Mixed Ni:Co Clusters: Toward the Control of Elemental Composition Using pH and Stoichiometry Geoffrey J. T. Cooper, Graham N. Newton, De-Liang Long, Paul Kgerler, Mali H. Rosnes, Marco Keller and Leroy Cronin pp 1097–1104 DOI: 10.1021/ic802197u

Water−Dichloromethane Interface Controlled Synthesis of Hierarchical Rutile TiO2 Superstructures and Their Photocatalytic Properties Changhua Wang, Changlu Shao, Yichun Liu and Xinghua Li pp 1105–1113 DOI: 10.1021/ic8018138 Supporting Info

Model Ziegler-Type Hydrogenation Catalyst Precursors, [(1,5-COD)M(μ-O2C8H15)]2 (M = Ir and Rh): Synthesis, Characterization, and Demonstration of Catalytic Activity En Route to Identifying the True Industrial Hydrogenation Catalysts William M. Alley, Chase W. Girard, Saim zkar and Richard G. Finke pp 1114–1121 DOI: 10.1021/ic801933b Supporting Info

Synthesis, Characterization, and in vitro Antimalarial and Antitumor Activity of New Ruthenium(II) Complexes of Chloroquine Chandima S. K. Rajapakse, Alberto Martnez, Becky Naoulou, Andrzej A. Jarzecki, Liliana Surez, Christiane Deregnaucourt, Vronique Sinou, Joseph Schrvel, Elgilda Musi, Grazia Ambrosini, Gary K. Schwartz and Roberto A. Snchez-Delgado pp 1122–1131 DOI: 10.1021/ic802220w Supporting Info

Complexation of Trivalent Lanthanides with Planar Tridentate Aromatic Ligands Tuned by Counteranions and Steric Constraints Aude Escande, Laure Gune, Kerry-Lee Buchwalder and Claude Piguet pp 1132–1147 DOI: 10.1021/ic801908c Supporting Info

Synthesis, Structure, and Magnetism of Heterobimetallic Trinuclear Complexes {[L2Co2Ln][X]} [Ln = Eu, X = Cl; Ln = Tb, Dy, Ho, X = NO3; LH3 = (S)P[N(Me)NCH−C6H3-2-OH-3-OMe]3]: A 3d−4f Family of Single-Molecule Magnets Vadapalli Chandrasekhar, Balasubramanian Murugesa Pandian, Jagadese J. Vittal and Rodolphe Clrac pp 1148–1157 DOI: 10.1021/ic801905p Supporting Info

One-Dimensional CoII and CuII Coordination Polymers and a Discrete CuII4 Complex of Carboxylate-Appended (2-Pyridyl)alkylamine Ligands: Spin-Canting and Anti-/Ferromagnetic Coupling Himanshu Arora, Francesc Lloret and Rabindranath Mukherjee pp 1158–1167 DOI: 10.1021/ic800861m Supporting Info

Synthesis of Urchin-like VO2 Nanostructures Composed of Radially Aligned Nanobelts and Their Disassembly Guicun Li, Kun Chao, Chuanqin Zhang, Qingshan Zhang, Hongrui Peng and Kezheng Chen pp 1168–1172 DOI: 10.1021/ic801620n

Squaramide Hydroxamate-Based Chemidosimeter Responding to Iron(III) with a Fluorescence Intensity Increase Nathaniel C. Lim, Svetlana V. Pavlova and Christian Brckner pp 1173–1182 DOI: 10.1021/ic801322x Supporting Info

An Immobilized Ortho-Palladated Dimethylbenzylamine Complex as an Efficient Catalyst for the Methanolysis of Phosphorothionate Pesticides Mark F. Mohamed, Alexei A. Neverov and R. Stan Brown pp 1183–1191 DOI: 10.1021/ic801382e

Formation of Carbonato and Hydroxo Complexes in the Reaction of Platinum Anticancer Drugs with Carbonate Anthony J. Di Pasqua, Corey R. Centerwall, Deborah J. Kerwood and James C. Dabrowiak pp 1192–1197 DOI: 10.1021/ic801579h Supporting Info

Chelation-Assisted Carbon-Halogen Bond Activation by a Rhodium(I) Complex Shanshan Chen, Yongxin Li, Jing Zhao and Xingwei Li pp 1198–1206 DOI: 10.1021/ic801878e Supporting Info

Structures of Copper Complexes of the Hybrid [SNS] Ligand of Bis(2-(benzylthio)ethyl)amine and Facile Catalytic Formation of 1-Benzyl-4-phenyl-1H-1,2,3-triazole through Click Reaction Shi-Qiang Bai, Lip Lin Koh and T. S. Andy Hor pp 1207–1213 DOI: 10.1021/ic801690v Supporting Info

On the Mechanism of Iron(III)-Dependent Oxidative Dehydrogenation of Amines Juan Pablo Saucedo-Vzquez, Vctor Manuel Ugalde-Saldvar, Alfredo Rubn Toscano, Peter M. H. Kroneck and Martha Elena Sosa-Torres pp 1214–1222 DOI: 10.1021/ic8016968 Supporting Info

Phosphine Polymerization by Nitric Oxide: Experimental Characterization and Theoretical Predictions of Mechanism Yi-Lei Zhao, Jason W. Flora, William David Thweatt, Stephen L. Garrison, Carlos Gonzalez, K. N. Houk and Manuel Marquez pp 1223–1231 DOI: 10.1021/ic801917a Supporting Info

Interaction of Transuranium Elements with Biologically Important Molecules: Structural and Spectroscopic Study of Np(V) Complexes with Imidazole Grigory B. Andreev, Nina A. Budantseva, Ivan G. Tananaev and Boris F. Myasoedov pp 1232–1235 DOI: 10.1021/ic801882p Supporting Info

Synthesis of New Cationic Donor-Stabilized Phosphenium Adducts and Their Unexpected P-Substituent Exchange Reactions Michle Azouri, Jacques Andrieu, Michel Picquet and Hlne Cattey pp 1236–1242 DOI: 10.1021/ic801870w

Catalyst-Free Growth of Quasi-Aligned Nanorods of Single Crystal Cu3Mo2O9 and Their Catalytic Properties W. G. Chu, H. F. Wang, Y. J. Guo, L. N. Zhang, Z. H. Han, Q. Q. Li and S. S. Fan pp 1243–1249 DOI: 10.1021/ic801885c Supporting Info

Structural Models for the Active Site of Acetyl-CoA Synthase: Synthesis of Dinuclear Nickel Complexes Having Thiolate, Isocyanide, and Thiourea on the Nip Site Mikinao Ito, Mai Kotera, Yumei Song, Tsuyoshi Matsumoto and Kazuyuki Tatsumi pp 1250–1256 DOI: 10.1021/ic801967e Supporting Info

Copper β-Octakis(trifluoromethyl)corroles: New Paradigms for Ligand Substituent Effects in Transition Metal Complexes Kolle Ekaney Thomas, Ingar H. Wasbotten and Abhik Ghosh p 1257 DOI: 10.1021/ic802317e

Mononuclear Manganese(III) Complexes as Building Blocks for the Design of Trinuclear Manganese Clusters: Study of the Ligand Influence on the Magnetic Properties of the [Mn3(μ3-O)]7+ Core Marta Viciano-Chumillas, Stefania Tanase, Ilpo Mutikainen, Urho Turpeinen, L. Jos de Jongh and Jan Reedijk p 1258 DOI: 10.1021/ic802339b

Issue 4

Synthesis, Properties, and Theoretical Studies of New Stepwise Layered Iodoplumbate: [Ni(opd)2(acn)2]n[Pb4I10]n Jin-Peng Li, Long-Hua Li, Li-Ming Wu and Ling Chen pp 1260–1262 DOI: 10.1021/ic8012624 Supporting Info

A Novel Cyclometalated Dimeric Iridium Complex, [(dfpbo)2Ir]2 [dfpbo = 2-(3,5-Difluorophenyl)benzoxazolato-N,C2′], Containing an Unsupported IrII−IrII Bond Hsiu-Pen Lee, Yi-Fen Hsu, Tsun-Ren Chen, Jhy-Der Chen, Kelvin H.-C. Chen and Ju-Chun Wang pp 1263–1265 DOI: 10.1021/ic8019952 Supporting Info

Novel Polythreaded Coordination Polymer: from an Armed-Polyrotaxane Sheet to a 3D Polypseudorotaxane Array, Photo- and Thermochromic Behaviors Qing-Xia Yao, Zhan-Feng Ju, Xu-Hui Jin and Jie Zhang pp 1266–1268 DOI: 10.1021/ic8021672 Supporting Info

Magnetic Bistability and Thermochromism in a Molecular CuII Chain Fatima Setifi, Samia Benmansour, Mathieu Marchivie, Galle Dupouy, Smail Triki, Jean Sala-Pala, Jean-Yves Salan, Carlos J. Gmez-García, Sbastien Pillet, Claude Lecomte and Eliseo Ruiz pp 1269–1271 DOI: 10.1021/ic802292s Supporting Info

Side Chains of Cobalt Corrinoids Control the Sensitivity and Selectivity in the Colorimetric Detection of Cyanide Christine Männel-Croisé and Felix Zelder pp 1272–1274 DOI: 10.1021/ic900053h Supporting Info

New Inorganic Helical Chain: Synthesis, Structure, Characterization, and Interconversion of BaGa2O2(OH)4 Min Kyung Kim, Vinna Jo, Il-Wun Shim and Kang Min Ok pp 1275–1277 DOI: 10.1021/ic802187w Supporting Info

High-Potential C112D/M121X (X = M, E, H, L) Pseudomonas aeruginosa Azurins Kyle M. Lancaster, Keiko Yokoyama, John H. Richards, Jay R. Winkler and Harry B. Gray pp 1278–1280 DOI: 10.1021/ic802322e Supporting Info

Metal−Organic Polyhedron Based on a CuII Paddle-Wheel Secondary Building Unit at the Truncated Octahedron Corners M. Jaya Prakash, Yang Zou, Seunghee Hong, Mira Park, Minh-Phuong Ngoc Bui, Gi Hun Seong and Myoung Soo Lah pp 1281–1283 DOI: 10.1021/ic802382p Supporting Info

Ternary Erbium Chromium Sulfides: Structural Relationships and Magnetic Properties Paz Vaqueiro, Iwona Szkoda, Rodolfo D. Sanchez and Anthony V. Powell pp 1284–1292 DOI: 10.1021/ic801482a Supporting Info

Synthesis and Characterization of Lithium Hemiporphyrazines Saovalak Sripothongnak, Anna M. Pischera, Matthew P. Espe, William S. Durfee and Christopher J. Ziegler pp 1293–1300 DOI: 10.1021/ic800817x Supporting Info

Diversity of Azido Magnetic Chains Constructed with Flexible Ligand 2,2′-Dipyridylamine Xiu-Teng Wang, Xiao-Hua Wang, Zhe-Ming Wang and Song Gao pp 1301–1308 DOI: 10.1021/ic801505a Supporting Info

Induction of Cell Death by Ternary Copper(II) Complexes of l-Tyrosine and Diimines: Role of Coligands on DNA Binding and Cleavage and Anticancer Activity Sethu Ramakrishnan, Venugopal Rajendiran, Mallayan Palaniandavar, Vaiyapuri Subbarayan Periasamy, Bangalore Suresh Srinag, Hanumanthappa Krishnamurthy and Mohammad Abdulkader Akbarsha pp 1309–1322 DOI: 10.1021/ic801144x Supporting Info

Theoretical Study of the Oxidation Reaction and Electron Spin Resonance Parameters Involving Sulfite Oxidase Elizabeth Hernandez-Marin and Tom Ziegler pp 1323–1333 DOI: 10.1021/ic801158t Supporting Info

FormationofCeO2NanotubesfromCe(OH)CO3 Nanorods through Kirkendall Diffusion Guozhu Chen, Sixiu Sun, Xun Sun, Weiliu Fan and Ting You pp 1334–1338 DOI: 10.1021/ic801714z Supporting Info

Formation of Crystalline Polymers from the Reaction of Amine-Functionalized C60 with Silver Salts Christopher J. Chancellor, Marilyn M. Olmstead and Alan L. Balch pp 1339–1345 DOI: 10.1021/ic8012427 Supporting Info

R3Au6+xAl26T (R = Ca, Sr, Eu, Yb; T = Early Transition Metal): a Large Family of Compounds with a Stuffed BaHg11 Structure Type Grown from Aluminum Flux Susan E. Latturner, Daniel Bilc, S. D. Mahanti and Mercouri G. Kanatzidis pp 1346–1355 DOI: 10.1021/ic801095v Supporting Info

Autoxidation of Platinum(IV) Hydrocarbyl Hydride Complexes To Form Platinum(IV) Hydrocarbyl Hydroperoxide Complexes Jennifer L. Look, Douglas D. Wick, James M. Mayer and Karen I. Goldberg pp 1356–1369 DOI: 10.1021/ic801216r Supporting Info

Nonlinear Optical and Related Properties of Iron(II) Pentacyanide Complexes with Quaternary Nitrogen Electron Acceptor Units Benjamin J. Coe, Simon P. Foxon, Elizabeth C. Harper, James Raftery, Rachel Shaw, Catherine A. Swanson, Inge Asselberghs, Koen Clays, Bruce S. Brunschwig and Anthony G. Fitch pp 1370–1379 DOI: 10.1021/ic801224u Supporting Info

Solution Interaction of Potassium and Calcium Bis(trimethylsilyl)amides; Preparation of Ca[N(SiMe3)2]2 from Dibenzylcalcium Adam M. Johns, Stephen C. Chmely and Timothy P. Hanusa pp 1380–1384 DOI: 10.1021/ic8012766

Synthesis and Electrochemical Characterization of Halide, Isocyanide, and Alkynyl Synthons Containing the Encumbered Triangular Cluster Unit Pt3(μ-PtBu2)3 Claudia Cavazza, Fabrizia Fabrizi de Biani, Tiziana Funaioli, Piero Leoni, Fabio Marchetti, Lorella Marchetti and Piero Zanello pp 1385–1397 DOI: 10.1021/ic801268v Supporting Info

An Acyclic Dimer of Cyclodiphosphazane {tBuHN(tBuNP)2OCH2}2 Containing Alkoxo and Amido Functionalities: Synthesis, Derivatization, Bi- (PdII, RhI), and Tetranuclear (PdII, AuI, RhIAuI) Transition Metal Complexes Maravanji S. Balakrishna, Ramalingam Venkateswaran and Joel T. Mague pp 1398–1406 DOI: 10.1021/ic801256h Supporting Info

Possible Steric Control of the Relative Strength of Chelation Enhanced Fluorescence for Zinc(II) Compared to Cadmium(II): Metal Ion Complexing Properties of Tris(2-quinolylmethyl)amine, a Crystallographic, UV−Visible, and Fluorometric Study Neil J. Williams, Wei Gan, Joseph H. Reibenspies and Robert D. Hancock pp 1407–1415 DOI: 10.1021/ic801403s

Cobalt Induced Tandem C−H Activation/Decarbonylation of Various Aromatic Aldehydes and Related Benzylic Alcohols Forming Mononuclear Aryl Monocarbonyl Complexes Robert Beck, Ulrich Flrke and Hans-Friedrich Klein pp 1416–1422 DOI: 10.1021/ic801673h Supporting Info

Crystal Structures of Titanate Nanotubes: A Raman Scattering Study Tao Gao, Helmer Fjellvåg and Poul Norby pp 1423–1432 DOI: 10.1021/ic801508k Supporting Info

In Situ Immobilization of Metalloligands: A Synthetic Route to Homometallic Mixed-Valence Coordination Polymers Wen-Xiu Ni, Mian Li, Shun-Ze Zhan, Jin-Zhang Hou and Dan Li pp 1433–1441 DOI: 10.1021/ic8015244 Supporting Info

Reaction Mechanism of the Dinuclear Zinc Enzyme N-Acyl-l-homoserine Lactone Hydrolase: A Quantum Chemical Study Rong-Zhen Liao, Jian-Guo Yu and Fahmi Himo pp 1442–1448 DOI: 10.1021/ic801531n

Synthesis, Crystal Structures, and Photoluminescent Properties of the Cu(I)/X/α,ω-Bis(benzotriazole)alkane Hybrid Family (X = Cl, Br, I, and CN) Man-Cheng Hu, Yan Wang, Quan-Guo Zhai, Shu-Ni Li, Yu-Cheng Jiang and Yong Zhang pp 1449–1468 DOI: 10.1021/ic801574k Supporting Info

Ligand-Selective Photodissociation from [Ru(bpy)(4AP)4]2+: a Spectroscopic and Computational Study Luca Salassa, Claudio Garino, Giovanni Salassa, Carlo Nervi, Roberto Gobetto, Carlo Lamberti, Diego Gianolio, Ranieri Bizzarri and Peter J. Sadler pp 1469–1481 DOI: 10.1021/ic8015436 Supporting Info

Self-Assembly of Ambivalent Organic/Inorganic Building Blocks Containing Re6 Metal Atom Cluster: Formation of a Luminescent Honeycomb, Hollow, Tubular Metal-Organic Framework Michael A. Shestopalov, Stphane Cordier, Olivier Hernandez, Yann Molard, Christiane Perrin, Andr Perrin, Vladimir E. Fedorov and Yuri V. Mironov pp 1482–1489 DOI: 10.1021/ic8018277 Supporting Info

Accelerated Photorelease of NO from {Ru-NO}6 Nitrosyls Containing Carboxamido-N and Carboxylato-O Donors: Syntheses, Structures, and Photochemistry Genevieve M. Halpenny and Pradip K. Mascharak pp 1490–1497 DOI: 10.1021/ic801748t Supporting Info

Synthesis, Electrochemistry, Photophysics, and Solvatochromism in New Cyclometalated 6-Phenyl-4-(p-R-phenyl)-2,2′-bipyridyl (R = Me, COOMe, P(O)(OEt)2) (CNN) Platinum(II) Thiophenolate Chromophores Jacob Schneider, Pingwu Du, Xiaoyong Wang, William W. Brennessel and Richard Eisenberg pp 1498–1506 DOI: 10.1021/ic801767q Supporting Info

Solution Structure and Dynamics, Stability, and NIR Emission Properties of Lanthanide Complexes with a Carboxylated Bispyrazolylpyridyl Ligand Marta Mato-Iglesias, Teresa Rodrguez-Blas, Carlos Platas-Iglesias, Matthieu Starck, Pascal Kadjane, Raymond Ziessel and Loc Charbonnire pp 1507–1518 DOI: 10.1021/ic801816p Supporting Info

Synthesis, Characterization, and Properties of Organically Templated Lanthanide Oxalatophosphates with a Three-Dimensional Honeycomb Structure: (H4APPIP)[Ln3(C2O4)5.5(H2PO4)2]·5H2O (Ln = Er−Lu, APPIP = 1,4-Bis(3-aminopropyl)piperazine) Chih-Min Wang, Yi-Ying Wu, Chia-Hung Hou, Chii-Chang Chen and Kwang-Hwa Lii pp 1519–1523 DOI: 10.1021/ic801817e Supporting Info

A Magneto-Structural Study of a Hexanuclear (VIVO)6-Complex and a Tetranuclear Mixed-Valent [VIII2VIV2] Species Biplab Biswas, Thomas Weyhermller, Eckhard Bill and Phalguni Chaudhuri pp 1524–1532 DOI: 10.1021/ic8018327 Supporting Info

Two Related Gadolinium Aquo Carbonate 2-D and 3-D Structures and Their Thermal, Spectroscopic, and Paramagnetic Properties David L. Rogow, Claudia H. Swanson, Allen G. Oliver and Scott R. J. Oliver pp 1533–1541 DOI: 10.1021/ic801844b Supporting Info

Nanostructured ZnS and CdS Films Synthesized using Layered Double Hydroxide Films as Precursor and Template Birgit Schwenzer, Lia Z. Pop, James R. Neilson, Timothy B. Sbardellati and Daniel E. Morse pp 1542–1550 DOI: 10.1021/ic801865w Supporting Info

Formation of a Partially Oxidized Gold Compound by Electrolytic Oxidation of the Solvoluminescent Gold(I) Trimer, Au3(MeNCOMe)3 Krzysztof Winkler, Monika Wysocka-ołopa, Katarzyna Reko, Ludwik Dobrzyski, Jess C. Vickery and Alan L. Balch pp 1551–1558 DOI: 10.1021/ic801922a

22-Isopolytungstate Fragment [H2W22O74]14−Coordinated to Lanthanide Ions Amal H. Ismail, Michael H. Dickman and Ulrich Kortz pp 1559–1565 DOI: 10.1021/ic801946m Supporting Info

Mononuclear Ferrocenophane Structural Motifs with Two Thiourea Arms Acting as a Dual Binding Site for Anions and Cations Francisco Otn, Arturo Espinosa, Alberto Trraga, Imma Ratera, Klaus Wurst, Jaime Veciana and Pedro Molina pp 1566–1576 DOI: 10.1021/ic801879x Supporting Info

Synthesis of Apoptosis-Inducing Iminophosphorane Organogold(III) Complexes and Study of Their Interactions with Biomolecular Targets Neha Shaik, Alberto Martnez, Idline Augustin, Hugh Giovinazzo, Armando Varela-Ramrez, Mercedes Sana, Renato J. Aguilera and Mara Contel pp 1577–1587 DOI: 10.1021/ic801925k Supporting Info

Nature of the Bonding in Metal-Silane σ-Complexes G. Sean McGrady, Peter Sirsch, Nicholas P. Chatterton, Andreas Ostermann, Carlo Gatti, Sandra Altmannshofer, Verena Herz, Georg Eickerling and Wolfgang Scherer pp 1588–1598 DOI: 10.1021/ic8019777 Supporting Info

New Findings in the Chemistry of Iron Carbonyls: The Previously Unreported [H4−nFe4(CO)12]n− (n = 1, 2) Series of Clusters, Which Fills the Gap with Ruthenium and Osmium Cristina Femoni, Maria Carmela Iapalucci, Giuliano Longoni, Stefano Zacchini and Salvatore Zarra pp 1599–1605 DOI: 10.1021/ic802015f Supporting Info

Mixed-Valent {Mn14} Aggregate Encapsulated by the Inorganic Polyoxometalate Shell: [MnIII13MnIIO12(PO4)4(PW9O34)4]31− Qiong Wu, Yang-Guang Li, Yong-Hui Wang, En-Bo Wang, Zhi-Ming Zhang and Rodolphe Clrac pp 1606–1612 DOI: 10.1021/ic802023h Supporting Info

Structural Chemistry and Magnetic Properties of Nd18Li8Fe5−xMxO39(M = Mn, Co) Sin E. Dutton, Peter D. Battle, Fernande Grandjean, Gary J. Long and Peter A. van Daesdonk pp 1613–1623 DOI: 10.1021/ic802035v Supporting Info

Bis(diphenylphosphino)methane-Phosphonate Ligands and Their Pd(II), Ni(II) and Cu(I) Complexes. Catalytic Oligomerization of Ethylene Adel Hamada and Pierre Braunstein pp 1624–1637 DOI: 10.1021/ic8020436 Supporting Info

Ligands for Dinitrogen Fixation at Schrock-Type Catalysts Stephan Schenk and Markus Reiher pp 1638–1648 DOI: 10.1021/ic802037w Supporting Info

Large Cation−Anion Materials Based on Trinuclear Ruthenium(III) Salts of Keggin and Wells-Dawson Anions Having Water-Filled Channels Masooma Ibrahim, Michael H. Dickman, Andreas Suchopar and Ulrich Kortz pp 1649–1654 DOI: 10.1021/ic802096v Supporting Info

Photofragmentation Pathways and Photodeposition of Nanoparticles from a Gas Phase Copper-Containing Precursor Philip X. Rutkowski and Jeffrey I. Zink pp 1655–1660 DOI: 10.1021/ic802138p

Systematic Thermodynamics of Hydration (and of Solvation) of Inorganic Solids Leslie Glasser and Franca Jones pp 1661–1665 DOI: 10.1021/ic802101g Supporting Info

Halogen Bonded Supramolecular Assemblies of [Ru(bipy)(CN)4]2− Anions and N-Methyl-Halopyridinium Cations in the Solid State and in Solution Sofia Derossi, Lee Brammer, Christopher A. Hunter and Michael D. Ward pp 1666–1677 DOI: 10.1021/ic8021529 Supporting Info

Fe L- and K-edge XAS of Low-Spin Ferric Corrole: Bonding and Reactivity Relative to Low-Spin Ferric Porphyrin Rosalie K. Hocking, Serena DeBeer George, Zeev Gross, F. Ann Walker, Keith O. Hodgson, Britt Hedman and Edward I. Solomon pp 1678–1688 DOI: 10.1021/ic802248t Supporting Info

Inorganic Frameworks from Selenidotetrelate Anions [T2Se6]4− (T = Ge, Sn): Synthesis, Structures, and Ionic Conductivity of [K2(H2O)3][MnGe4Se10] and (NMe4)2[MSn4Se10] (M = Mn, Fe) Sima Haddadpour, Maike Melullis, Halgard Staesche, C. R. Mariappan, Bernhard Roling, Rodolphe Clrac and Stefanie Dehnen pp 1689–1698 DOI: 10.1021/ic802170f Supporting Info

Structural Study of Acidic Metallocavitands and Characterization of their Interactions with Lewis Bases Christian N. Garon, Serge I. Gorelsky, Olivier Sigouin, Tom K. Woo and Frdric-Georges Fontaine pp 1699–1710 DOI: 10.1021/ic802233e Supporting Info

Photophysical and Redox Properties of Dinuclear Ru and Os Polypyridyl Complexes with Incorporated Photostable Spiropyran Bridge Ron T. F. Jukes, Biljana Bozic, Peter Belser, Luisa De Cola and Frantiek Hartl pp 1711–1721 DOI: 10.1021/ic800963u

Donor−Acceptor Chemistry at Heavy Chalcogen Centers Jason L. Dutton and Paul J. Ragogna pp 1722–1730 DOI: 10.1021/ic801883e Supporting Info

Synthesis and Characterization of 4,5-Dicyano-2H-1,2,3-triazole and Its Sodium, Ammonium, and Guanidinium Salts Margaret-Jane Crawford, Konstantin Karaghiosoff, Thomas M. Klaptke and Franz A. Martin pp 1731–1743 DOI: 10.1021/ic801793p Supporting Info

Complex Formation of Uranyl Ion with Triphenylphosphine Oxide and Its Ligand Exchange Reaction in 1-Butyl-3-methylimidazolium Nonafluorobutanesulfonate Ionic Liquid Koichiro Takao, Takafumi Takahashi and Yasuhisa Ikeda pp 1744–1752 DOI: 10.1021/ic8018666 Supporting Info

Organometallic Osmium(II) Arene Anticancer Complexes Containing Picolinate Derivatives Sabine H. van Rijt, Anna F. A. Peacock, Russell D. L. Johnstone, Simon Parsons and Peter J. Sadler pp 1753–1762 DOI: 10.1021/ic8020222 Supporting Info

One- Versus Two-Electron Oxidation with Peroxomonosulfate Ion: Reactions with Iron(II), Vanadium(IV), Halide Ions, and Photoreaction with Cerium(III) Gbor Lente, Jzsef Kalmr, Zsuzsa Baranyai, Alz Kun, Ildik Kk, Dvid Bajusz, Marcell Takcs, Lilla Veres and Istvn Fbin pp 1763–1773 DOI: 10.1021/ic801569k Supporting Info

Synthesis of Mixed Cp/TpMe2 Lanthanide Complexes from Lanthanocene Precursors and their Structures and Reactivities Fuyan Han, Jie Zhang, Yanan Han, Zhengxing Zhang, Zhenxia Chen, Linhong Weng and Xigeng Zhou pp 1774–1781 DOI: 10.1021/ic802094q Supporting Info

Radical Formation in the [MeReO3]-Catalyzed Aqueous Peroxidative Oxidation of Alkanes: A Theoretical Mechanistic Study Maxim L. Kuznetsov and Armando J. L. Pombeiro p 1782 DOI: 10.1021/ic9000158

Issue 5

Sensitization of Naphthalene Monomer Phosphorescence in a Sandwich Adduct with an Electron-Poor Trinuclear Silver(I) Pyrazolate Complex Mohammad A. Omary, Oussama Elbjeirami, Chammi S. Palehepitiya Gamage, Kristin M. Sherman and H. V. Rasika Dias pp 1784–1786 DOI: 10.1021/ic8021326 Supporting Info

Site Preferences of NH4+ in Its Solid Solutions with Cs2WS4 and Rb2WS4 from Multinuclear Solid-State MAS NMR Hans J. Jakobsen, Henrik Bildsøe, Jørgen Skibsted, Michael R. Hansen, Michael Brorson, Bikshandarkoil R. Srinivasan and Wolfgang Bensch pp 1787–1789 DOI: 10.1021/ic8023937 Supporting Info

•NO2-Mediated meso-Hydroxylation of Iron(III) Porphyrin G. J. Abhilash, Jagannath Bhuyan, Pinky Singh, Suman Maji, Kuntal Pal and Sabyasachi Sarkar pp 1790–1792 DOI: 10.1021/ic800864w Supporting Info

Magnetic Circular Dichroism Spectrum of Plastocyanin by Calculation Michael Seth and Tom Ziegler pp 1793–1795 DOI: 10.1021/ic801802v Supporting Info

Synthesis of Fluorinated ReCl(4,4′-R2-2,2′-bipyridine)(CO)3 Complexes and Their Photophysical Characterization in CH3CN and Supercritical CO2 Mark D. Doherty, David C. Grills and Etsuko Fujita pp 1796–1798 DOI: 10.1021/ic8019556 Supporting Info

Highly Selective Fluorescence Detection of Cu2+ in Water by Chiral Dimeric Zn2+ Complexes through Direct Displacement Snehadrinarayan Khatua, Shin Hei Choi, Junseong Lee, Jung Oh Huh, Youngkyu Do and David G. Churchill pp 1799–1801 DOI: 10.1021/ic802314u Supporting Info

Chiral Synthesis of a Mononuclear Nickel(II) Complex Formed from an Achiral Tripodal Amine Ligand: Spontaneous Resolution A. Srinivasa Rao, Abhijit Pal, Rajarshi Ghosh and Samar K. Das pp 1802–1804 DOI: 10.1021/ic802171b Supporting Info

Unprecedented Linking of Two Polyoxometalate Units with a Metal−Metal Multiple Bond Maxim N. Sokolov, Vladimir S. Korenev, Natalya V. Izarova, Eugenia V. Peresypkina, Cristian Vicent and Vladimir P. Fedin pp 1805–1807 DOI: 10.1021/ic802373j

Thermodynamic Investigations of the Staudinger Reaction of Trialkylphosphines with 1-Adamantyl Azide and the Isolation of an Unusual s-cis Phosphazide George C. Fortman, Burjor Captain and Carl D. Hoff pp 1808–1810 DOI: 10.1021/ic8024205 Supporting Info

Optical and Electrochemical Properties of Shell−Core Dendrimers: Ruthenium Coordination Complexes Capped with Sized Phenothiazine-substituted Bipyridines Linyong Zhu, Douglas Magde, James K. Whitesell and Marye Anne Fox pp 1811–1818 DOI: 10.1021/ic800965p

Network Structured SnO2/ZnO Heterojunction Nanocatalyst with High Photocatalytic Activity Lirong Zheng, Yuanhui Zheng, Chongqi Chen, Yingying Zhan, Xingyi Lin, Qi Zheng, Kemei Wei and Jiefang Zhu pp 1819–1825 DOI: 10.1021/ic802293p Supporting Info

Tetra-, Tri-, and Mononuclear Manganese(II/III) Complexes of a Phenol-Based N2O2 Capping Ligand: Use of Carboxylates as Ancillary Ligands in Tuning the Nuclearity of the Complexes Debdas Mandal, Pabitra Baran Chatterjee, Shubhajit Bhattacharya, Ki-Young Choi, Rodolphe Clrac and Muktimoy Chaudhury pp 1826–1835 DOI: 10.1021/ic801132r Supporting Info

An Efficient Homogeneous Intermolecular Rhenium-Based Photocatalytic System for the Production of H2 Benjamin Probst, Christoph Kolano, Peter Hamm and Roger Alberto pp 1836–1843 DOI: 10.1021/ic8013255 Supporting Info

pH-Specific Synthetic Chemistry and Solution Studies in the Binary System of Iron(III) with the α-Hydroxycarboxylate Substrate Quinic Acid: Potential Relevance to Iron Chemistry in Plant Fluids M. Menelaou, C. Mateescu, H. Zhao, I. Rodriguez-Escudero, N. Lalioti, Y. Sanakis, A. Simopoulos and A. Salifoglou pp 1844–1856 DOI: 10.1021/ic800356v Supporting Info

Tuning Through-Bond Fe(III)/Fe(II) Coupling by Solvent Manipulation of a Central Ruthenium Redox Couple Yu-Chen Lin, Wei-Tin Chen, Joe Tai, Denny Su, Sheng-Yi Huang, Ingrid Lin, Ju-Ling Lin, Mandy M. Lee, Mong Feng Chiou, Yen-Hsiang Liu, Ken-Shin Kwan, Yuan-Jang Chen and Hsing-Yin Chen pp 1857–1870 DOI: 10.1021/ic801271q Supporting Info

Mechanism of the Divanadium-Substituted Polyoxotungstate [γ-1,2-H2SiV2W10O40]4− Catalyzed Olefin Epoxidation by H2O2: A Computational Study Aleksey E. Kuznetsov, Yurii V. Geletii, Craig L. Hill, Keiji Morokuma and Djamaladdin G. Musaev pp 1871–1878 DOI: 10.1021/ic801372j Supporting Info

Oxidative Reactions of Tetrametal Pd(0)···Mo(II)Mo(II)···Pd(0) Clusters: Electrochemical Communication of Two Pd(0) Centers through the Mo2 Moiety and Oxidative Formation of a Pd(I)Mo(II)Mo(II)Pd(I) Array Kazushi Mashima, Asuka Shima, Keisuke Nakao, Atsushi Fukumoto, Yutaka Kaneda and Yoshitaka Kusumi pp 1879–1886 DOI: 10.1021/ic801398f Supporting Info

Consequences of N,C,N′- and C,N,N′-Coordination Modes on Electronic and Photophysical Properties of Cyclometalated Aryl Ruthenium(II) Complexes Sipke H. Wadman, Martin Lutz, Duncan M. Tooke, Anthony L. Spek, Frantiek Hartl, Remco W. A. Havenith, Gerard P. M. van Klink and Gerard van Koten pp 1887–1900 DOI: 10.1021/ic801595m Supporting Info

Homochiral Lanthanide Phosphonates with Brick-Wall-Shaped Layer Structures Showing Chiroptical and Catalytical Properties Xun-Gao Liu, Kai Zhou, Jia Dong, Cheng-Jian Zhu, Song-Song Bao and Li-Min Zheng pp 1901–1905 DOI: 10.1021/ic801689r Supporting Info

Photochemistry of SO2/Cl2/O2 Gas Mixtures: Synthesis of the New Peroxide ClSO2OOSO2Cl Rosana M. Romano, Carlos O. Della Vdova, Helmut Beckers and Helge Willner pp 1906–1910 DOI: 10.1021/ic802143p Supporting Info

Hydrogen Polyphosphides P3H23− and P3H32−: Synthesis and Crystal Structure of K3(P3H2)·2.3NH3, Rb3(P3H2)·NH3, [Rb(18-crown-6)]2(P3H3)·7.5NH3, and [Cs(18-crown-6)]2(P3H3)·7NH3 Florian Kraus, Jrgen C. Aschenbrenner, T. Klamroth and Nikolaus Korber pp 1911–1919 DOI: 10.1021/ic8014546 Supporting Info

Stability of [2]Pseudorotaxanes Templated Through Second-Sphere Coordination Barry A. Blight, James A. Wisner and Michael C. Jennings pp 1920–1927 DOI: 10.1021/ic801725u Supporting Info

Matrix Effects on the Triplet State of the OLED Emitter Ir(4,6-dFppy)2(pic) (FIrpic): Investigations by High-Resolution Optical Spectroscopy Andreas F. Rausch, Mark E. Thompson and Hartmut Yersin pp 1928–1937 DOI: 10.1021/ic801250g

77Se NMR Spectroscopic, DFT MO, and VBT Investigations of the Reversible Dissociation of Solid (Se6I2)[AsF6]2·2SO2 in Liquid SO2 to Solutions Containing 1,4-Se6I22+ in Equilibrium with Sen2+ (n = 4, 8, 10) and Seven Binary Selenium Iodine Cations: Preliminary Evidence for 1,1,4,4-Se4Br42+ and cyclo-Se7Br+ Scott Brownridge, Larry Calhoun, H. Donald B. Jenkins, Risto S. Laitinen, Michael P. Murchie, Jack Passmore, Jarkko Pietikinen, J.Mikko Rautiainen, Jeremy C.P. Sanders, Gary J. Schrobilgen, Reijo J. Suontamo, Heikki M. Tuononen, Jussi U. Valkonen and Chi- Ming Wong pp 1938–1959 DOI: 10.1021/ic8015673 Supporting Info

Synthesis and Characterization of TpiPrMoO(S2PR2) (R = Pri, Ph, OEt, OPri, (−)-Mentholate) and {HB(OMe)(Pripz)2}MoO(S2PPri2), Including Isomers of Known 1,2-Borotropically-Shifted Complexes Charles G. Young, Michael S. Malarek, David J. Evans, Christian J. Doonan, Victor Wee Lin Ng and Jonathan M. White pp 1960–1966 DOI: 10.1021/ic8015518 Supporting Info

Observation of the Ammonium Salt of 12-Molybdophosphoric Acid by in Situ Raman Spectroscopy during Solid-State Synthesis: Spectral Analysis and Reconstruction Using the Band-Target Entropy Minimization (BTEM) Algorithm Chilukoti Srilakshmi, Wee Chew, Kanaparthi Ramesh and Marc Garland pp 1967–1973 DOI: 10.1021/ic801609d

Iron Carbonyl Thiocarbonyls: Effect of Substituting a Thiocarbonyl Group for a Carbonyl Group in Mononuclear and Binuclear Iron Carbonyl Derivatives Zhong Zhang, Qian-shu Li, Yaoming Xie, R. Bruce King and Henry F. Schaefer, III pp 1974–1988 DOI: 10.1021/ic8016276 Supporting Info

Design Considerations for a System for Photocatalytic Hydrogen Production from Water Employing Mixed-Metal Photochemical Molecular Devices for Photoinitiated Electron Collection Shamindri M. Arachchige, Jared R. Brown, Eric Chang, Avijita Jain, David F. Zigler, Krishnan Rangan and Karen J. Brewer pp 1989–2000 DOI: 10.1021/ic8017387 Supporting Info

Investigating Metal Size Effects in the Ln2(μ-η2:η2-N2) Reduction System: Reductive Reactivity with Complexes of the Largest and Smallest Trivalent Lanthanide Ions, La3+ and Lu3+ William J. Evans, Sara E. Lorenz and Joseph W. Ziller pp 2001–2009 DOI: 10.1021/ic801853d Supporting Info

Lanthanide−Organic Cation Frameworks with Zeolite Gismondine Topology and Large Cavities from Intersected Channels Templated by Polyoxometalate Counterions Chun-Hong Li, Kun-Lin Huang, Ying-Nan Chi, Xi Liu, Zhan-Gang Han, Long Shen and Chang-Wen Hu pp 2010–2017 DOI: 10.1021/ic801846h Supporting Info

Synthesis and Characterization of Ruthenium bis-Bipyridine Mono- and Disulfinato Complexes Rowshan Ara Begum, Abdiaziz A. Farah, Howard N. Hunter and A. B. P. Lever pp 2018–2027 DOI: 10.1021/ic801898t Supporting Info

Spin-Frustrated Complex, [FeIIFeIII(trans-1,4-cyclohexanedicarboxylate)1.5]∞: Interplay between Single-Chain Magnetic Behavior and Magnetic Ordering Yan-Zhen Zheng, Wei Xue, Wei-Xiong Zhang, Ming-Liang Tong, Xiao-Ming Chen, Fernande Grandjean, Gary J. Long, Seik-Weng Ng, Pierre Panissod and Marc Drillon pp 2028–2042 DOI: 10.1021/ic8019155 Supporting Info

Isoreticular Metal-Organic Polyhedral Networks Based on 5-Connecting Paddlewheel Motifs Hyungphil Chun, Heejin Jung and Jinwoo Seo pp 2043–2047 DOI: 10.1021/ic801784j Supporting Info

Conformational and Isomeric Preferences of Six-Membered Inorganic Heterocycles [EtNP(E)(OR)]3 (E = Lone Pair, O, S, or Se): A Synthetic, Spectroscopic, Structural, and Computational Study Ramaswamy Murugavel, Ganesan Prabusankar, Ashish Sharma, Raghavan B. Sunoj and Ray J. Butcher pp 2048–2059 DOI: 10.1021/ic801945q Supporting Info

Novel Types of Tetra-, Hexa-, Octa-, and Dodecanuclear Silver Clusters Containing (2,7-Di-tert-butylfluoren-9-ylidene)methanedithiolate Jos Vicente, Pablo Gonzlez-Herrero, Yolanda Garca-Snchez and Peter G. Jones pp 2060–2071 DOI: 10.1021/ic802045j Supporting Info

Microporous Lanthanide Metal-Organic Frameworks Containing Coordinatively Linked Interpenetration: Syntheses, Gas Adsorption Studies, Thermal Stability Analysis, and Photoluminescence Investigation Shengqian Ma, Daqiang Yuan, Xi-Sen Wang and Hong-Cai Zhou pp 2072–2077 DOI: 10.1021/ic801948z Supporting Info

Structural, Spectroscopic, and Kinetic Investigation of the Molybdenum Dialkylhydrazido Complexes [MoBr(NNC5H10)(dppe)2]Br and [Mo(NNC5H10)(dppe)2]: Activation Parameters and Revised Mechanism for N−N Cleavage Ameli Dreher, Klaus Mersmann, Christian Nther, Ivana Ivanovic-Burmazovic, Rudi van Eldik and Felix Tuczek pp 2078–2093 DOI: 10.1021/ic801952v Supporting Info

Intensely Luminescent Alkynyl−Phosphine Gold(I)−Copper(I) Complexes: Synthesis, Characterization, Photophysical, and Computational Studies Igor O. Koshevoy, Yi-Chih Lin, Antti J. Karttunen, Pi-Tai Chou, Pirjo Vainiotalo, Sergey P. Tunik, Matti Haukka and Tapani A. Pakkanen pp 2094–2102 DOI: 10.1021/ic801987t Supporting Info

Synthesis, Structures, and Properties of Mixed Dithiolene-Carbonyl and Dithiolene-Phosphine Complexes of Tungsten P. Chandrasekaran, Kuppuswamy Arumugam, Upul Jayarathne, Lisa M. Prez, Joel T. Mague and James P. Donahue pp 2103–2113 DOI: 10.1021/ic802016b Supporting Info

What a Difference a 5f Element Makes: Trivalent and Tetravalent Uranium Halide Complexes Supported by One and Two Bis[2-(diisopropylphosphino)-4-methylphenyl]amido (PNP) Ligands Thibault Cantat, Brian L. Scott, David E. Morris and Jaqueline L. Kiplinger pp 2114–2127 DOI: 10.1021/ic802061x Supporting Info

Two-Step Spin-Transition Iron(III) Compound with a Wide [High Spin-Low Spin] Plateau Jinkui Tang, Jos Snchez Costa, Simon Smulders, Gbor Molnr, Azzedine Bousseksou, Simon J. Teat, Yangguang Li, Gerard A. van Albada, Patrick Gamez and Jan Reedijk pp 2128–2135 DOI: 10.1021/ic801973x Supporting Info

Thermochromic Phase Transition on CuMo0.9W0.1O4@SiO2 Core−Shell Particles M. Gaudon, B. Basly, Y. Fauque, J. Majimel and M. H. Delville pp 2136–2139 DOI: 10.1021/ic802057c Supporting Info

Two Homometallic Antiferromagnets Based on Oxalato-Bridged Honeycomb Assemblies: (A)2[MII2(C2O4)3] (A = Ammonium Salt Derived from Diethylenetriamine; MII = Fe2+, Co2+) Zhiming Duan, Yan Zhang, Bin Zhang and Francis L. Pratt pp 2140–2146 DOI: 10.1021/ic8021003 Supporting Info

From Neutral to Anionic η1-Carbon Ligands: Experimental Synthesis and Theoretical Analysis of a Rhodium−Yldiide Complex Remigiusz Zurawinski, Christine Lepetit, Yves Canac, Marian Mikolajczyk and Remi Chauvin pp 2147–2155 DOI: 10.1021/ic802104f Supporting Info

One-Electron Oxidation of Ruthenocene: Reactions of the Ruthenocenium Ion in Gentle Electrolyte Media Jannie C. Swarts, Ayman Nafady, John H. Roudebush, Sabrina Trupia and William E. Geiger pp 2156–2165 DOI: 10.1021/ic802105b

Crystal Structure Solid-State Cross Polarization Magic Angle Spinning 13C NMR Correlation in Luminescent d10 Metal-Organic Frameworks Constructed with the 1,2-Bis(1,2,4-triazol-4-yl)ethane Ligand Hesham A. Habib, Anke Hoffmann, Henning A. Hppe, Gunther Steinfeld and Christoph Janiak pp 2166–2180 DOI: 10.1021/ic802069k Supporting Info

Controlled Synthesis, Characterization, and Morphology-Dependent Reducibility of Ceria−Zirconia−Yttria Solid Solutions with Nanorod-like, Microspherical, Microbowknot-like, and Micro-octahedral Shapes Yujuan Zhang, Lei Zhang, Jiguang Deng, Hongxing Dai and Hong He pp 2181–2192 DOI: 10.1021/ic802195j Supporting Info

Ln3Pb3(IO3)13(μ3−O) (Ln = La−Nd): New Types of Second-Order Nonlinear Optical Materials Containing Two Types of Lone Pair Cations Ting Hu, Li Qin, Fang Kong, Yong Zhou and Jiang-Gao Mao pp 2193–2199 DOI: 10.1021/ic8022375 Supporting Info

Characterization of Chemical Speciation of Titanyl Sulfate Solutions for Production of Titanium Dioxide Precipitates Istvn Szilgyi, Erich Knigsberger and Peter M. May pp 2200–2204 DOI: 10.1021/ic801722r Supporting Info

Metal Complexes of a Picolinate-Based Nitronyl Nitroxide Free Radical Eugenio Coronado, Carlos Gimnez-Saiz, Francisco M. Romero and Ana Tarazn pp 2205–2214 DOI: 10.1021/ic802218j Supporting Info

Synthesis and Reactions of Mono- and Dinuclear Ni(I) Thiolate Complexes Mikinao Ito, Tsuyoshi Matsumoto and Kazuyuki Tatsumi pp 2215–2223 DOI: 10.1021/ic802276w Supporting Info

Determination of the Metal−Dithiolate Fold Angle in Mononuclear Molybdenum(V) Centers by EPR Spectroscopy Simon C. Drew and Graeme R. Hanson pp 2224–2232 DOI: 10.1021/ic802343f Supporting Info

New Antimony(III) Bromide Complexes with Thioamides: Synthesis, Characterization, and Cytostatic Properties Ibrahim I. Ozturk, Sotiris K. Hadjikakou, Nick Hadjiliadis, Nikolaos Kourkoumelis, Maciej Kubicki, Anastasios J. Tasiopoulos, Hanadi Scleiman, Mirela M. Barsan, Ian S. Butler and Jan Balzarini pp 2233–2245 DOI: 10.1021/ic8019205

Iron(0) and Ruthenium(0) Complexes of Dinitrogen Leslie D. Field, Ruth W. Guest, Khuong Q. Vuong, Scott J. Dalgarno and Paul Jensen pp 2246–2253 DOI: 10.1021/ic8019827 Supporting Info

Ferromagnetic Superexchange Coupling through a Diamagnetic Iron(II) Ion in a Mixed-Valent Iron(III, II, III) meso-Helicate Toshihide Mochizuki, Takashi Nogami and Takayuki Ishida pp 2254–2259 DOI: 10.1021/ic8020589 Supporting Info

Concerted Dismutation of Chlorite Ion: Water-Soluble Iron-Porphyrins As First Generation Model Complexes for Chlorite Dismutase Michael J. Zdilla, Amanda Q. Lee and Mahdi M. Abu-Omar pp 2260–2268 DOI: 10.1021/ic801681n Supporting Info

Characterization of cis- and trans-HSSOH via Rotational Spectroscopy and Quantum-Chemical Calculations Monika Koerber, Oliver Baum, Thomas F. Giesen, Stephan Schlemmer, Josef Hahn and Jrgen Gauss pp 2269–2272 DOI: 10.1021/ic802076f

Preparation and Structural Characterization of Molecular Al−O−Sn(II) and Al−O−Sn(IV) Compounds Sharanappa Nembenna, Sanjay Singh, Anukul Jana, Herbert W. Roesky, Ying Yang, Hongqi Ye, Holger Ott and Dietmar Stalke pp 2273–2276 DOI: 10.1021/ic802151c Supporting Info

CeAsSeSynthesis, Crystal Structure, and Physical Properties A. Schlechte, R. Niewa, Yu. Prots, W. Schnelle, M. Schmidt and R. Kniep pp 2277–2284 DOI: 10.1021/ic802246g Supporting Info

Pressure-Induced Transformation of 6H Hexagonal to 3C Perovskite Structure in PbMnO3 Kengo Oka, Masaki Azuma, Shigeto Hirai, Alexei A. Belik, Hiroshi Kojitani, Masaki Akaogi, Mikio Takano and Yuich Shimakawa pp 2285–2288 DOI: 10.1021/ic802081f

Structural Tungsten-Imido Chemistry: The Gas-Phase Structure of W(NBut)2(NHBut)2 and the Solid-State Structures of Novel Heterobimetallic W/N/M (M = Rh, Pd, Zn) Species Hamid Choujaa, Samuel D. Cosham, Andrew L. Johnson, Graeme R. Kafka, Mary F. Mahon, Sarah L. Masters, Kieran C. Molloy, David W. H. Rankin, Heather E. Robertson and Derek A. Wann pp 2289–2299 DOI: 10.1021/ic8021134 Supporting Info

Substrate Binding Preferences and pKa Determinations of a Nitrile Hydratase Model Complex: Variable Solvent Coordination to [(bmmp-TASN)Fe]OTf Martin G. O’Toole, Brian Bennett, Mark S. Mashuta and Craig A. Grapperhaus pp 2300–2308 DOI: 10.1021/ic802180d Supporting Info

The First Octahedral Cluster Complexes With Terminal Formate Ligands: Synthesis, Structure, and Properties of K4[Re6S8(HCOO)6] and Cs4[Re6S8(HCOO)6] Konstantin A. Brylev, Yuri V. Mironov, Svetlana G. Kozlova, Vladimir E. Fedorov, Sung-Jin Kim, Hans-Jrgen Pietzsch, Holger Stephan, Akitaka Ito, Shoji Ishizaka and Noboru Kitamura pp 2309–2315 DOI: 10.1021/ic802178q Supporting Info

A 13C and 15N Solid-State NMR Study of Structural Disorder and Aurophilic Bonding in AuI and AuIII Cyanide Complexes Kristopher J. Harris and Roderick E. Wasylishen pp 2316–2332 DOI: 10.1021/ic8022198

Mechanochemical Synthesis of Alkaline Earth Carbides and Intercalation Compounds Sandra M. Hick, Carolin Griebel and Richard G. Blair pp 2333–2338 DOI: 10.1021/ic8022437

Issue 6

Simple Ligand Modifications as a Key to Playing with the Stability of Cu(I), Cu(II), and Cu(III) Organometallic Complexes Albert Poater and Luigi Cavallo pp 2340–2342 DOI: 10.1021/ic8020063 Supporting Info

Interaction of Transuranium Elements with Biologically Important Ligands: Structural and Spectroscopic Evidence for Nucleotide Coordination to Plutonium Grigory Andreev, Nina Budantseva, Marina Sokolova, Ivan Tananaev and Boris Myasoedov pp 2343–2345 DOI: 10.1021/ic802053s Supporting Info

Expanding the Crystal Chemistry of Actinyl Peroxides: μ-η2:η1 Peroxide Coordination in Trimers of U6+ Polyhedra Daniel K. Unruh, Alicia Burtner and Peter C. Burns pp 2346–2348 DOI: 10.1021/ic8024217 Supporting Info

Zirconocene−Iridium Hydrido Complexes: Arene Carbon−Hydrogen Bond Activation and Formation of a Planar Square Zr2Ir2 Complex Masataka Oishi and Hiroharu Suzuki pp 2349–2351 DOI: 10.1021/ic8020113 Supporting Info

Ligand-Based Neutral Ruthenium(II) Arene Complex: Selective Anticancer Action Chun-Hui Wu, De-Hong Wu, Xuan Liu, Gulnisa Guoyiqibayi, Da-Dong Guo, Gang Lv, Xue-Mei Wang, Hong Yan, Hui Jiang and Zu-Hong Lu pp 2352–2354 DOI: 10.1021/ic900009j Supporting Info

Redox Isomerism in the Lanthanide Complex [(dpp-Bian)Yb(DME)(μ-Br)]2 (dpp-Bian = 1,2-Bis[(2,6-diisopropylphenyl)imino]acenaphthene) Igor L. Fedushkin, Olga V. Maslova, Eugeny V. Baranov and Andrei S. Shavyrin pp 2355–2357 DOI: 10.1021/ic900022s Supporting Info

A Dithiolate-Bridged (CN)2(CO)Fe−Ni Complex Reproducing the IR Bands of [NiFe] Hydrogenase Soichiro Tanino, Zilong Li, Yasuhiro Ohki and Kazuyuki Tatsumi pp 2358–2360 DOI: 10.1021/ic900017s Supporting Info

C−H Bond Amination from a Ferrous Dipyrromethene Complex Evan R. King and Theodore A. Betley pp 2361–2363 DOI: 10.1021/ic900219b Supporting Info

Solvent-Assisted Formation of Vesicles by a Self-Assembling Ni3−Schiff Base Complex Pampa Mukherjee, Michael G. B. Drew and Ashutosh Ghosh pp 2364–2370 DOI: 10.1021/ic801889a Supporting Info

Monovalent K, Cs, Tl, and Ag Nitrosodicyanomethanides: Completely Different 3D Networks with Useful Properties of Luminescent Materials and Nonelectric Sensors for Gases Garrett Glover, Nikolay Gerasimchuk, Richard Biagioni and Konstantin V. Domasevitch pp 2371–2382 DOI: 10.1021/ic801364w Supporting Info

Controlled Reversible Immobilization of Ru Carbene on Single-Walled Carbon Nanotubes: A New Strategy for Green Catalytic Systems Based on a Solvent Effect on π−π Interaction Guiyan Liu, Bin Wu, Jianzheng Zhang, Xiaoli Wang, Mingbo Shao and Jianhui Wang pp 2383–2390 DOI: 10.1021/ic801111h Supporting Info

Anion Binding by Protonated Forms of the Tripodal Ligand Tren Carla Bazzicalupi, Andrea Bencini, Antonio Bianchi, Andrea Danesi, Claudia Giorgi and Barbara Valtancoli pp 2391–2398 DOI: 10.1021/ic8013128 Supporting Info

Structural Versatility of the ε-SmGax Phase: X-Ray, Electron Diffraction, and DFT Studies Monique Tillard, David Zitoun and Claude Belin pp 2399–2406 DOI: 10.1021/ic801379c Supporting Info

Influence of Alkoxyl Substituent on 4,6-Diphenyl-2,2′-bipyridine Ligand on Photophysics of Cyclometalated Platinum(II) Complexes: Admixing Intraligand Charge Transfer Character in Low-Lying Excited States Pin Shao, Yunjing Li, Alexander Azenkeng, Mark R. Hoffmann and Wenfang Sun pp 2407–2419 DOI: 10.1021/ic801589q Supporting Info

Platinum(II) Terpyridyl-Acetylide Dyads and Triads with Nitrophenyl Acceptors via a Convenient Synthesis of a Boronated Phenylterpyridine Paul Jarosz, Kenneth Lotito, Jacob Schneider, Duraisamy Kumaresan, Russell Schmehl and Richard Eisenberg pp 2420–2428 DOI: 10.1021/ic801769v

Homogeneous Catalytic Dehydrogenation/Dehydrocoupling of Amine-Borane Adducts by the Rh(I) Wilkinson’s Complex Analogue RhCl(PHCy2)3 (Cy = cyclohexyl) Matthew E. Sloan, Timothy J. Clark and Ian Manners pp 2429–2435 DOI: 10.1021/ic801752k Supporting Info

Three-Dimensional Metal-Organic Frameworks Based on Functionalized Tetracarboxylate Linkers: Synthesis, Strucures, and Gas Sorption Studies Shuting Wu, Liqing Ma, La-Sheng Long, Lan-Sun Zheng and Wenbin Lin pp 2436–2442 DOI: 10.1021/ic801631w Supporting Info

Spin-State Crossover with Structural Changes in a Cobalt(II) Organometallic Species: Low-Coordinate, First Row, Heteroleptic Amido Transition Metal Aryls. Synthesis and Characterization of Ar′MN(H)Ar# (M = Mn, Fe, Co) (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2, Ar# = C6H3-2,6-(C6H2-2,4,6-Me3)2) Chengbao Ni, James C. Fettinger, Gary J. Long and Philip P. Power pp 2443–2448 DOI: 10.1021/ic801660a Supporting Info

A Synthetic Model for the Inhibition of Glutathione Peroxidase by Antiarthritic Gold Compounds Krishna P. Bhabak and Govindasamy Mugesh pp 2449–2455 DOI: 10.1021/ic8019183 Supporting Info

Copper(II) Dinuclear Pyrazine-Based Rack-Type Complexes: Preparation, Structure, and Magnetic Properties Juan Ramrez, Adrian-Mihail Stadler, Guillaume Rogez, Marc Drillon and Jean-Marie Lehn pp 2456–2463 DOI: 10.1021/ic801675d Supporting Info

N−H and N=C Bond Formation via Germanium(III) Diradicaloid Intermediates and C−S Bond Cleavage in Reactions of the Digermyne Ar′GeGeAr′ (Ar′ = C6H3-2,6-(C6H3-2,6-Pri2)2) with Azides Xinping Wang, Chengbao Ni, Zhongliang Zhu, James C. Fettinger and Philip P. Power pp 2464–2470 DOI: 10.1021/ic801713v Supporting Info

Facile Modification of 1,3,5-Triaza-7-phosphatricyclo[3.3.1.13,7]decane Phosphanes Coordinated to Ruthenium(II) Almudena García-Fernndez, Josefina Díez, M. Pilar Gamasa and Elena Lastra pp 2471–2481 DOI: 10.1021/ic801710y Supporting Info

Tuning the Structure and Magnetism of Azido-Mediated CuII Systems by Coligand Modifications Jiong-Peng Zhao, Bo-Wen Hu, E. C. Saudo, Qian Yang, Yong-Fei Zeng and Xian-He Bu pp 2482–2489 DOI: 10.1021/ic802066a Supporting Info

Thermotropic Ruthenium(II)-Containing Metallomesogens Based on Substituted 1,10-Phenanthroline Ligands Thomas Cardinaels, Jan Ramaekers, Kris Driesen, Peter Nockemann, Kristof Van Hecke, Luc Van Meervelt, Bart Goderis and Koen Binnemans pp 2490–2499 DOI: 10.1021/ic801772q Supporting Info

Intramolecular Phosphine−Phosphine Donor−Acceptor Complexes Piotr Wawrzyniak, Amy L. Fuller, Alexandra M. Z. Slawin and Petr Kilian pp 2500–2506 DOI: 10.1021/ic801833a Supporting Info

Dinitrogen Complexes Supported by Tris(phosphino)silyl Ligands Matthew T. Whited, Neal P. Mankad, Yunho Lee, Paul F. Oblad and Jonas C. Peters pp 2507–2517 DOI: 10.1021/ic801855y Supporting Info

Structural Variety of Alkali Metal Compounds Containing P−E−M (E = S, Se; M = Li, Na, K) Units Derived from Nitrogen Rich Heterocycles Jhon A. Balanta-Daz, Mnica Moya-Cabrera, Vojtech Jancik, Leslie W. Pineda-Cedeo, Rubn A. Toscano and Raymundo Cea-Olivares pp 2518–2525 DOI: 10.1021/ic801950q Supporting Info

Eu3Co2In15 and KM2In9 (M = Co, Ni): 3D Frameworks Based on Transition Metal Centered In9 Clusters Xiao-Wu Lei, Guo-Hua Zhong, Long-Hua Li, Chun-Li Hu, Min-Jie Li and Jiang-Gao Mao pp 2526–2533 DOI: 10.1021/ic8019765 Supporting Info

Synthesis of Bis(phosphinoferrocenyl) Copper Complexes from Zwitterionic Quinonoid Ligands and Their Structural and Redox Properties Pierre Braunstein, Denis Bubrin and Biprajit Sarkar pp 2534–2540 DOI: 10.1021/ic802042w Supporting Info

Supra-Nanosecond Dynamics of a Red-to-Blue Photon Upconversion System Tanya N. Singh-Rachford and Felix N. Castellano pp 2541–2548 DOI: 10.1021/ic802114d Supporting Info

Structural, Spectroscopic, and Thermodynamic Consequences of Anti-Chelate Effect in Nine-Coordinate Lanthanide Podates Patrick E. Ryan, Laure Gune, Gabriel Canard, Frdric Gumy, Jean-Claude G. Bnzli and Claude Piguet pp 2549–2560 DOI: 10.1021/ic802130z Supporting Info

Scandium SALEN Complexes Bearing Chloro, Aryloxo, and Hydroxo Ligands Christian Meermann, Karl W. Trnroos and Reiner Anwander pp 2561–2570 DOI: 10.1021/ic802082b Supporting Info

Catalytic Activity of Biscobalt Porphyrin-Corrole Dyads Toward the Reduction of Dioxygen Karl M. Kadish, Laurent Frmond, Jing Shen, Ping Chen, Kei Ohkubo, Shunichi Fukuzumi, Maya El Ojaimi, Claude P. Gros, Jean-Michel Barbe and Roger Guilard pp 2571–2582 DOI: 10.1021/ic802092n

A Novel Reactivity Mode for Metal-Activated Dialkylcyanamide Species: Addition of N,N′-Diphenylguanidine to a cis-(R2NCN)2PtII Center Giving an Eight-Membered Chelated Platinaguanidine Pavel V. Gushchin, Maxim L. Kuznetsov, Matti Haukka, Meng-Jiy Wang, Aleksander V. Gribanov and Vadim Yu. Kukushkin pp 2583–2592 DOI: 10.1021/ic802109d Supporting Info

Electrochemical and Chemical Oxidation of [Pt2(μ-pyrophosphite)4]4− Revisited: Characterization of a Nitrosyl Derivative, [Pt2(μ-pyrophosphite)4(NO)]3− Martin A. Bennett, Suresh K. Bhargava, Alan M. Bond, Vipul Bansal, Craig M. Forsyth, Si-Xuan Guo and Steven H. Privr pp 2593–2604 DOI: 10.1021/ic802213v Supporting Info

Self-Assembled Pd(II) Metallocycles Using an Ambidentate Donor and the Study of Square−Triangle Equilibria Sushobhan Ghosh and Partha Sarathi Mukherjee pp 2605–2613 DOI: 10.1021/ic802254f Supporting Info

Effect of Imidazole and Phenolate Axial Ligands on the Electronic Structure and Reactivity of Oxoiron(IV) Porphyrin π-Cation Radical Complexes: Drastic Increase in Oxo-Transfer and Hydrogen Abstraction Reactivities Akihiro Takahashi, Takuya Kurahashi and Hiroshi Fujii pp 2614–2625 DOI: 10.1021/ic802123m Supporting Info

Electron Paramagnetic Resonance and Electron Nuclear Double Resonance Investigation of the Diradical Bis(α-iminopyridinato)zinc Complex Maurice van Gastel, Connie C. Lu, Karl Wieghardt and Wolfgang Lubitz pp 2626–2632 DOI: 10.1021/ic802131w Supporting Info

Intramolecular Hydrogen-Bonded Tertiary Phosphines as 1,3,5-Triaza-7-phosphaadamantane (PTA) Analogues Allen T. Ekubo, Mark R. J. Elsegood, Andrew J. Lake and Martin B. Smith pp 2633–2638 DOI: 10.1021/ic801709z Supporting Info

Interactions of a Cationic Mercury(II) Thiolate Complex [Hg(Tab)2](PF6)2 with N-Donor Ligands Xiao-Yan Tang, Rong-Xin Yuan, Zhi-Gang Ren, Hong-Xi Li, Yong Zhang and Jian-Ping Lang pp 2639–2651 DOI: 10.1021/ic8021744 Supporting Info

An Iron Complex of Dipyridophenazine as a Potent Photocytotoxic Agent in Visible Light Sounik Saha, Ritankar Majumdar, Mithun Roy, Rajan R. Dighe and Akhil R. Chakravarty pp 2652–2663 DOI: 10.1021/ic8022612 Supporting Info

Conjugation of Selenophene with Bipyridine for a High Molar Extinction Coefficient Sensitizer in Dye-Sensitized Solar Cells Feifei Gao, Yueming Cheng, Qingjiang Yu, Shi Liu, Dong Shi, Yunhui Li and Peng Wang pp 2664–2669 DOI: 10.1021/ic802289e Supporting Info

Ground- and Excited-State Dynamics of Aluminum and Gallium Corroles Dorota Kowalska, Xia Liu, Umakanta Tripathy, Atif Mahammed, Zeev Gross, Satoshi Hirayama and Ronald P. Steer pp 2670–2676 DOI: 10.1021/ic900056n Supporting Info

Monocationic Trihydride and Dicationic Dihydride−Dihydrogen and Bis(dihydrogen) Osmium Complexes Containing Cyclic and Acyclic Triamine Ligands: Influence of the N−Os−N Angles on the Hydrogen−Hydrogen Interactions Miguel Baya, Miguel A. Esteruelas, Montserrat Olivn and Enrique Oate pp 2677–2686 DOI: 10.1021/ic8023259 Supporting Info

Magnetic Properties and Magnetic Structure of CuII3MoVI2O9 Serge Vilminot, Gilles Andr and Mohamedally Kurmoo pp 2687–2692 DOI: 10.1021/ic802410p Supporting Info

Uranium(VI) Bis(imido) Chalcogenate Complexes: Synthesis and Density Functional Theory Analysis Liam P. Spencer, Ping Yang, Brian L. Scott, Enrique R. Batista and James M. Boncella pp 2693–2700 DOI: 10.1021/ic802212m Supporting Info

Synthesis and Characterization of Group 11 1,1,3,3-Tetraalkylguanidinate (TAG) Clusters: [M2(μ-TAG){μ-N(SiMe3)2}]2 (M = Cu, Ag, and Au) Scott D. Bunge and Jennifer L. Steele pp 2701–2706 DOI: 10.1021/ic802291u Supporting Info

Issue 7

Monomers and Polymers of Tripalladium(0) Ditropylium Halides Frank L. Mulligan, Dominic C. Babbini, Isaac R. Davis, Stephanie K. Hurst and Gary S. Nichol pp 2708–2710 DOI: 10.1021/ic8014578 Supporting Info

Mononuclear CuII−Phenolate Bioinspired Complex is Catalytically Promiscuous: Phosphodiester and Peptide Amide Bond Cleavage Mauricio C. Bof Oliveira, Deise Mazera, Marciela Scarpellini, Patricia Cardoso Severino, Ademir Neves and Hernn Terenzi pp 2711–2713 DOI: 10.1021/ic802208v Supporting Info

A Helicoid Ferrocene Zeferino Gomez-Sandoval, Eduardo Pea, Clia Fonseca Guerra, F. Matthias Bickelhaupt, Miguel Angel Mendez-Rojas and Gabriel Merino pp 2714–2716 DOI: 10.1021/ic8024638

A New Dinuclear Ruthenium Complex as an Efficient Water Oxidation Catalyst Yunhua Xu, Torbjrn Åkermark, Viktor Gyollai, Dapeng Zou, Lars Eriksson, Lele Duan, Rong Zhang, Bjrn Åkermark and Licheng Sun pp 2717–2719 DOI: 10.1021/ic802052u Supporting Info

From Superatomic Au25(SR)18− to Superatomic M@Au24(SR)18q Core−Shell Clusters De-en Jiang and Sheng Dai pp 2720–2722 DOI: 10.1021/ic8024588 Supporting Info

A Chiral Luminescent Coordination Polymer Featuring a Unique 4-Connected Self-Catenated Topology Built from Helical Motifs Eric Shyu, Ronald M. Supkowski and Robert L. LaDuca pp 2723–2725 DOI: 10.1021/ic900241q Supporting Info

Control of Protein Oligomerization Symmetry by Metal Coordination: C2 and C3 Symmetrical Assemblies through CuII and NiII Coordination Eric N. Salgado, Richard A. Lewis, Susanne Mossin, Arnold L. Rheingold and F. Akif Tezcan pp 2726–2728 DOI: 10.1021/ic9001237 Supporting Info

K2Ln2As2Se9 (Ln = Sm, Gd): The First Quaternary Rare-Earth Selenoarsenate Compounds with a 3D Framework Containing Chairlike As2Se4 Units Yuandong Wu and Wolfgang Bensch pp 2729–2731 DOI: 10.1021/ic802368j Supporting Info

Uranyl Diphosphonates with Pillared Structures Pius O. Adelani and Thomas E. Albrecht-Schmitt pp 2732–2734 DOI: 10.1021/ic900172s Supporting Info

Mssbauer, Electron Paramagnetic Resonance, and Theoretical Studies of a Carbene-Based All-Ferrous Fe4S4 Cluster: Electronic Origin and Structural Identification of the Unique Spectroscopic Site Mrinmoy Chakrabarti, Liang Deng, R. H. Holm, Eckard Mnck and Emile L. Bominaar pp 2735–2747 DOI: 10.1021/ic802192w Supporting Info

Linear MEMe Versus Bent MEMe: Bonding Analysis in Heavier Metal-ylidyne Complexes [(Cp)(CO)2MEMe] and Metallo-ylidenes [(Cp)(CO)3M−EMe] (M = Cr, Mo, W; E = Si, Ge, Sn, Pb) Krishna K. Pandey and Agust Lleds pp 2748–2759 DOI: 10.1021/ic801072g Supporting Info

trans-Dichloro-bis-(arylazoimidazole)palladium(II): Synthesis, Structure, Photoisomerization, and DFT Calculation P. Pratihar, T. K. Mondal, A. K. Patra and C. Sinha pp 2760–2769 DOI: 10.1021/ic8012365

Copper(II) Interaction with Mono-, Bis- and Tris-Ring N3O2 Macrocycles: Synthetic, X-ray, Competitive Membrane Transport, and Hypochromic Shift Studies Joobeom Seo, Sunhong Park, Shim Sung Lee, Marina Fainerman-Melnikova and Leonard F. Lindoy pp 2770–2779 DOI: 10.1021/ic801265y Supporting Info

Chemical Issues Addressing the Construction of the Distal Ni[Cysteine-Glycine-Cysteine]2− Site of Acetyl CoA Synthase: Why Not Copper? Kayla N. Green, Scott M. Brothers, Boram Lee, Marcetta Y. Darensbourg and David A. Rockcliffe pp 2780–2792 DOI: 10.1021/ic801628r Supporting Info

Engineering New Metal-Organic Frameworks Built from Flexible Tetrapyridines Coordinated to Cu(II) and Cu(I) Patrick E. Ryan, Christophe Lescop, Dominic Lalibert, Tamara Hamilton, Thierry Maris and James D. Wuest pp 2793–2807 DOI: 10.1021/ic8019809 Supporting Info

Monomeric, Dimeric and Polymeric W/Cu/S Clusters Based on [Et4N][Tp*W(μ3-S)3(CuBr)3] and Various Nitrogen Donor Ligands Zhen-Hong Wei, Hong-Xi Li, Mei-Ling Cheng, Xiao-Yan Tang, Yang Chen, Yong Zhang and Jian-Ping Lang pp 2808–2817 DOI: 10.1021/ic8019342 Supporting Info

Contrasts between the Vibronic Contributions in the tris-(2,2′-bipyridyl)Osmium(II) Emission Spectrum and the Implications of Resonance-Raman Parameters Onduru S. Ondongo and John F. Endicott pp 2818–2829 DOI: 10.1021/ic801512g Supporting Info

Binding of 4-(N,N-dimethylamino)pyridine to Salen- and Salan-Cr(III) Cations: A Mechanistic Understanding on the Difference in Their Catalytic Activity for CO2/Epoxide Copolymerization Dun-Yan Rao, Bo Li, Rong Zhang, Hui Wang and Xiao-Bing Lu pp 2830–2836 DOI: 10.1021/ic802384x Supporting Info

An Unprecedented Family of Lanthanide-Containing Coordination Polymers with Highly Tunable Emission Properties N. Kerbellec, D. Kustaryono, V. Haquin, M. Etienne, C. Daiguebonne and O. Guillou pp 2837–2843 DOI: 10.1021/ic801616y

Theoretical Studies on Metal−Metal Interaction, Excited States, and Spectroscopic Properties of Binuclear Au−Au, Au−Rh, and Rh−Rh Complexes with Diphosphine Ligands: Buildup of Complexity from Monomers to Dimers Qing-Jiang Pan, Xin Zhou, Yuan-Ru Guo, Hong-Gang Fu and Hong-Xing Zhang pp 2844–2854 DOI: 10.1021/ic801687w Supporting Info

Synthesis, Characterization, Luminescence, and Non-linear Optical Properties of Oxadiazole- and Truxene-Containing Platinum(II) Alkynyl Complexes with Donor−Acceptor Functionalities Carmen Ka Man Chan, Chi-Hang Tao, Hoi-Lam Tam, Nianyong Zhu, Vivian Wing-Wah Yam and Kok-Wai Cheah pp 2855–2864 DOI: 10.1021/ic8017979 Supporting Info

Magnetostructural Correlations in CuII−NC−WV Linkage: The Case of [CuII(diimine)]2+−[WV(CN)8]3− 0D Assemblies Tomasz Korzeniak, Cdric Desplanches, Robert Podgajny, Carlos Gimnez-Saiz, Katarzyna Stadnicka, Michał Rams and Barbara Sieklucka pp 2865–2872 DOI: 10.1021/ic801989b Supporting Info

A Polynuclear d10−d10 Metal Complex with Unusual Near-Infrared Luminescence and High Thermal Stability Chengyang Yue, Chunfeng Yan, Rui Feng, Mingyan Wu, Lian Chen, Feilong Jiang and Maochun Hong pp 2873–2879 DOI: 10.1021/ic801840g Supporting Info

A Theoretical Study of the Magnetic Circular Dichroism Spectrum for Sulfite Oxidase Based on Time-Dependent Density Functional Theory Elizabeth Hernandez-Marin, Michael Seth and Tom Ziegler pp 2880–2886 DOI: 10.1021/ic801875u Supporting Info

[MIII(dmit)2]−-Coordinated MnIII Salen-Type Dimers (MIII = NiIII, AuIII; dmit2− = 1,3-Dithiol-2-thione-4,5-dithiolate): Design of Single-Component Conducting Single-Molecule Magnet-Based Materials Hiroki Hiraga, Hitoshi Miyasaka, Rodolphe Clrac, Marc Fourmigu and Masahiro Yamashita pp 2887–2898 DOI: 10.1021/ic802110b Supporting Info

Coupling Reactions of Functionalized Zintl Ions [E9Cd(C6H5)]3− (E = Sn, Pb) with Tributyltinhydride: Synthesis and Isolation of {Sn9CdSn[(CH2)3CH3]3}3− Binbin Zhou, Mark S. Denning, Thomas A. D. Chapman and Jose M. Goicoechea pp 2899–2907 DOI: 10.1021/ic8022826 Supporting Info

Modulating the Near-Infrared Luminescence of Neodymium and Ytterbium Complexes with Tridentate Ligands Based on Benzoxazole-Substituted 8-Hydroxyquinolines Nail M. Shavaleev, Rosario Scopelliti, Frdric Gumy and Jean-Claude G. Bnzli pp 2908–2918 DOI: 10.1021/ic8020468 Supporting Info

Host−Guest Interactions, Uniform vs Fragmented Linear Atom Chains and Likeliness of Peierls Distortions in the (Ca7N4)[Mx] (M = Ag, Ga, In) Phases Pere Alemany, Miquel Llunell and Enric Canadell pp 2919–2931 DOI: 10.1021/ic801983a

Copper(II) Complexes of l-Arginine as Netropsin Mimics Showing DNA Cleavage Activity in Red Light Ashis K. Patra, Tuhin Bhowmick, Sovan Roy, Suryanarayanarao Ramakumar and Akhil R. Chakravarty pp 2932–2943 DOI: 10.1021/ic8017425 Supporting Info

Zn and Fe Complexes Containing a Redox Active Macrocyclic Biquinazoline Ligand Priyabrata Banerjee, Anna Company, Thomas Weyhermller, Eckhard Bill and Corinna R. Hess pp 2944–2955 DOI: 10.1021/ic8020172 Supporting Info

Cyanide-Bridged FeIII−MnIII Bimetallic Complexes with Dimeric and Chain Structures Constructed from a Newly Made mer-Fe Tricyanide: Structures and Magnetic Properties Jae Il Kim, Hyun Young Kwak, Jung Hee Yoon, Dae Won Ryu, In Young Yoo, Namgeun Yang, Beong Ki Cho, Je-Geun Park, Hyosug Lee and Chang Seop Hong pp 2956–2966 DOI: 10.1021/ic802033q Supporting Info

1,2,4-Diazaphospholide Complexes of Barium: Mechanism of Formation and Crystallographic Characterization Chengfu Pi, Li Wan, Weiping Liu, Zaifu Pan, Haoyu Wu, Yunhua Wang, Wenjun Zheng, Linhong Weng, Zhenxia Chen and Limin Wu pp 2967–2975 DOI: 10.1021/ic802157g Supporting Info

Aqueous Coordination Chemistry of H2: Why is Coordinated H2 Inert to Substitution by Water in trans-Ru(P2)2(H2)H+-type Complexes (P2 = a Chelating Phosphine)? Nathaniel K. Szymczak, Dale A. Braden, Justin L. Crossland, Yevgeniya Turov, Lev N. Zakharov and David R. Tyler pp 2976–2984 DOI: 10.1021/ic801884x Supporting Info

In Situ XRD, XAS, and Magnetic Susceptibility Study of the Reduction of Ammonium Nickel Phosphate NiNH4PO4·H2O into Nickel Phosphide Gilles Berhault, Pavel Afanasiev, Hermione Lobou, Christophe Geantet, Tivadar Cseri, Christophe Pichon, Catherine Guillot-Deudon and Alain Lafond pp 2985–2992 DOI: 10.1021/ic802074k Supporting Info

Aqueous Fluorometric and Colorimetric Sensing of Phosphate Ions by a Fluorescent Dinuclear Zinc Complex Snehadrinarayan Khatua, Shin Hei Choi, Junseong Lee, Kibong Kim, Youngkyu Do and David G. Churchill pp 2993–2999 DOI: 10.1021/ic8022387 Supporting Info

Synthesis and Redox Chemistry of High-Valent Uranium Aryloxides Skye Fortier, Guang Wu and Trevor W. Hayton pp 3000–3011 DOI: 10.1021/ic802266y Supporting Info

Improvement of the Dynamic Range of pH Sensing by Using a Luminescent Tricarbonylpolypyridylrhenium(I) Complex with Three Different Protonation Sites Mauricio Cattaneo, Florencia Fagalde, Claudio D. Borsarelli and Nstor E. Katz pp 3012–3017 DOI: 10.1021/ic802203d Supporting Info

Visible and Near-Infrared Emission by Samarium(III)-Containing Ionic Liquid Mixtures Kyra Lunstroot, Peter Nockemann, Kristof Van Hecke, Luc Van Meervelt, Christiane Grller-Walrand, Koen Binnemans and Kris Driesen pp 3018–3026 DOI: 10.1021/ic8020782 Supporting Info

Heterotetranuclear Oxalato-Bridged ReIV3MII (M = Mn, Fe, Co, Ni, Cu) Complexes: A New Example of a Single-Molecule Magnet (M = Ni) Jos Martnez-Lillo, Donatella Armentano, Giovanni De Munno, Wolfgang Wernsdorfer, Juan Modesto Clemente-Juan, J. Krzystek, Francesc Lloret, Miguel Julve and Juan Faus pp 3027–3038 DOI: 10.1021/ic8021497 Supporting Info

Magnetic Compensation and Ordering in the Bimetallic Oxalates: Why Are the 2D and 3D Series so Different? Randy S. Fishman, Miguel Clemente-Len and Eugenio Coronado pp 3039–3046 DOI: 10.1021/ic802341k

Identification by NMR Spectroscopy of the Two Stereoisomers of the Platinum Complex [PtCl2(S-ahaz)] (S-ahaz = 3(S)-Aminohexahydroazepine) Bound to a DNA 14-mer Oligonucleotide. NMR Evidence of Structural Alteration of a Platinated A·T-rich 14-mer DNA Duplex Connie I. Diakos, Barbara A. Messerle, P. del Socorro Murdoch, John A. Parkinson, Peter J. Sadler, Ronald R. Fenton and Trevor W. Hambley pp 3047–3056 DOI: 10.1021/ic802207m Supporting Info

Synthesis and Modification of a Functionalized 3D Open-Framework Structure with MIL-53 Topology Tim Ahnfeldt, Daniel Gunzelmann, Thierry Loiseau, Dunja Hirsemann, Jrgen Senker, Gerard Frey and Norbert Stock pp 3057–3064 DOI: 10.1021/ic8023265 Supporting Info

Exploring the Effects of Reduction or Lewis Acid Coordination on the UO Bond of the Uranyl Moiety Trevor W. Hayton and Guang Wu pp 3065–3072 DOI: 10.1021/ic802360y Supporting Info

Synthesis and Characterization of Siloxy, Aminoxy, and Oxo Complexes from the Reaction of a Tantalum Amide Silyl Complex with Oxygen He Qiu, Shu-Jian Chen, Chang-Sheng Wang, Yun-Dong Wu, Ilia A. Guzei, Xue-Tai Chen and Zi-Ling Xue pp 3073–3079 DOI: 10.1021/ic802380u Supporting Info

Reaction of a (Salen)ruthenium(VI) Nitrido Complex with Isocyanide Hoi-Ki Kwong, Wai-Lun Man, Jing Xiang, Wing-Tak Wong and Tai-Chu Lau pp 3080–3086 DOI: 10.1021/ic802338f Supporting Info

Thermally Induced Interconversions of Metal−Pyrimidine-4,6-dicarboxylate Polymers: A Structural, Spectroscopic, and Magnetic Study Norberto Masciocchi, Simona Galli, Giulia Tagliabue, Angelo Sironi, Oscar Castillo, Antonio Luque, Garikoitz Beobide, Wenguo Wang, M. Angustias Romero, Elisa Barea and Jorge A. R. Navarro pp 3087–3094 DOI: 10.1021/ic802365w Supporting Info

Symmetric Heteropolynuclear Ti(IV)/Cu(I) Complexes Exhibiting Stepwise Electrochemical Reductions to Ti(III) Species Pierre Le Gendre, Virginie Comte, Marie-Jolle Ondel-Eymin, Claude Mose, Eveline Pousson, Philippe Richard, Yves Mugnier, Daniel Fortin, Ren T. Boer and Pierre D. Harvey pp 3095–3103 DOI: 10.1021/ic8023869 Supporting Info

Synthesis and Coordination Properties of Trifluoromethyl Decorated Derivatives of 2,6-Bis[(diphenylphosphinoyl)methyl]pyridine N-Oxide Ligands with Lanthanide Ions Sylvie Pailloux, Cornel Edicome Shirima, Alisha D. Ray, Eileen N. Duesler, Robert T. Paine, John R. Klaehn, Michael E. McIlwain and Benjamin P. Hay pp 3104–3113 DOI: 10.1021/ic802390c Supporting Info

Isolation of a 177Hf Complex Formed by β-Decay of a 177Lu-Labeled Radiotherapeutic Compound and NMR Structural Elucidation of the Ligand and its Lu and Hf Complexes Aldo Cagnolini, Nicola D’Amelio, Edmund Metcalfe, Hanh D. Nguyen, Silvio Aime, Rolf E. Swenson and Karen E. Linder pp 3114–3124 DOI: 10.1021/ic802328a Supporting Info

Mononuclear MnIII and MnIV Bis-terpyridine Complexes: Electrochemical Formation and Spectroscopic Characterizations Sophie Romain, Carole Baffert, Carole Duboc, Jean-Claude Leprtre, Alain Deronzier and Marie-Nolle Collomb pp 3125–3131 DOI: 10.1021/ic8024342

General Synthesis of Uniform Metal Sulfide Colloidal Particles via Autocatalytic Surface Growth: A Self-Correcting System Xin-Hao Li, Hong-Bin Li, Guo-Dong Li and Jie-Sheng Chen pp 3132–3138 DOI: 10.1021/ic802348d Supporting Info

Exchange Interactions in Azido-Bridged Ligand NiII Complexes: A Theoretical Analysis Gabriele Manca, Joan Cano and Eliseo Ruiz pp 3139–3144 DOI: 10.1021/ic802397k Supporting Info

Synthesis, Structural Characterization, and Electronic Structure of Single-Crystalline CuxV2O5 Nanowires Christopher J. Patridge, Cherno Jaye, Hengsong Zhang, Amy C. Marschilok, Daniel A. Fischer, Esther S. Takeuchi and Sarbajit Banerjee pp 3145–3152 DOI: 10.1021/ic802408c

Sn3I8·2(18-crown-6): a Mixed-Valent Tin-Crown-Ether Complex Michael Wolff, Thomas Harmening, Rainer Pttgen and Claus Feldmann pp 3153–3156 DOI: 10.1021/ic8024183 Supporting Info

Synthesis and Characterization of Dicobalthexacarbonyl-Alkyne Derivatives of Amino Acids, Peptides, and Peptide Nucleic Acid (PNA) Monomers Gilles Gasser, Merja A. Neukamm, Alexandra Ewers, Oliver Brosch, Thomas Weyhermller and Nils Metzler-Nolte pp 3157–3166 DOI: 10.1021/ic900013r Supporting Info

Ferromagnetic CuII4, CoII4, and NiII6 Azido Complexes Derived from Metal-Assisted Methanolysis of Di-2,6-(2-pyridylcarbonyl)pyridine Anastasia N. Georgopoulou, Catherine P. Raptopoulou, Vassilis Psycharis, Rafael Ballesteros, Beln Abarca and Athanassios K. Boudalis pp 3167–3176 DOI: 10.1021/ic900115c Supporting Info

New Derivatives of PCP-Type Pincer Complexes of Nickel Annie Castonguay, Andr L. Beauchamp and Davit Zargarian pp 3177–3184 DOI: 10.1021/ic801641u Supporting Info

Structural and Infrared Spectroscopic Studies of Some Novel Mechanochemically Accessed Adducts of Silver(I) Oxoanion Salts with Thiourea Graham A. Bowmaker, Brian W. Skelton and Allan H. White pp 3185–3197 DOI: 10.1021/ic802312j Supporting Info

Single Crystal Electron Paramagnetic Resonance Spectra of Cs2MnF6 and K2MnF6 Diluted in the Isomorphous Germanium Salts Christian Aagaard Thuesen, Anne-Laure Barra and Jørgen Glerup pp 3198–3204 DOI: 10.1021/ic802223j

Synthesis, Structure, and Catalase-Like Activity of Dimanganese(III) Complexes of 1,5-Bis[(2-hydroxy-5-X-benzyl)(2-pyridylmethyl)amino]pentan-3-ol (X = H, Br, OCH3) Hernn Biava, Claudia Palopoli, Carine Duhayon, Jean-Pierre Tuchagues and Sandra Signorella pp 3205–3214 DOI: 10.1021/ic8019793 Supporting Info

Ruthenium Phthalocyanine-Bipyridyl Dyads as Sensitizers for Dye-Sensitized Solar Cells: Dye Coverage versus Molecular Efficiency Tristan Rawling, Christine Austin, Florian Buchholz, Stephen B. Colbran and Andrew M. McDonagh pp 3215–3227 DOI: 10.1021/ic802087n Supporting Info

Facile Synthesis of Bistridentate RuII Complexes Based on 2,6-Di(quinolin-8-yl)pyridyl Ligands: Sensitizers with Microsecond 3MLCT Excited State Lifetimes Michael Jger, Rohan J. Kumar, Helmar Grls, Jonas Bergquist and Olof Johansson pp 3228–3238 DOI: 10.1021/ic802342t Supporting Info

Synthesis of N,C Bound Sulfur, Selenium, and Tellurium Heterocycles via the Reaction of Chalcogen Halides with −CH3 Substituted Diazabutadiene Ligands Jason L. Dutton, Caleb D. Martin, Michael J. Sgro, Nathan D. Jones and Paul J. Ragogna pp 3239–3247 DOI: 10.1021/ic802320s Supporting Info

Structurally Characterized 1,1,3,3-Tetramethylguanidine Solvated Magnesium Aryloxide Complexes: [Mg(μ-OEt)(DBP)(H-TMG)]2, [Mg(μ-OBc)(DBP)(H-TMG)]2, [Mg(μ-TMBA)(DBP)(H-TMG)]2, [Mg(μ-DPP)(DBP)(H-TMG)]2, [Mg(BMP)2(H-TMG)2], [Mg(O-2,6-Ph2C6H3)2 (H-TMG)2] Jessie D. Monegan and Scott D. Bunge pp 3248–3256 DOI: 10.1021/ic8022776 Supporting Info

Structural Study of Ga(III), In(III), and Fe(III) Complexes of Triaza-Macrocycle Based Ligands with N3S3 Donor Set Johannes Notni, Karolin Pohle, Joop A. Peters, Helmar Grls and Carlos Platas-Iglesias pp 3257–3267 DOI: 10.1021/ic900119a Supporting Info

Hydrolytic Synthesis and Structural Characterization of Lanthanide Hydroxide Clusters Supported by Nicotinic Acid Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng, Ruiyao Wang and Zhiping Zheng pp 3268–3273 DOI: 10.1021/ic802357m Supporting Info

Substitution and Reaction Chemistry of Cobalt Complexes Supported by [N2P2] Ligands Wayne A. Chomitz and John Arnold pp 3274–3286 DOI: 10.1021/ic802337t Supporting Info

Molecular Recognition of Redox-Switchable Bis-Crown Moieties Assembled on a Dicobalt Complex Hisashi Shimakoshi, Kaori Shibata and Yoshio Hisaeda p 3287 DOI: 10.1021/ic9003438

A New Synthetic Route to Mg2Na2NiH6 Where a [NiH4] Complex Is for the First Time Stabilized by Alkali Metal Counterions Karim Kadir and Dag Norus pp 3288–3289 DOI: 10.1021/ic900387m

High-Frequency and -Field EPR Spectroscopy of Tris(2,4-pentanedionato)manganese(III): Investigation of Solid-State versus Solution Jahn−Teller Effects J. Krzystek, Gregory J. Yeagle, Ju-Hyun Park, R. David Britt, Mark W. Meisel, Louis-Claude Brunel and Joshua Telser p 3290 DOI: 10.1021/ic900315h

Design, Synthesis, and Characterizations of a Series of Pt4 Macrocycles and Fluorescent Sensing of Cu2+/Ni2+ Through Metal Coordination Sushobhan Ghosh, Rajesh Chakrabarty and Partha Sarathi Mukherjee p 3291 DOI: 10.1021/ic900333z

Ferromagnetic Dy−Ni and Antiferromagnetic Dy−Cu Couplings in Single-Molecule Magnets [Dy2Ni] and [Dy2Cu] Atsushi Okazawa, Takashi Nogami, Hiroyuki Nojiri and Takayuki Ishida p 3292 DOI: 10.1021/ic900351p

Issue 8

Preface for the Forum on Molecular Magnetism: The Role of Inorganic Chemistry Eugenio Coronado and Kim R. Dunbar pp 3293–3295 DOI: 10.1021/ic900218f

Structure and Magnetic Interactions in the Organic-Based Ferromagnet Decamethylferrocenium Tetracyanoethenide, [FeCp*2]•+[TCNE]•− Jae-Hyuk Her, Peter W. Stephens, Jordi Ribas-Ario, Juan J. Novoa, William W. Shum and Joel S. Miller pp 3296–3307 DOI: 10.1021/ic801679m Supporting Info

Azide Groups in Higher Oxidation State Manganese Cluster Chemistry: From Structural Aesthetics to Single-Molecule Magnets Theocharis C. Stamatatos and George Christou pp 3308–3322 DOI: 10.1021/ic801217j

Magnetic [n × n] (n = 2−5) Grids by Directed Self-Assembly Louise N. Dawe, Konstantin V. Shuvaev and Laurence K. Thompson pp 3323–3341 DOI: 10.1021/ic801078h Supporting Info

3d−4f Combined Chemistry: Synthetic Strategies and Magnetic Properties Marius Andruh, Jean-Pierre Costes, Carmen Diaz and Song Gao pp 3342–3359 DOI: 10.1021/ic801027q

Functional Coordination Nanoparticles Laure Catala, Florence Volatron, Daniela Brinzei and Talal Mallah pp 3360–3370 DOI: 10.1021/ic8012574

Spin-Crossover Behavior in Cyanide-Bridged Iron(II)−Copper(I) Bimetallic 1−3D Metal−Organic Frameworks Gloria Agust, M. Carmen Muoz, Ana B. Gaspar and Jos A. Real pp 3371–3381 DOI: 10.1021/ic8010458 Supporting Info

Magnetic Exchange Coupling in Actinide-Containing Molecules Jeffrey D. Rinehart, T. David Harris, Stosh A. Kozimor, Bart M. Bartlett and Jeffrey R. Long pp 3382–3395 DOI: 10.1021/ic801303w Supporting Info

Molecular Magnets Containing Wheel Motifs Norihisa Hoshino, Ayuk M. Ako, Annie K. Powell and Hiroki Oshio pp 3396–3407 DOI: 10.1021/ic801776w Supporting Info

Organizing and Addressing Magnetic Molecules Dante Gatteschi, Andrea Cornia, Matteo Mannini and Roberta Sessoli pp 3408–3419 DOI: 10.1021/ic8013283

Slow Dynamics of the Magnetization in One-Dimensional Coordination Polymers: Single-Chain Magnets Hitoshi Miyasaka, Miguel Julve, Masahiro Yamashita and Rodolphe Clrac pp 3420–3437 DOI: 10.1021/ic802050j Supporting Info

Trigonal-Bipyramidal Metal Cyanide Complexes: A Versatile Platform for the Systematic Assessment of the Magnetic Properties of Prussian Blue Materials Kristen E. Funck, Matthew G. Hilfiger, Curtis P. Berlinguette, Michael Shatruk, Wolfgang Wernsdorfer and Kim R. Dunbar pp 3438–3452 DOI: 10.1021/ic801990g Supporting Info

Photomagnetism in Clusters and Extended Molecule-Based Magnets Anne Bleuzen, Valrie Marvaud, Corine Mathoniere, Barbara Sieklucka and Michel Verdaguer pp 3453–3466 DOI: 10.1021/ic802007g

Mononuclear Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9− and [Ln(β2-SiW11O39)2]13−(LnIII = Tb, Dy, Ho, Er, Tm, and Yb) Murad A. AlDamen, Salvador Cardona-Serra, Juan M. Clemente-Juan, Eugenio Coronado, Alejandro Gaita-Ario, Carlos Mart-Gastaldo, Fernando Luis and Oscar Montero pp 3467–3479 DOI: 10.1021/ic801630z Supporting Info

Nanomodulation of Molecular Nanomagnets Patrick L. Feng, Changhyun Koo, John J. Henderson, Paul Manning, Motohiro Nakano, Enrique del Barco, Stephen Hill and David N. Hendrickson pp 3480–3492 DOI: 10.1021/ic802336k Supporting Info

A Purely Lanthanide-Based Complex Exhibiting Ferromagnetic Coupling and Slow Magnetic Relaxation Behavior Zhi Chen, Bin Zhao, Peng Cheng, Xiao-Qing Zhao, Wei Shi and You Song pp 3493–3495 DOI: 10.1021/ic801507g Supporting Info

Synthesis and Characterization of VV(3,6-DBSQ)(3,6-DBCat)2, a d0 Metal Complex with Dioxygenase Catalytic Activity Aimee M. Morris, Cortlandt G. Pierpont and Richard G. Finke pp 3496–3498 DOI: 10.1021/ic802122q Supporting Info

Orbital Hybridization and Magnetic Coupling of the A-Site Cu Spins in CaCu3B4O12 (B = Ti, Ge, and Sn) Perovskites M. Mizumaki, T. Saito, H. Shiraki and Y. Shimakawa pp 3499–3501 DOI: 10.1021/ic802166b

Family of Heterometallic Semicircular MnIII2LnIII3 Strands Muhammad Nadeem Akhtar, Yan-Zhen Zheng, Yanhua Lan, Valeriu Mereacre, Christopher E. Anson and Annie K. Powell pp 3502–3504 DOI: 10.1021/ic9000686 Supporting Info

Synthesis and Crystallization of Infinite Indium and Gallium Acetate 1D Chain Structures and Concomitant Ethyl Acetate Hydrolysis Zachary L. Mensinger, Lev N. Zakharov and Darren W. Johnson pp 3505–3507 DOI: 10.1021/ic9000945 Supporting Info

Zinc Glycolate: A Precursor to ZnO Jaykrushna Das, Ivana R. Evans and Deepa Khushalani pp 3508–3510 DOI: 10.1021/ic900067w Supporting Info

A Tetranuclear CuII-Based 2D Aggregate with an Unprecedented Tetradentate μ4-N1,N3,N7,N9-Adeninate Nucleobase En-Cui Yang, Hong-Kun Zhao, Yan Feng and Xiao-Jun Zhao pp 3511–3513 DOI: 10.1021/ic900113e Supporting Info

An Iron Carbonyl Pyridonate Complex Related to the Active Site of the [Fe]-Hydrogenase (Hmd) Blaise V. Obrist, Dafa Chen, Anne Ahrens, Volker Schnemann, Rosario Scopelliti and Xile Hu pp 3514–3516 DOI: 10.1021/ic900281g Supporting Info

Transformation of a Layered Zinc Phosphite to a Three-Dimensional Open-Framework Structure with Intersecting 16- and 12-Ring Channels Zhien Lin, Hari Pada Nayek and Stefanie Dehnen pp 3517–3519 DOI: 10.1021/ic900306t Supporting Info

A Heterobimetallic Gallyl Complex Containing an Unsupported Ga−Y Bond Stephen T. Liddle, David P. Mills, Benedict M. Gardner, Jonathan McMaster, Cameron Jones and William D. Woodul pp 3520–3522 DOI: 10.1021/ic900278t Supporting Info

Direct Observation of Molecular Structural Change during Intersystem Crossing by Real-Time Spectroscopy with a Few Optical Cycle Laser Izumi Iwakura, Takayoshi Kobayashi and Atsushi Yabushita pp 3523–3528 DOI: 10.1021/ic801477a Supporting Info

Crystal and Molecular Structure of Manganese(II) Lapacholate, a Novel Polymeric Species Undergoing Temperature-Reversible Metal to Ligand Electron Transfer Francesco Caruso, Miguel A. Martnez, Miriam Rossi, Alexander Goldberg, M. Elizabeth Chacn Villalba and Pedro J. Aymonino pp 3529–3534 DOI: 10.1021/ic8015194 Supporting Info

A Simple Route to Single-Scorpionate Nickel(II) Complexes with Minimum Steric Requirements Patrick J. Desrochers, Adam L. Corken, Richard M. Tarkka, Brian M. Besel, Erin E. Mangum and Tiffany N. Linz pp 3535–3541 DOI: 10.1021/ic8015645 Supporting Info

Synthesis, Characterization, and Application of Vanadium−Salan Complexes in Oxygen Transfer Reactions Pedro Ado, Joo Costa Pessoa, Rui T. Henriques, Maxim L. Kuznetsov, Fernando Avecilla, Mannar R. Maurya, Umesh Kumar and Isabel Correia pp 3542–3561 DOI: 10.1021/ic8017985 Supporting Info

Organometallic Complexes for Nonlinear Optics. 43. Quadratic Optical Nonlinearities of Dipolar Alkynylruthenium Complexes with Phenyleneethynylene/Phenylenevinylene Bridges Luca Rigamonti, Bandar Babgi, Marie P. Cifuentes, Rachel L. Roberts, Simon Petrie, Robert Stranger, Stefania Righetto, Ayele Teshome, Inge Asselberghs, Koen Clays and Mark G. Humphrey pp 3562–3572 DOI: 10.1021/ic801953z Supporting Info

Lanthanide Compounds with Fluorinated Aryloxide Ligands: Near-Infrared Emission from Nd, Tm, and Er Kieran Norton, G. A. Kumar, Jennifer L. Dilks, Thomas J. Emge, Richard E. Riman, Mikhail G. Brik and John G. Brennan pp 3573–3580 DOI: 10.1021/ic8020639 Supporting Info

Influence of Conformational Flexibility on Self-Assembly and Luminescence Properties of Lanthanide Coordination Polymers with Flexible exo-Bidentate Biphenol Derivatives Yanling Guo, Wei Dou, Xiaoyan Zhou, Weisheng Liu, Wenwu Qin, Zhipeng Zang, Hongrui Zhang and Daqi Wang pp 3581–3590 DOI: 10.1021/ic802060e Supporting Info

Low-Energy Bands of Ferrocene−Ferrocenium Dimers: Bandshape Analysis with a Four-Level Two-Mode Vibronic Coupling Configuration Interaction (VCCI) Model Including Asymmetry Ralf Warratz and Felix Tuczek pp 3591–3607 DOI: 10.1021/ic802112h Supporting Info

Facile Synthesis of Novel Two- And Three-Dimensional Coordination Polymers Containing Dialkyltin Phosphonate-Based Tri/Tetra-Nuclear Clusters with Appended Sulfonate Groups Ravi Shankar, Archana Jain, Atul Pratap Singh, Gabriele Kociok-Khn and Kieran C. Molloy pp 3608–3616 DOI: 10.1021/ic802160a Supporting Info

Acid-Sensitive Pt(II) 2,6-Di(pyridin-2-yl)pyrimidin-4(1H)-one Complexes Hui Zhang, Bingguang Zhang, Yunjing Li and Wenfang Sun pp 3617–3627 DOI: 10.1021/ic801919g Supporting Info

What Singles out the FeO2+ Moiety? A Density-Functional Theory Study of the Methane-to-Methanol Reaction Catalyzed by the First Row Transition-Metal Oxide Dications MO(H2O)p2+, M = V−Cu Carine Michel and Evert Jan Baerends pp 3628–3638 DOI: 10.1021/ic802095m

Synthesis, Reactivity, and Kinetics of Substitution in W3PdSe4 Cuboidal Clusters. A Reexamination of the Kinetics of Substitution of the Related W3S4 Cluster with Thiocyanate Andrs G. Algarra, Maxim N. Sokolov, Javier Gonzlez-Platas, Mara Jess Fernndez-Trujillo, Manuel G. Basallote and Rita Hernndez-Molina pp 3639–3649 DOI: 10.1021/ic802150x Supporting Info

Aluminoborates with Open Frameworks: Syntheses, Structures, and Properties Cheng Rong, Zhiwu Yu, Qiang Wang, Shou-Tian Zheng, Chun-Yang Pan, Feng Deng and Guo-Yu Yang pp 3650–3659 DOI: 10.1021/ic802124v Supporting Info

Structure and Vibrational Properties of Oxohalides of Vanadium Vincent Guiot, Irene Suarez-Martinez, Philipp Wagner, Jonathan Goss, Patrick Briddon, Abdul W. Allaf and Christopher Paul Ewels pp 3660–3666 DOI: 10.1021/ic8022562

Proton-Transfer and H2-Elimination Reactions of Trimethylamine Alane: Role of Dihydrogen Bonding and Lewis Acid−Base Interactions Oleg A. Filippov, Victoria N. Tsupreva, Lyudmila M. Golubinskaya, Antonina I. Krylova, Vladimir I. Bregadze, Agusti Lledos, Lina M. Epstein and Elena S. Shubina pp 3667–3678 DOI: 10.1021/ic802262h Supporting Info

Studies on the Atropisomerism of Fe(II) 2,6-Bis(N-arylimino)pyridine Complexes Juan Cmpora, M. ngeles Cartes, Antonio Rodrguez-Delgado, A. Marcos Naz, Pilar Palma and Carmen M. Prez, Diego del Rio pp 3679–3691 DOI: 10.1021/ic802271y Supporting Info

Visible-Light Photoisomerization and Photoaquation of trans-[Ru(1,3,5-triaza-7-phosphaadamantane)4Cl2] in Organic Solvent and Water Rugiada Girotti, Antonio Romerosa, Sonia Maas, Manuel Serrano-Ruiz and Robin N. Perutz pp 3692–3698 DOI: 10.1021/ic802284j Supporting Info

Palladium N(CH2CH2PiPr2)2-Dialkylamides: Synthesis, Structural Characterization, and Reactivity Alexander N. Marziale, Eberhardt Herdtweck, Jrg Eppinger and Sven Schneider pp 3699–3709 DOI: 10.1021/ic802286u Supporting Info

Polynuclear Spin Crossover Complexes: Synthesis, Structure, and Magnetic Behavior of [Fe4(μ-CN)4(phen)4(L)2)]4+ Squares Ishtvan Boldog, Francisco J. Muoz-Lara, Ana B. Gaspar, M. Carmen Muoz, Maksym Seredyuk and Jos A. Real pp 3710–3719 DOI: 10.1021/ic802306r Supporting Info

Cationic Clathrate I Si46-xPxTey (6.6(1) ≤ y ≤ 7.5(1), x ≤ 2y): Crystal Structure, Homogeneity Range, and Physical Properties J. V. Zaikina, K. A. Kovnir, U. Burkhardt, W. Schnelle, F. Haarmann, U. Schwarz, Yu. Grin and A. V. Shevelkov pp 3720–3730 DOI: 10.1021/ic8023887 Supporting Info

Ground and Excited Electronic States of Quininone-Containing Re(I)-Based Rectangles: a Comprehensive Study of Their Preparation, Electrochemistry, and Photophysics Dibyendu Bhattacharya, Malaichamy Sathiyendiran, Tzuoo-Tsair Luo, Che-Hao Chang, Yu-Hsiang Cheng, Ching-Yao Lin, Gene-Hsiang Lee, Shie-Ming Peng and Kuang-Lieh Lu pp 3731–3742 DOI: 10.1021/ic8024099 Supporting Info

Molecular Tools for the Self-Assembly of Bisporphyrin Photodyads: A Comprehensive Physicochemical and Photophysical Study Jrmy Brandel, Ali Trabolsi, Hassan Traboulsi, Frdric Melin, Matthieu Koepf, Jennifer A. Wytko, Mourad Elhabiri, Jean Weiss and Anne-Marie Albrecht-Gary pp 3743–3754 DOI: 10.1021/ic802407x Supporting Info

Conjugated Triarylboryl Donor−Acceptor Systems Supported by 2,2′-Bipyridine: Metal Chelation Impact on Intraligand Charger Transfer Emission, Electron Accepting Ability, and “Turn-on” Fluoride Sensing Yi Sun and Suning Wang pp 3755–3767 DOI: 10.1021/ic9000335 Supporting Info

Group 11 Metal Chemistry of a Tetradentate Ligand, Phenylene-1,4-diaminotetra(phosphonite), p-C6H4[N{P(OC6H4OMe-o)2}2]2 Chelladurai Ganesamoorthy and Maravanji S. Balakrishna , Joel T. Mague pp 3768–3782 DOI: 10.1021/ic900085e Supporting Info

Trivalent Iron and Ruthenium Complexes with a Redox Noninnocent (2-Mercaptophenylimino)-methyl-4,6-di-tert-butylphenolate(2-) Ligand Nabarun Roy, Stephen Sproules, Thomas Weyhermller and Karl Wieghardt pp 3783–3791 DOI: 10.1021/ic8023716 Supporting Info

Tuning the Framework Topologies of CoII-Doped ZnII−Tetrazole-benzoate Coordination Polymers by Ligand Modifications: Structures and Spectral Studies Wei-Chao Song, Jian-Rong Li, Peng-Chao Song, Ying Tao, Qun Yu, Xiao-Lan Tong and Xian-He Bu pp 3792–3799 DOI: 10.1021/ic802438n Supporting Info

Ligand-Dependent Ultrasonic-Assistant Self-Assemblies and Photophysical Properties of Lanthanide Nicotinic/Isonicotinic Complexes Wentong Chen and Shunichi Fukuzumi pp 3800–3807 DOI: 10.1021/ic9000279 Supporting Info

Synthesis and Characterization of Iron Derivatives Having a Pyridine-Linked Bis(anilide) Pincer Ligand Edward C. Weintrob, Daniel Tofan and John E. Bercaw pp 3808–3813 DOI: 10.1021/ic900083s Supporting Info

Complexation of Uranium(VI) by Gluconate in Acidic Solutions: a Thermodynamic Study with Structural Analysis Zhicheng Zhang, Gregory Helms, Sue B. Clark, Guoxin Tian, PierLuigi Zanonato and Linfeng Rao pp 3814–3824 DOI: 10.1021/ic8018925 Supporting Info

Compounds with the Electron-Rich [W6Cl18]2− Cluster Anion Sonja Tragl, Markus Strbele, Jochen Glaser, Cristian Vicent, Rosa Llusar and H.-Jrgen Meyer pp 3825–3831 DOI: 10.1021/ic8019843 Supporting Info

Synthesis and Characterization of Mixed Chalcogen Triangular Complexes with New Mo3(μ3-S)(μ2-Se2)34+ and M3(μ3-S)(μ2-Se)34+(M = Mo, W) Cluster Cores Artem L. Gushchin, Bee-Lean Ooi, Pernille Harris, Cristian Vicent and Maxim N. Sokolov pp 3832–3839 DOI: 10.1021/ic8023327 Supporting Info

Is 2.07 Å a Record for the Shortest Pt−S Distance? Revision of Two Reported X-ray Structures Andrea Ienco, Maria Caporali, Fabrizio Zanobini and Carlo Mealli pp 3840–3847 DOI: 10.1021/ic8023748 Supporting Info

Synthesis, Crystal and Electronic Structures, and Physical Properties of the Novel Compounds LaR4Mo36O52 (R = Dy, Er, Yb, and Y) Containing Infinite Chains of Trans-Edge-Shared Mo6 Octahedra and Mo2 Pairs and Rectangular Mo4 Clusters with Triple Mo−Mo Bonds N. Barrier, B. Fontaine, S. Pierrefixe, R. Gautier and P. Gougeon pp 3848–3856 DOI: 10.1021/ic801942d Supporting Info

Group 11 Complexes of the P,Te-Centered Ligand [TePiPr2NPiPr2]−: Synthesis, Structures, and Insertion Reactions of the Copper(I) Complex with Chalcogens Jamie S. Ritch and Tristram Chivers pp 3857–3865 DOI: 10.1021/ic802428b Supporting Info

Multimetallic Arrays: Bi-, Tri-, Tetra-, and Hexametallic Complexes Based on Gold(I) and Gold(III) and the Surface Functionalization of Gold Nanoparticles with Transition Metals Edward R. Knight, Nina H. Leung, Amber L. Thompson, G. Hogarth and James D. E. T. Wilton-Ely pp 3866–3874 DOI: 10.1021/ic802442d Supporting Info

DFT Study on N2 Activation by a Hydride-Bridged Diniobium Complex. NN Bond Cleavage Accompanied by H2 Evolution Hiromasa Tanaka, Yoshihito Shiota, Tsukasa Matsuo, Hiroyuki Kawaguchi and Kazunari Yoshizawa pp 3875–3881 DOI: 10.1021/ic802377p Supporting Info

Isomeric Zinc(II) Triazolate Frameworks with 3-Connected Networks: Syntheses, Structures, and Sorption Properties Ai-Xin Zhu, Jian-Bin Lin, Jie-Peng Zhang and Xiao-Ming Chen pp 3882–3889 DOI: 10.1021/ic802446m Supporting Info

Size- and Surface-Determined Transformations: From Ultrathin InOOH Nanowires to Uniform c-In2O3 Nanocubes and rh-In2O3 Nanowires Xiangxing Xu and Xun Wang pp 3890–3895 DOI: 10.1021/ic802449w Supporting Info

Ruthenium(II) Complexes Incorporating 2-(2′-Pyridyl)pyrimidine-4-carboxylic Acid Nickita Nickita, Gilles Gasser, Pauline Pearson, Matthew J. Belousoff, Lai Y. Goh, Alan M. Bond, Glen B. Deacon and Leone Spiccia p 3896 DOI: 10.1021/ic9004505

Issue 9

Synthesis of Hollow Metal Oxide Nanospheres by Templating Polymeric Micelles with Core−Shell−Corona Architecture Dian Liu and Kenichi Nakashima pp 3898–3900 DOI: 10.1021/ic900078s Supporting Info

Continuous Band-Gap Reduction on ZnO Submicrorods via Covering with ZnS1−xSex or ZnSe1−xTex Alloy in Core/Sheath Morphology Yi-Zhi Huang, Li-Ming Wu, Shao-Wu Du and Ling Chen pp 3901–3903 DOI: 10.1021/ic802280z

Two Gallium Antimony Sulfides Built on a Novel Heterometallic Cluster Mei-Ling Feng, Zai-Lai Xie and Xiao-Ying Huang pp 3904–3906 DOI: 10.1021/ic900144d Supporting Info

Deep-Red-Emitting Electrochemical Cells Based on Heteroleptic Bis-chelated Ruthenium(II) Complexes Henk J. Bolink, Eugenio Coronado, Rubn D. Costa, Pablo Gavia, Enrique Ortí and Sergio Tatay pp 3907–3909 DOI: 10.1021/ic802433b Supporting Info

Synthesis and Characterization of a Binuclear Iron(III) Complex Bridged by 1-Aminocyclopropane-1-carboxylic Acid. Ethylene Production in the Presence of Hydrogen Peroxide Wadih Ghattas, Zeinab Serhan, Nadia El Bakkali-Taheri, Marius Rglier, Masahito Kodera, Yutaka Hitomi and A. Jalila Simaan pp 3910–3912 DOI: 10.1021/ic9001626 Supporting Info

Heme d1 Nitrosyl Complex of cd1 Nitrite Reductase Studied by High-Field-Pulse Electron Paramagnetic Resonance Spectroscopy Marina Radoul, Fabio Centola, Serena Rinaldo, Francesca Cutruzzol, Israel Pecht and Daniella Goldfarb pp 3913–3915 DOI: 10.1021/ic802355y Supporting Info

Structure Modulated Electronic Contributions to Metalloenediyne Reactivity: Synthesis and Thermal Bergman Cyclization of MLX2 Compounds Sibaprasad Bhattacharyya, Aurora E. Clark, Maren Pink and Jeffrey M. Zaleski pp 3916–3925 DOI: 10.1021/ic801116q Supporting Info

Density Functional Analysis of Ancillary Ligand Electronic Contributions to Metal-Mediated Enediyne Cyclization Aurora E. Clark, Sibaprasad Bhattacharryya and Jeffrey M. Zaleski pp 3926–3933 DOI: 10.1021/ic801117m Supporting Info

Direct Deconvolution of Two-State Pump-Probe X-ray Absorption Spectra and the Structural Changes in a 100 ps Transient of Ni(II)-tetramesitylporphyrin S. Della-Longa, L. X. Chen, P. Frank, K. Hayakawa, K. Hatada and M. Benfatto pp 3934–3942 DOI: 10.1021/ic8008943 Supporting Info

Thermodynamics and Structure of Actinide(IV) Complexes with Nitrilotriacetic Acid L. Bonin, D. Guillaumont, A. Jeanson, C. Den Auwer, M. Grigoriev, J.-C. Berthet, C. Hennig, A. Scheinost and Ph. Moisy pp 3943–3953 DOI: 10.1021/ic801453w Supporting Info

Influence of Mixed Substituents on the Macrocyclic Ring Distortions of Free Base Porphyrins and Their Metal Complexes P. Bhyrappa, C. Arunkumar and B. Varghese pp 3954–3965 DOI: 10.1021/ic801618m Supporting Info

Functionalization of Calix[4]arene as a Molecular Bridge To Assemble Luminescent Chemically Bonded Rare-Earth Hybrid Systems Hai-Feng Lu, Bing Yan and Jin-Liang Liu pp 3966–3975 DOI: 10.1021/ic801465p

Syntheses, Crystal Structures, and Gas Storage Studies in New Three-Dimensional 5-Aminoisophthalate Praseodymium Polymeric Complexes Yongcai Qiu, Hong Deng, Shihe Yang, Jixia Mou, Carole Daiguebonne, Nicolas Kerbellec, Olivier Guillou and Stuart R. Batten pp 3976–3981 DOI: 10.1021/ic8020518 Supporting Info

Exploring the Ground and Excited State Potential Energy Landscapes of the Mixed-Valence Biferrocenium Complex Ryan G. Hadt and Victor N. Nemykin pp 3982–3992 DOI: 10.1021/ic801801m Supporting Info

Structure and Dynamics of the U4+ Ion in Aqueous Solution: An ab Initio Quantum Mechanical Charge Field Molecular Dynamics Study Robert J. Frick, Andreas B. Pribil, Thomas S. Hofer, Bernhard R. Randolf, Anirban Bhattacharjee and Bernd M. Rode pp 3993–4002 DOI: 10.1021/ic801554p

Nearly Monodisperse CuInS2 Hierarchical Microarchitectures for Photocatalytic H2 Evolution under Visible Light Lei Zheng, Yang Xu, Yan Song, Changzheng Wu, Miao Zhang and Yi Xie pp 4003–4009 DOI: 10.1021/ic802399f Supporting Info

Determination of Experimental Charge Density in Model Nickel Macrocycle: [3,11-Bis(methoxycarbonyl)-1,5,9,13-tetraazacyclohexadeca-1,3,9,11-tetraenato-(2-)-κ4N]nickel(II) Sławomir Domagała, Bohdan Korybut-Daszkiewicz, Leo Straver and Krzysztof Woniak pp 4010–4020 DOI: 10.1021/ic801835g Supporting Info

Long-Range Through-Bond Heteronuclear Communication in Platinum Complexes Olena V. Zenkina, Leonid E. Konstantinovski, Linda J. W. Shimon, Yael Diskin-Posner, Mark A. Iron and Milko E. van der Boom pp 4021–4030 DOI: 10.1021/ic801940h Supporting Info

Synthesis and X-ray Structures of a Series of Heteroleptic Selenites of Copper Antonio Sousa-Pedrares, Mara Luz Durn, Jos Arturo Garca-Vzquez, Jaime Romero, Antonio Sousa and Jos A. Real pp 4031–4043 DOI: 10.1021/ic8019099 Supporting Info

Magnetic Properties and Vapochromic Reversible Guest-Induced Transformation in a Bispyrazolato Copper(II) Polymer: an Experimental and Dispersion-Corrected Density Functional Theory Study Alessandro Bencini, Maurizio Casarin, Daniel Forrer, Lorenzo Franco, Federica Garau, Norberto Masciocchi, Luciano Pandolfo, Claudio Pettinari, Marco Ruzzi and Andrea Vittadini pp 4044–4051 DOI: 10.1021/ic801928b

Establishing Amide···Amide Reliability and Synthon Transferability in the Supramolecular Assembly of Metal-Containing One-Dimensional Architectures Christer B. Aakery, Benjamin M. T. Scott, Michelle M. Smith, Joaquin F. Urbina and John Desper pp 4052–4061 DOI: 10.1021/ic801992t Supporting Info

Probing the Mechanism of O2 Activation by a Copper(I) Biomimetic Complex of a C−H Hydroxylating Copper Monooxygenase Albert Poater and Luigi Cavallo pp 4062–4066 DOI: 10.1021/ic802269v Supporting Info

Synthesis, Structure, and Optical Properties of the Platinum(II) Complexes of Indaphyrin and Thiaindaphyrin Kimberly S. F. Lau, Shengxian Zhao, Claudia Ryppa, Steffen Jockusch, Nicholas J. Turro, Matthias Zeller, Martin Gouterman, Gamal E. Khalil and Christian Brckner pp 4067–4074 DOI: 10.1021/ic802041z Supporting Info

Photochemical Study on the Reactivity of Tetrasulfur Tetranitride, S4N4 Elena A. Pritchina, Nina P. Gritsan, Andrey V. Zibarev and Thomas Bally pp 4075–4082 DOI: 10.1021/ic802145x Supporting Info

Synthesis and Characterization of Polynuclear Copper(II) Complexes with Pyridylbis(phenol) Ligands Rajendra Shakya, Anna Jozwiuk, Douglas R. Powell and Robert P. Houser pp 4083–4088 DOI: 10.1021/ic9000768 Supporting Info

Facile Entrapment of a Hydride inside the Tetracapped Tetrahedral CuI8 Cage Inscribed in a S12 Icosahedral Framework Ping-Kuei Liao, Bijay Sarkar, Hao-Wei Chang, Ju-Chun Wang and C. W. Liu pp 4089–4097 DOI: 10.1021/ic802288p Supporting Info

Regioselective Catenation of Dinuclear Palladium and Platinum Metallocycles Promoted by π···π Interactions Vctor Blanco, Dolores Abella, Elena Pa, Carlos Platas-Iglesias, Carlos Peinador and Jos M. Quintela pp 4098–4107 DOI: 10.1021/ic8022425 Supporting Info

Stereoselective Formation of Helical Binuclear Metal Complexes: Synthesis, Characterization, and Crystal Structures of Chiral Bis-Rhenium(I) Quaterpyridine Complexes Ho-Lun Yeung, Wai-Yeung Wong, Chun-Yuen Wong and Hoi-Lun Kwong pp 4108–4117 DOI: 10.1021/ic802249f Supporting Info

Properties of the [M(dppm)2M′]2+ Building Blocks (M, M′ = Pd or Pt): Site Selectivity, Emission Features, and Frontier Orbital Analysis Sbastien Clment, Shawkat M. Aly, Diana Bellows, Daniel Fortin, Carsten Strohmann, Laurent Guyard, Alaa S. Abd-El-Aziz, Michael Knorr and Pierre D. Harvey pp 4118–4133 DOI: 10.1021/ic8023315 Supporting Info

Gold Complexes with the Selenolate Ligand [2-(Me2NCH2)C6H4Se]− Olga Crespo, M. Concepcin Gimeno, Antonio Laguna, Monika Kulcsar and Cristian Silvestru pp 4134–4142 DOI: 10.1021/ic802396g Supporting Info

Does the 4f Electron Configuration Affect Molecular Geometries? A Joint Computational, Vibrational Spectroscopic, and Electron Diffraction Study of Dysprosium Tribromide Cornelis Petrus Groen, Zoltn Varga, Mria Kolonits, Kirk A. Peterson and Magdolna Hargittai pp 4143–4153 DOI: 10.1021/ic802340g Supporting Info

Calcium−Phosphonate Interactions: Solution Behavior and Ca2+ Binding by 2-Hydroxyethylimino-bis(methylenephosphonate) Studied by Multinuclear NMR Spectroscopy Konstantinos D. Demadis, Nikoleta Stavgianoudaki, Gisbert Grossmann, Margit Gruner and Joseph L. Schwartz pp 4154–4164 DOI: 10.1021/ic802400r Supporting Info

Symmetry-Dependent Strong Reduction of the Spin Exchange Interactions in Cs2CuCl4 by the 6p Orbitals of Cs+ Ions Changhoon Lee, Jinhee Kang, Kee Hag Lee and Myung-Hwan Whangbo pp 4165–4170 DOI: 10.1021/ic802412x Supporting Info

Dithiocarbamate Complexes of Ti(IV) Alkoxides: Synthesis, Characterization, and Electrochemistry Alberto Donzelli and Pierre G. Potvin pp 4171–4178 DOI: 10.1021/ic802394a Supporting Info

Synthesis of Cyclometallated Platinum Complexes with Substituted Thienylpyridines and Detailed Characterization of Their Luminescence Properties Dmitry N. Kozhevnikov, Valery N. Kozhevnikov, Maria M. Ustinova, Amedeo Santoro, Duncan W. Bruce, Burkhard Koenig, Rafał Czerwieniec, Tobias Fischer, Manfred Zabel and Hartmut Yersin pp 4179–4189 DOI: 10.1021/ic802401j Supporting Info

Reduction Chemistry of Aryl- and Alkyl-Substituted Bis(imino)pyridine Iron Dihalide Compounds: Molecular and Electronic Structures of [(PDI)2Fe] Derivatives Bradley M. Wile, Ryan J. Trovitch, Suzanne C. Bart, Aaron M. Tondreau, Emil Lobkovsky, Carsten Milsmann, Eckhard Bill, Karl Wieghardt and Paul J. Chirik pp 4190–4200 DOI: 10.1021/ic801623m Supporting Info

Structures of the Solvated Organic-Based Ferromagnet Decamethylferrocenium Tetracyanoethenide, [FeCp*2]·+[TCNE]·−·yRCN (R = Me, Et, n-Pr) Joel S. Miller, Peter K. Gantzel, Arnold L. Rheingold and Michelle L. Taliaferro pp 4201–4206 DOI: 10.1021/ic900075j Supporting Info

Structural and Photophysical Studies of Highly Stable Lanthanide Complexes of Tripodal 8-Hydroxyquinolinate Ligands Based on 1,4,7-Triazacyclononane Aline Nonat, Daniel Imbert, Jacques Pcaut, Marion Giraud and Marinella Mazzanti pp 4207–4218 DOI: 10.1021/ic9000076 Supporting Info

Cadmium(II) Cysteine Complexes in the Solid State: A Multispectroscopic Study Farideh Jalilehvand, Vicky Mah, Bonnie O. Leung, Jnos Mink, Guy M. Bernard and Lszl Hajba pp 4219–4230 DOI: 10.1021/ic900145n Supporting Info

Hexacoordinated Oligosilanes from a Hexacoordinated Silicon(IV) Complex Containing an O,N,N,O Salen-type and Thiocyanato-N Ligands Gerardo Gonzlez-Garca, Eleuterio lvarez, ngel Marcos-Fernndez and J. Alfredo Gutirrez pp 4231–4238 DOI: 10.1021/ic8024364 Supporting Info

Interaction of Copper(II) with the Prion Peptide Fragment HuPrP(76−114) Encompassing Four Histidyl Residues within and outside the Octarepeat Domain Giuseppe Di Natale, Katalin sz, Zoltn Nagy, Daniele Sanna, Giovanni Micera, Giuseppe Pappalardo, Imre Svg and Enrico Rizzarell pp 4239–4250 DOI: 10.1021/ic802190v Supporting Info

Rhenium(I) Tricarbonyl Complexes with Poly(azolyl)borates Generated in Situ from an Organometallic Precursor Containing the B−H···Re Coordination Motif Margarida Videira, Carolina Moura, Amitabha Datta, Antnio Paulo, Isabel C. Santos and I. Santos pp 4251–4257 DOI: 10.1021/ic802403u Supporting Info

Yttrium Complexes Supported by Linked Bis(amide) Ligand: Synthesis, Structure, and Catalytic Activity in the Ring-Opening Polymerization of Cyclic Esters Tatyana V. Mahrova, Georgy K. Fukin, Anton V. Cherkasov, Alexander A. Trifonov, Noureddine Ajellal and Jean-Franois Carpentier pp 4258–4266 DOI: 10.1021/ic802427f Supporting Info

Issue 10

Electrical Properties of New Organic Conductor (BEST)2InBr4 [BEST = Bis(ethylenediseleno)tetrathiafulvalene] up to 10.8 GPa and Antiferromagnetic Transition of (BEST)2FeBr4 Hengbo Cui, James Brooks, David Graf, Yoshinori Okano, Haoling Sun and Hayao Kobayashi pp 4268–4270 DOI: 10.1021/ic900220g Supporting Info

C−H Bond Activation of Decamethylcobaltocene Mediated by a Nitrogenase Fe8S7 P-Cluster Model Yasuhiro Ohki, Ayuro Murata, Motosuke Imada and Kazuyuki Tatsumi pp 4271–4273 DOI: 10.1021/ic900284f Supporting Info

Synthesis and Electronic Spectra of Fluorinated Aryloxide and Alkoxide [NiX4]2− Anions BingNa Zheng, Maria O. Miranda, Antonio G. DiPasquale, James A. Golen, Arnold L. Rheingold and Linda H. Doerrer pp 4274–4276 DOI: 10.1021/ic9003593 Supporting Info

Solvation of Ln(III) Lanthanide Cations in the [BMI][SCN], [MeBu3N][SCN], and [BMI]5[Ln(NCS)8] Ionic Liquids: A Molecular Dynamics Study A. Chaumont and G. Wipff pp 4277–4289 DOI: 10.1021/ic802227p Supporting Info

Structural and Physical Properties of the 6M BaIrO3: A New Metallic Iridate Synthesized under High Pressure Jinggeng Zhao, Liuxiang Yang, Yong Yu, Fengying Li, Richeng Yu and Changqing Jin pp 4290–4294 DOI: 10.1021/ic801707m Supporting Info

Alteration of Molecular Conformations, Coordination Modes, and Architectures for a Novel 3,8-Diimidazol-1,10-phenanthroline Compound in the Construction of Cadmium(II) and Zinc(II) Homochiral Coordination Polymers Involving an Auxiliary Chiral Camphorate Ligand Li Wang, Wei You, Wei Huang, Cheng Wang and Xiao-Zeng You pp 4295–4305 DOI: 10.1021/ic802445q Supporting Info

Cyclometalated 6-Phenyl-2,2′-bipyridyl (CNN) Platinum(II) Acetylide Complexes: Structure, Electrochemistry, Photophysics, and Oxidative- and Reductive-Quenching Studies Jacob Schneider, Pingwu Du, Paul Jarosz, Theodore Lazarides, Xiaoyong Wang, William W. Brennessel and Richard Eisenberg pp 4306–4316 DOI: 10.1021/ic801947v Supporting Info

Replacement of a Nitrogen by a Phosphorus Donor in Biomimetic Copper Complexes: a Surprising and Informative Case Study with Calix[6]arene-Based Cryptands Diana Over, Aurlien de la Lande, Xianshun Zeng, Olivier Parisel and Olivia Reinaud pp 4317–4330 DOI: 10.1021/ic802253t Supporting Info

1,4-Phenylenebis(methylidyne)tetrakis(phosphonic acid): A New Building Block in Metal Organic Framework Synthesis Monika Plabst and Thomas Bein pp 4331–4341 DOI: 10.1021/ic802294e Supporting Info

Polymorphism of Potassium Ferrocyanide Trihydrate as Studied by Solid-State Multinuclear NMR Spectroscopy and X-ray Diffraction Mathew J. Willans, Roderick E. Wasylishen and Robert McDonald pp 4342–4353 DOI: 10.1021/ic802134j Supporting Info

Syntheses and Vibrational Circular Dichroism Spectra of the Complete Series of [Ru((−)- or (+)-tfac)n(acac)3−n] (n = 0 3, tfac = 3-Trifluoroacetylcamphorato and acac = Acetylacetonato) Hisako Sato, Yukie Mori, Yutaka Fukuda and Akihiko Yamagishi pp 4354–4361 DOI: 10.1021/ic801971p Supporting Info

R5Pn3-type Phases of the Heavier Trivalent Rare-Earth-Metal Pnictides (Pn = Sb, Bi): New Phase Transitions for Er5Sb3 and Tm5Sb3 Shalabh Gupta, E. Alejandro Len-Escamilla, Fei Wang, Gordon J. Miller and John D. Corbett pp 4362–4371 DOI: 10.1021/ic802464u Supporting Info

Characterization of Redox States of Ru(OH2)(Q)(tpy)2+ (Q = 3,5-di-tert-butyl-1,2-benzoquinone, tpy = 2,2′:6′,2″-terpyridine) and Related Species through Experimental and Theoretical Studies Ming-Kang Tsai, Jonathan Rochford, Dmitry E. Polyansky, Tohru Wada, Koji Tanaka, Etsuko Fujita and James T. Muckerman pp 4372–4383 DOI: 10.1021/ic900057y Supporting Info

How to Make the Ionic Si−O Bond More Covalent and the Si−O−Si Linkage a Better Acceptor for Hydrogen Bonding Simon Grabowsky, Maxie F. Hesse, Carsten Paulmann, Peter Luger and Jens Beckmann pp 4384–4393 DOI: 10.1021/ic900074r Supporting Info

Quadruply Bonded Dimetal Units Supported by 2,4,6-Triisopropylbenzoates MM(TiPB)4 (MM = Mo2, MoW, and W2): Preparation and Photophysical Properties Brian G. Alberding, Malcolm H. Chisholm, Yi-Hsuan Chou, Judith C. Gallucci, Yagnaseni Ghosh, Terry L. Gustafson, Nathan J. Patmore, Carly R. Reed and Claudia Turro pp 4394–4399 DOI: 10.1021/ic900092c Supporting Info

Characterization of Intermediary Redox States of the Water Oxidation Catalyst, [Ru(bpy)2(OH2)]2O4+ Jonathan L. Cape, Sergei V. Lymar, Travis Lightbody and James K. Hurst pp 4400–4410 DOI: 10.1021/ic9001219 Supporting Info

Reinvestigation of a Ru2-Incorporated Polyoxometalate Dioxygenase Precatalyst, “[WZnRu2III(H2O)(OH)(ZnW9O34)2]11−”: Evidence For Marginal, ≤0.2 Equivalents of Ru Incorporation Plus Faster Catalysis by Physical Mixtures of [RuII(DMSO)4Cl2] and the Parent Polyoxometalate [WZn3(H2O)2(ZnW9O34)2]12− Aimee M. Morris, Oren P. Anderson and Richard G. Finke pp 4411–4420 DOI: 10.1021/ic9000363 Supporting Info

Facile Synthesis and Unique Physicochemical Properties of Three-Dimensionally Ordered Macroporous Magnesium Oxide, Gamma-Alumina, and Ceria−Zirconia Solid Solutions with Crystalline Mesoporous Walls Huining Li, Lei Zhang, Hongxing Dai and Hong He pp 4421–4434 DOI: 10.1021/ic900132k Supporting Info

Redox-Regulated Inhibition of T7 RNA Polymerase via Establishment of Disulfide Linkages by Substituted Dppz Dirhodium(II,II) Complexes J. Dafhne Aguirre, Helen T. Chifotides, Alfredo M. Angeles-Boza, Abdellatif Chouai, Claudia Turro and Kim R. Dunbar pp 4435–4444 DOI: 10.1021/ic900164j

β-Diketiminato Calcium and Magnesium Amides; Model Complexes for Hydroamination Catalysis Anthony G. M. Barrett, Ian J. Casely, Mark. R. Crimmin, Michael S. Hill, Jennifer R. Lachs, Mary F. Mahon and Panayiotis A. Procopiou pp 4445–4453 DOI: 10.1021/ic900091x Supporting Info

Ferromagnetic and Antiferromagnetic Coupling of [Ni(dmit)2]− Anion Layers Induced by Cs+2(benzo[18]crown-6)3 Supramolecule Tomoyuki Akutagawa, Kozo Shitagami, Masaki Aonuma, Shin-ichiro Noro and Takayoshi Nakamura pp 4454–4461 DOI: 10.1021/ic9001847 Supporting Info

Coordination Chemistry of [HFe(CN)2(CO)3]− and Its Derivatives: Toward a Model for the Iron Subsite of the [NiFe]-Hydrogenases C. Matthew Whaley, Thomas B. Rauchfuss and Scott R. Wilson pp 4462–4469 DOI: 10.1021/ic900200s Supporting Info

Solvothermal Metal Azide Decomposition Routes to Nanocrystalline Metastable Nickel, Iron, and Manganese Nitrides Jonglak Choi and Edward G. Gillan pp 4470–4477 DOI: 10.1021/ic900260u Supporting Info

Synthesis and X-ray Crystal Structure of (OsO3F2)2·2XeOF4 and the Raman Spectra of (OsO3F2)∞, (OsO3F2)2, and (OsO3F2)2·2XeOF4 Michael J. Hughes, Hlne P. A. Mercier and Gary J. Schrobilgen pp 4478–4490 DOI: 10.1021/ic900242m Supporting Info

Dendrimer-Encapsulated Pd Nanoparticles versus Palladium Acetate as Catalytic Precursors in the Stille Reaction in Water Mara Bernechea, Ernesto de Jess, Carmen Lpez-Mardomingo and Pilar Terreros pp 4491–4496 DOI: 10.1021/ic9002753 Supporting Info

Lanthanide Complexes with Cucurbit[n]urils (n = 5, 6, 7) and Perrhenate Ligands: New Examples of Encapsulation of Perrhenate Anions Pierre Thury pp 4497–4513 DOI: 10.1021/ic900328z Supporting Info

Effects of Electron-Deficient β-Diketiminate and Formazan Supporting Ligands on Copper(I)-Mediated Dioxygen Activation Sungjun Hong, Lyndal M. R. Hill, Aalo K. Gupta, Benjamin D. Naab, Joe B. Gilroy, Robin G. Hicks, Christopher J. Cramer and William B. Tolman pp 4514–4523 DOI: 10.1021/ic9002466 Supporting Info

Highly Monodisperse Colloidal Magnesium Nanoparticles by Room Temperature Digestive Ripening Suresh Babu Kalidindi and Balaji R. Jagirdar pp 4524–4529 DOI: 10.1021/ic9003577 Supporting Info

Periodic Trends in Actinide Phosphonates: Divergence and Convergence between Thorium, Uranium, Neptunium, and Plutonium Systems Anna-Gay D. Nelson, Travis H. Bray, Forrest A. Stanley and Thomas E. Albrecht-Schmitt pp 4530–4535 DOI: 10.1021/ic900484w Supporting Info

Spin Frustration and Long-Range Ordering in an AlB2-like Metal-Organic Framework with Unprecedented N,N,N-Tris-tetrazol-5-yl-amine Ligand Xian-Ming Zhang, Tao Jiang, Hai-Shun Wu and Ming-Hua Zeng pp 4536–4541 DOI: 10.1021/ic9002912 Supporting Info

Bonding Characteristics, Thermal Expansibility, and Compressibility of RXO4 (R = Rare Earths, X = P, As) within Monazite and Zircon Structures Huaiyong Li, Siyuan Zhang, Shihong Zhou and Xueqiang Cao pp 4542–4548 DOI: 10.1021/ic900337j

Palladium Diselenolenes: a New Group of near-Infrared Lumophores Karen Rofe, Peter Douglas, Christopher P. Morley, Christopher A. Webster and Jeremie G. Pichereau pp 4549–4556 DOI: 10.1021/ic801694r

High-Nuclearity Mixed-Valence Clusters and Mixed-Valence Chains: General Approach to the Calculation of the Energy Levels and Bulk Magnetic Properties J. M. Clemente-Juan, J. J. Borrs-Almenar, E. Coronado, A. V. Palii and B. S. Tsukerblat pp 4557–4568 DOI: 10.1021/ic802201h

Catalase vs Peroxidase Activity of a Manganese(II) Compound: Identification of a Mn(III)−(μ-O)2−Mn(IV) Reaction Intermediate by Electrospray Ionization Mass Spectrometry and Electron Paramagnetic Resonance Spectroscopy Josane A. Lessa, Adolfo Horn, Jr., rika S. Bull, Michelle R. Rocha, Mario Benassi, Rodrigo R. Catharino, Marcos N. Eberlin, Annelise Casellato, Christoper J. Noble, Graeme R. Hanson, Gerhard Schenk, Giselle C. Silva, O. A. C. Antunes and Christiane Fernandes pp 4569–4579 DOI: 10.1021/ic801969c Supporting Info

Effect of Hydrogen Atoms on the Structures of Trinuclear Metal Carbonyl Clusters: Trinuclear Manganese Carbonyl Hydrides Xian-mei Liu, Chao-yang Wang, Qian-shu Li, Yaoming Xie, R. Bruce King and Henry F. Schaefer, III pp 4580–4591 DOI: 10.1021/ic802413c Supporting Info

Issue 11

Tristability Arising from Singlet−Triplet and Quartet Spin States for Dimeric CoIISalen Kil Sik Min, Jordan Arthur, William W. Shum, Muktha Bharathy, Hans-Conrad zur Loye and Joel S. Miller pp 4593–4594 DOI: 10.1021/ic900436e Supporting Info

Homo- and Heterobismetal Complexes of 5-Hydroxy-10,15,25,30-tetrakis(pentafluorophenyl)-Substituted [26]Hexaphyrin(1.1.1.1.1.1) Taro Koide, Gengo Kashiwazaki, Ko Furukawa and Atsuhiro Osuka pp 4595–4597 DOI: 10.1021/ic900084p Supporting Info

New Crystalline Layered Zinc Phosphate with 10-Membered-Ring Channels Perpendicular to Layers Lei Liu, Stanislav Ferdov, Cristina Coelho, Ying Kong, Lus Mafra, Jin P. Li, Jin X. Dong, Uwe Kolitsch, Rute A. S Ferreira, Ekkehart Tillmanns, Joo Rocha and Zhi Lin pp 4598–4600 DOI: 10.1021/ic900107p Supporting Info

Divergent Approach to a Large Variety of Versatile Luminescent Lanthanide Complexes Pascal Kadjane, Matthieu Starck, Franck Camerel, Diana Hill, Niko Hildebrandt, Raymond Ziessel and Loc J. Charbonnire pp 4601–4603 DOI: 10.1021/ic9001169 Supporting Info

Vanadium Octacyanoniobate-Based Magnet with a Curie Temperature of 138 K Wataru Kosaka, Kenta Imoto, Yoshihide Tsunobuchi and Shin-ichi Ohkoshi pp 4604–4606 DOI: 10.1021/ic9001576 Supporting Info

New Aryltellurenyl Iodides with Uncommon Valences: Synthetic and Structural Characteristics of [RTeTeI2R], [R2TeTeR2][Te4I14], and [RTe(I)I2] (R = 2,6-Dimethoxyphenyl) G. Manzoni de Oliveira, Eliandro Faoro and E. Schulz Lang pp 4607–4609 DOI: 10.1021/ic900193k Supporting Info

Interpretation of the Magnetic Properties of a Compound Consisting of Cocrystallized CuII3 and CuII4 Clusters through the Targeted Synthesis and Study of Its Discrete CuII4 Component Theocharis C. Stamatatos, Gina C. Vlahopoulou, Catherine P. Raptopoulou, Aris Terzis, Albert Escuer and Spyros P. Perlepes pp 4610–4612 DOI: 10.1021/ic900188k Supporting Info

Polymorphism in High-Crystalline-Stability Metal−Organic Nanotubes Fangna Dai, Haiyan He and Daofeng Sun pp 4613–4615 DOI: 10.1021/ic900283t Supporting Info

A Three-Dimensional Porous Metal−Organic Framework Constructed from Two-Dimensional Sheets via Interdigitation Exhibiting Dynamic Features Shengqian Ma, Daofeng Sun, Paul M. Forster, Daqiang Yuan, Wenjuan Zhuang, Yu-Sheng Chen, John B. Parise and Hong-Cai Zhou pp 4616–4618 DOI: 10.1021/ic900372t Supporting Info

Synthetic, Structural, and Theoretical Investigation of Guanidinate Complexes Containing Planar Cu6 Cores Scott D. Bunge, Jesus A. Ocana, Travis L. Cleland and Jennifer L. Steele pp 4619–4621 DOI: 10.1021/ic9003627 Supporting Info

Noncovalent Interactions in a Transition-Metal Triphenylphosphine Complex: a Density Functional Case Study Nicolas Sieffert and Michael Bhl pp 4622–4624 DOI: 10.1021/ic900347e Supporting Info

Synthesis and Characterization of New Mono- and Heptazinc Complexes with Unusual Amide Coordination Modes Manindranath Bera, Ghezai T. Musie and Douglas R. Powell pp 4625–4627 DOI: 10.1021/ic900373f Supporting Info

Molecular Nanocluster with a [Sn4Ga4Zn2Se20]8− T3 Supertetrahedral Core Guohai Xu, Peng Guo, Shuyan Song, Hongjie Zhang and Cheng Wang pp 4628–4630 DOI: 10.1021/ic900376h Supporting Info

4f Gadolinium(III) Complex Involving Tetrathiafulvalene-amido-2-pyrimidine-1-oxide as a Ligand Fabrice Pointillart, Yann Le Gal, Stphane Golhen, Olivier Cador and Lahcne Ouahab pp 4631–4633 DOI: 10.1021/ic9003966 Supporting Info

A Chiral meso-ABC-Corrolatochromium(V) Complex Olga A. Egorova, Olga G. Tsay, Snehadrinarayan Khatua, Jung Oh Huh and David G. Churchill pp 4634–4636 DOI: 10.1021/ic900393v Supporting Info

DNA Condensation Induced by Ruthenium(II) Polypyridyl Complexes [Ru(bpy)2(PIPSH)]2+ and [Ru(bpy)2(PIPNH)]2+ Bin Sun, Jing-Xin Guan, Li Xu, Bo-Le Yu, Long Jiang, Jun-Feng Kou, Li Wang, Xi-Dong Ding, Hui Chao and Liang-Nian Ji pp 4637–4639 DOI: 10.1021/ic900102r Supporting Info

Ligand-Assisted Preparation of Palladium Supported Nanoparticles: a Step toward Size Control Liane M. Rossi, Inna M. Nangoi and Natlia J. S. Costa pp 4640–4642 DOI: 10.1021/ic900440p Supporting Info

High Conductivity of the New Supramoleclar Copper Complex with Oxidized Pyrazinoselenathiafulvalene (=pyra-STF) as the Ligand, [CuICl1.5(pyra-STF)0.5+] Shun Ichikawa and Hatsumi Mori pp 4643–4645 DOI: 10.1021/ic9004449 Supporting Info

Mixed f−d Coordination Complexes as Dual Visible- and Near-Infrared-Emitting Probes for Targeting DNA Aline M. Nonat, Susan J. Quinn and Thorfinnur Gunnlaugsson pp 4646–4648 DOI: 10.1021/ic900422z Supporting Info

New Prototype Isoreticular Metal−Organic Framework Zn4O(FMA)3 for Gas Storage Ming Xue, Yun Liu, Roxanna M. Schaffino, Shengchang Xiang, Xiaojun Zhao, Guang-Shan Zhu, Shi-Lun Qiu and Banglin Chen pp 4649–4651 DOI: 10.1021/ic900486r Supporting Info

Vapor-Diffusion-Mediated Single Crystal-to-Single Crystal Transformation of a Discrete Dimeric Copper(II) Complex to a Discrete Tetrameric Copper(II) Complex Shaikh M. Mobin, Ashwini K. Srivastava, Pradeep Mathur and Goutam Kumar Lahiri pp 4652–4654 DOI: 10.1021/ic900510v Supporting Info

Solid-State Coordination Chemistry of Copper(II) Tetrazolates: Anion Control of Frameworks Constructed from Trinuclear Copper(II) Building Blocks Wayne Ouellette, Hongxue Liu, Charles J. O’Connor and Jon Zubieta pp 4655–4657 DOI: 10.1021/ic9003802 Supporting Info

Use of Hydrazine in the Hydrothermal Synthesis of Chalcogenides: the Neutral Framework Material [Mn2SnS4(N2H4)2] Manolis J. Manos and Mercouri G. Kanatzidis pp 4658–4660 DOI: 10.1021/ic900517u Supporting Info

Molecular-Programmed Self-Assembly of Homo- and Heterometallic Tetranuclear Coordination Compounds: Synthesis, Crystal Structures, and Magnetic Properties of Rack-Type CuII2MII2 Complexes (M = Cu and Ni) with Tetranucleating Phenylenedioxamato Bridging Ligands Emilio Pardo, Danielle Cangussu, Rodrigue Lescouzec, Yves Journaux, Jorge Pasn, Fernando S. Delgado, Catalina Ruiz-Prez, Rafael Ruiz-Garca, Joan Cano, Miguel Julve and Francesc Lloret pp 4661–4673 DOI: 10.1021/ic900055d Supporting Info

Three-Dimensional Metal Azide Coordination Polymers with Amino Carboxylate Coligands: Synthesis, Structure, and Magnetic Properties Zi-Lu Chen, Chun-Fang Jiang, Wei-Hong Yan, Fu-Pei Liang and Stuart R. Batten pp 4674–4684 DOI: 10.1021/ic802026n Supporting Info

Effects of Hydrothermal Temperature on the Microstructures of BiVO4 and Its Photocatalytic O2 Evolution Activity under Visible Light Dingning Ke, Tianyou Peng, Liang Ma, Ping Cai and Ke Dai pp 4685–4691 DOI: 10.1021/ic900064m Supporting Info

On an Electrode Modified by a Supramolecular Ruthenium Mixed Valence (RuII/RuIII) Diphosphine-Porphyrin Assembly Luis R. Dinelli, Gustavo Von Poelhsitz, Eduardo E. Castellano, Javier Ellena, Srgio E. Galembeck and Alzir A. Batista pp 4692–4700 DOI: 10.1021/ic702471d Supporting Info

Cerium(IV) Catalysts for the Ring-Opening Polymerization of Lactide Erin M. Broderick and Paula L. Diaconescu pp 4701–4706 DOI: 10.1021/ic802047u Supporting Info

Three Lanthanum MOF Polymorphs: Insights into Kinetically and Thermodynamically Controlled Phases Felipe Gndara, Vctor A. de la Pea-O’Shea, Francesc Illas, Natalia Snejko, David M. Proserpio, Enrique Gutirrez-Puebla and M. Angeles Monge pp 4707–4713 DOI: 10.1021/ic801779j Supporting Info

Hybrid Materials of Lanthanide Centers/Functionalized 2-Thenoyltrifluoroacetone/Silicon−Oxygen Network/Polymeric Chain: Coordination Bonded Assembly, Physical Characterization, and Photoluminescence Xiao-Fei Qiao and Bing Yan pp 4714–4723 DOI: 10.1021/ic8017776 Supporting Info

Role of Intermolecular Interactions in Oxygen Transfer Catalyzed by Silsesquioxane Trisilanolate Vanadium(V) Silvia Lovat, Miriam Mba, Hendrikus C. L. Abbenhuis, Dieter Vogt, Cristiano Zonta and Giulia Licini pp 4724–4728 DOI: 10.1021/ic802191z Supporting Info

Ligand-Driven Light-Induced Spin Change Activity and Bidirectional Photomagnetism of Styrylpyridine Iron(II) Complexes in Polymeric Media M.-L. Boillot, S. Pillet, A. Tissot, E. Rivire, N. Claiser and C. Lecomte pp 4729–4736 DOI: 10.1021/ic802319c Supporting Info

Crystal Structure and Magnetic Properties of a New Chiral Manganese(II) Three-Dimensional Framework: Na3[Mn3(HCOO)9] Vernica Paredes-Garca, Andrs Vega, Miguel A. Novak, Maria G. F. Vaz and Denise A. Souza, Diego Venegas-Yazigi, Evgenia Spodine pp 4737–4742 DOI: 10.1021/ic8019292 Supporting Info

Direct Detection and Characterization of Chloride in the Active Site of the Low-pH Form of Sulfite Oxidase Using Electron Spin Echo Envelope Modulation Spectroscopy, Isotopic Labeling, and Density Functional Theory Calculations Eric L. Klein, Andrei V. Astashkin, Dmitry Ganyushin, Christoph Riplinger, Kayunta Johnson-Winters, Frank Neese and John H. Enemark pp 4743–4752 DOI: 10.1021/ic801787s Supporting Info

Enantiopure Tetranuclear Iron(III) Complexes Using Chiral Reduced Schiff Base Ligands: Synthesis, Structure, Spectroscopy, Magnetic Properties, and DFT Studies Reena Singh, Atanu Banerjee, Enrique Colacio and Kajal Krishna Rajak pp 4753–4762 DOI: 10.1021/ic802206q Supporting Info

Rates of Electron Self-Exchange Reactions between Oxo-Centered Ruthenium Clusters Are Determined by Orbital Overlap John C. Goeltz, Christina J. Hanson and Clifford P. Kubiak pp 4763–4767 DOI: 10.1021/ic8022024

Synthesis, Structure and Charge Transport Properties of Yb5Al2Sb6: A Zintl Phase with Incomplete Electron Transfer Iliya Todorov, Duck Young Chung, Linhui Ye, Arthur J. Freeman and Mercouri G. Kanatzidis pp 4768–4776 DOI: 10.1021/ic900035a Supporting Info

Regiospecific Intramolecular O-Demethylation of the Ligand by Action of Molecular Dioxygen on a Ferrous Complex: Versatile Coordination Chemistry of Dioxygen in FeCl2 Complexes with (2,3-Dimethoxyphenyl) α-Substituted Tripods in the tris(2-Pyridylmethyl)amine Series Laila Benhamou, Ahmed Machkour, Olaf Rotthaus, Mohammed Lachkar, Richard Welter and Dominique Mandon pp 4777–4786 DOI: 10.1021/ic802359z Supporting Info

Molecular CoIII/FeII Cyano-Bridged Mixed-Valence Compounds with High Nuclearities and Diversity of CoIII Coordination Environments: Preparative and Mechanistic Aspects Paul V. Bernhardt, Manuel Martnez and Carlos Rodrguez pp 4787–4797 DOI: 10.1021/ic802198s Supporting Info

Local Coordination of Fe3+ in Layered LiCo1−yAlyO2 Oxides Determined by High-Frequency Electron Paramagnetic Resonance Spectroscopy R. Stoyanova, A.-L. Barra, E. Zhecheva, R. Alcntara, G. Ortiz and J.-L. Tirado pp 4798–4805 DOI: 10.1021/ic802228e

Semiorganic Nonlinear Optical Material: Preparation and Properties of (NH4)·Sr[l-(+)-C4H2O6·B(OH)2]·4H2O Xiaoyun Fan, Shilie Pan, Xueling Hou, Gang Liu and Jide Wang pp 4806–4810 DOI: 10.1021/ic802448z Supporting Info

Building Alkali-Metal-Halide Layers within a Perovskite Host by Sequential Intercalation: (A2Cl)LaNb2O7 (A = Rb, Cs) Jonglak Choi, Xiao Zhang and John B. Wiley pp 4811–4816 DOI: 10.1021/ic802344b Supporting Info

(Ni2), (Ni3), and (Ni2 + Ni3): A Unique Example of Isolated and Cocrystallized Ni2 and Ni3 Complexes Pampa Mukherjee, Michael G. B. Drew, Carlos J. Gmez-Garca and Ashutosh Ghosh pp 4817–4827 DOI: 10.1021/ic802385c Supporting Info

Iron(II) Complexes with Redox-Active Tetrazene (RNNNNR) Ligands Ryan E. Cowley, Eckhard Bill, Frank Neese, William W. Brennessel and Patrick L. Holland pp 4828–4836 DOI: 10.1021/ic900001y Supporting Info

Mixed-Metal Assemblies Based on Cyanide-Bridged Cubane-Type Mo3CuS4/Mo3S4 Clusters and Molybdenum Carbonyls Rosa Llusar, Ivan Sorribes and Cristian Vicent pp 4837–4846 DOI: 10.1021/ic9002302 Supporting Info

Novel Fluorescent Cationic Silver Thiosemicarbazone Clusters Containing Different Eight-Membered Ag4S4 Metallacycles Alfonso Castieiras and Rosa Pedrido pp 4847–4855 DOI: 10.1021/ic900062y Supporting Info

Photochemical Reduction of UO22+ in the Presence of Alcohol Studied by Density Functional Theory Calculations Satoru Tsushima pp 4856–4862 DOI: 10.1021/ic900066z Supporting Info

Fluxionality in a Paramagnetic Seven-Coordinate Iron(II) Complex: A Variable-Temperature, Two-Dimensional NMR and DFT Study David G. Lonnon, Graham E. Ball, Ivan Taylor, Donald C. Craig and Stephen B. Colbran pp 4863–4872 DOI: 10.1021/ic900233d Supporting Info

Copper Coordination Polymers Based on Single-Chain or Sheet Structures Involving Dinuclear and Tetranuclear Copper(II) Units: Synthesis, Structures, and Magnetostructural Correlations Santokh Singh Tandon, Scott D. Bunge, Douglas Motry, Jos Snchez Costa, Guillem Arom, Jan Reedijk and Laurence K. Thompson pp 4873–4881 DOI: 10.1021/ic900240y Supporting Info

Structural and Photoluminescence Studies of a Europium(III) Tetrakis(β-diketonate) Complex with Tetrabutylammonium, Imidazolium, Pyridinium and Silica-Supported Imidazolium Counterions Sofia M. Bruno, Rute A. S. Ferreira, Filipe A. Almeida Paz, Lus D. Carlos, Martyn Pillinger, Paulo Ribeiro-Claro and Isabel S. Gonalves pp 4882–4895 DOI: 10.1021/ic900274a Supporting Info

Photochemically-Induced Acid Generation from 18-Molybdodiphosphate and 18-Tungstodiphosphate within Poly(2-Hydroxyethyl Methacrylate) Films Antonios M. Douvas, Anna Kapella, Dimitra Dimotikali and Panagiotis Argitis pp 4896–4907 DOI: 10.1021/ic900295n Supporting Info

Self-Assembly of Hydroxy(phenyl)iodonium Ions in Acidic Aqueous Solution: Preparation, and X-ray Crystal Structures of Oligomeric Phenyliodine(III) Sulfates Victor N. Nemykin, Alexey Y. Koposov, Brian C. Netzel, Mekhman S. Yusubov and Viktor V. Zhdankin pp 4908–4917 DOI: 10.1021/ic900282k Supporting Info

Copper Phthalate Coordination Polymers Incorporating Kinked Dipyridyl Ligands: An Unprecedented 8-Connected Network and One-Dimensional Chiral Nanobarrels with Hydrophobic Channels Constructed from Septuple Helical Motifs Maxwell A. Braverman, Joseph H. Nettleman, Ronald M. Supkowski and Robert L. LaDuca pp 4918–4926 DOI: 10.1021/ic900331m Supporting Info

An Efficient Templating Approach for Synthesis of Highly Uniform CdTe and PbTe Nanowires Hai-Wei Liang, Shuo Liu, Qing-Song Wu and Shu-Hong Yu pp 4927–4933 DOI: 10.1021/ic900245w Supporting Info

Nickelacyclic-Cobaltocene vs. Nickelacyclic-Nickelocene. Synthesis, X-ray Structures, Electron Transfer Activity, EPR Spectroscopy, and Theoretical Calculations Piotr Buchalski, Elbieta Kamiska, Katarzyna Piwowar, Kinga Suwiska, Lucjan Jerzykiewicz, Fulvio Rossi, Franco Laschi, Fabrizia Fabrizi de Biani and Piero Zanello pp 4934–4941 DOI: 10.1021/ic900329w Supporting Info

Reversible Water Intercalation Accompanied by Coordination and Color Changes in a Layered Metal−Organic Framework Partha Mahata, K. V. Ramya and Srinivasan Natarajan pp 4942–4951 DOI: 10.1021/ic9003356 Supporting Info

Visible Light-Driven Hydrogen Production from Aqueous Protons Catalyzed by Molecular Cobaloxime Catalystspp 4952–4962 DOI: 10.1021/ic900389z Supporting Info

Formation and Reactivity of [(tacn)-N-CO-ReIIIBr(CO)2]+ in Water: a Theoretical and Experimental Study Fabio Zobi, Olivier Blacque, Gideon Steyl, Bernhard Spingler and Roger Alberto pp 4963–4970 DOI: 10.1021/ic9002803 Supporting Info

Zn3, Ni3, and Cu3 Complexes of a Novel Tricompartmental Acyclic Ligand Matilde Fondo, Noelia Ocampo, Ana M. Garca-Deibe and Jess Sanmartn pp 4971–4979 DOI: 10.1021/ic900292h Supporting Info

1D Coordination Polymers Constructed from anti−anti Carboxylato-Bridged MnIII3O(Brppz)3 Units: From Long-Range Magnetic Ordering to Single-Chain Magnet Behaviors Cai-Ming Liu, De-Qing Zhang and Dao-Ben Zhu pp 4980–4987 DOI: 10.1021/ic900345s Supporting Info

Temperature Dependence of Single-Crystal Elastic Constants of Flux-Grown α-GaPO4 P. Armand, M. Beaurain, B. Ruffl, B. Menaert and P. Papet pp 4988–4996 DOI: 10.1021/ic900146y

Ni(II)/H2O2 Reactivity in Bis[(pyridin-2-yl)methyl]amine Tridentate Ligand System. Aromatic Hydroxylation Reaction by Bis(μ-oxo)dinickel(III) Complex Atsushi Kunishita, Yoshitaka Doi, Minoru Kubo, Takashi Ogura, Hideki Sugimoto and Shinobu Itoh pp 4997–5004 DOI: 10.1021/ic900059m Supporting Info

Access to Carbaboranyl GlycophosphonatesAn Odyssey Sven Stadlbauer, Peter Welzel and Evamarie Hey-Hawkins pp 5005–5010 DOI: 10.1021/ic9004278

Synthesis and Structural Analysis of Half-Titanocenes Containing η2-Pyrazolato Ligands, and Their Use in Catalysis for Ethylene Polymerization Irfan Saeed, Shohei Katao and Kotohiro Nomura pp 5011–5020 DOI: 10.1021/ic9004246 Supporting Info

Syntheses and Crystal Structures of Ruthenium and Rhodium Olefin Complexes Containing GaCp Thomas Cadenbach, Christian Gemel, Timo Bollermann and Roland A. Fischer pp 5021–5026 DOI: 10.1021/ic802283r Supporting Info

Alkylation of a Dimolybdenum SO Bridge, Subsequent Reactions, and Characterization of the Thioperoxide Bridge Chi Minh Tuong, Whitney K. Hammons, Ashley L. Howarth, Kelly E. Lutz, Ackim D. Maduvu, Laura B. Haysley, Brian R. T. Allred, Lenore K. Hoyt, Mark S. Mashuta and Mark E. Noble pp 5027–5038 DOI: 10.1021/ic9002093 Supporting Info

Formation and Interconversion of Organo-Cobalt Complexes in Reactions of Cobalt(II) Porphyrins with Cyanoalkyl Radicals and Vinyl Olefins Chi-How Peng, Shan Li and Bradford B. Wayland pp 5039–5046 DOI: 10.1021/ic900384n Supporting Info

Preface for the Forum on Molecular Magnetism: The Role of Inorganic Chemistry Eugenio Coronado and Kim R. Dunbar p 5047 DOI: 10.1021/ic900736y

Electron Exchange Involving a Sulfur-Stabilized Ruthenium Radical Cation Anthony P. Shaw, Bradford L. Ryland, Jack R. Norton,*, Daniela Buccella and Alberto Moscatelli p 5048 DOI: 10.1021/ic900661z

Issue 12

A Mn17 Octahedron with a Giant Ground-State Spin: Occurrence in Discrete Form and as Multidimensional Coordination Polymers Eleni E. Moushi, Theocharis C. Stamatatos, Wolfgang Wernsdorfer, Vassilios Nastopoulos, George Christou and Anastasios J. Tasiopoulos pp 5049–5051 DOI: 10.1021/ic801795x Supporting Info

Crystal Structure of Na2Mg2NiH6 Revisited Maria Orlova, Jean-Philippe Rapin and Klaus Yvon pp 5052–5054 DOI: 10.1021/ic802417a Supporting Info

Molecular Uranates: Laser Synthesis of Uranium Oxide Anions in the Gas Phase Joaquim Maralo, Marta Santos, Antnio Pires de Matos and John K. Gibson pp 5055–5057 DOI: 10.1021/ic9003998

A Base-Stabilized Silylene with a Tricoordinate Silicon Atom as a Ligand for a Metal Complex Wei Yang, Hao Fu, Haijun Wang, Mingqing Chen, Yuqiang Ding, Herbert W. Roesky and Anukul Jana pp 5058–5060 DOI: 10.1021/ic900204c Supporting Info

Recognition Preference of Rhodamine-Thiospirolactams for Mercury(II) in Aqueous Solution Wei Huang, Chunxia Song, Cheng He, Guojun Lv, Xiaoyue Hu, Xiang Zhu and Chunying Duan pp 5061–5072 DOI: 10.1021/ic8015657 Supporting Info

A Family of Polynuclear Clusters Containing Cyano-Bridged T-Shaped FeIII3MII (M = Cu, Co, Mn) Metal Cores: Syntheses, Structures, and Magnetic Properties Zhi-Guo Gu, Yi-Fan Xu, Ling-Chen Kang, Yi-Zhi Li, Jing-Lin Zuo and Xiao-Zeng You pp 5073–5080 DOI: 10.1021/ic8023524 Supporting Info

Synthesis, Characterization, and Reactivity of Nickel Hydride Complexes Containing 2,6-C6H3(CH2PR2)2 (R = tBu, cHex, and iPr) Pincer Ligands Brian J. Boro, Eileen N. Duesler, Karen I. Goldberg and Richard A. Kemp pp 5081–5087 DOI: 10.1021/ic8020194 Supporting Info

Kinetic versus Thermodynamic Isomers of the Deltahedral Cobaltadicarbaboranes R. Bruce King, Ioan Silaghi-Dumitrescu and Ioana ovago pp 5088–5095 DOI: 10.1021/ic8020904 Supporting Info

Amine, Amido, and Imido Complexes of Tantalum Supported by a Pyridine-Linked Bis(phenolate) Pincer Ligand: Ta−N π-Bonding Influences Pincer Ligand Geometry Ian A. Tonks, Larry M. Henling, Michael W. Day and John E. Bercaw pp 5096–5105 DOI: 10.1021/ic802234x Supporting Info

Ligand Dependence of Binding to Three-Coordinate Fe(II) Complexes Karen P. Chiang, Pamela M. Barrett, Feizhi Ding, Jeremy M. Smith, Savariraj Kingsley, William W. Brennessel, Meghan M. Clark, Rene J. Lachicotte and Patrick L. Holland pp 5106–5116 DOI: 10.1021/ic802440h Supporting Info

Size Effects in the Oriented-Attachment Growth Process: The Case of Cu Nanoseeds Shuling Shen, Jing Zhuang, Xiangxing Xu, Amjad Nisar, Shi Hu and Xun Wang pp 5117–5128 DOI: 10.1021/ic900394z Supporting Info

Conjugate Base of a Secondary Phosphine Selenide [P(Se)(OiPr)2]− as the Bridging Unit for the Construction of Heterometallic Fe(II)−Hg(II)/Cd(II) Complexes Bijay Sarkar, Sung-Yin Wen, Jyun-Hua Wang, Ling-Song Chiou, Ping-Kuei Liao, Bidyut Kumar Santra, Ju-Chun Wang and C. W. Liu pp 5129–5140 DOI: 10.1021/ic8024556 Supporting Info

Synthesis, Short-Range Structure, and Electrochemical Properties of New Phases in the Li−Mn−N−O System Jordi Cabana, Nicolas Dupr, Frdric Gillot, Alan V. Chadwick, Clare P. Grey and M. Rosa Palacn pp 5141–5153 DOI: 10.1021/ic900082u Supporting Info

Organometallic [Re(CO)3]+ and [Re(CO)2(NO)]2+ Labeled Substrates for Human Thymidine Kinase 1 Harriet Struthers, Adelheid Hagenbach, Ulrich Abram and Roger Schibli pp 5154–5163 DOI: 10.1021/ic9000126 Supporting Info

Density-Functional Theory Study of the Stereochemistry of Chloroiron(III) and Chloromanganese(III) Complexes of a Bridled Chiroporphyrin Latvi Max Lawson Daku, Anna Castaings and Jean-Claude Marchon pp 5164–5176 DOI: 10.1021/ic900031c Supporting Info

In Situ Ligand Transformation in the Synthesis of Manganese Complexes: Mono-, Tri- and a Barrel-shaped Tetradeca-nuclear MnII14 Aggregate Muhammad Usman Anwar, Yanhua Lan, Lianne M. C. Beltran, Rodolphe Clrac, Sven Pfirrmann, Christopher E. Anson and Annie K. Powell pp 5177–5186 DOI: 10.1021/ic9001048 Supporting Info

Spectroscopy and Electronic Structures of Ru2(ap)4-alkynyl Compounds Lei Zhang, Bin Xi, Isiah Po-Chun Liu, M. M. R. Choudhuri, Robert J. Crutchley, James B. Updegraff, John D. Protasiewicz and Tong Ren pp 5187–5194 DOI: 10.1021/ic9000973 Supporting Info

Binuclear Cobalt Complexes of Schiff-Base Calixpyrroles and Their Roles in the Catalytic Reduction of Dioxygen Manuel Volpe, Heather Hartnett, James W. Leeland, Kathryn Wills, Marianne Ogunshun, Bridgette J. Duncombe, Claire Wilson, Alexander J. Blake, Jon McMaster and Jason B. Love pp 5195–5207 DOI: 10.1021/ic9001175 Supporting Info

Expanding the pH Range of Metal−Nucleobase Complexes for Acid−Base Chemistry: Properties of Bis(guanine) Complexes of (bpy)PtII with Either Two Major or Major and Minor Tautomers Bonded Simultaneously Pilar Brandi-Blanco, Pablo J. Sanz Miguel, Barbara Mller, Elisa Gil Bardaj, Michael Willermann and Bernhard Lippert pp 5208–5215 DOI: 10.1021/ic900176c Supporting Info

Neutron Diffraction, Electronic Band Structure, and Electrical Resistivity of Mo3−xRuxSb7 Christophe Candolfi, Bertrand Lenoir, Juliusz Leszczynski, Anne Dauscher, Janusz Tobola, Simon J. Clarke and Ron I. Smith pp 5216–5223 DOI: 10.1021/ic900171u Supporting Info

Establishing the Binding Affinity of Organic Carboxylates to 15-Metallacrown-5 Complexes Choong-Sun Lim, Jeff W. Kampf and Vincent L. Pecoraro pp 5224–5233 DOI: 10.1021/ic9001829 Supporting Info

Cobalt Complex as Building Blocks: Synthesis, Characterization, and Catalytic Applications of {Cd2+−Co3+−Cd2+} and {Hg2+−Co3+−Hg2+} Heterobimetallic Complexes Anurag Mishra, Afsar Ali, Shailesh Upreti, M. Stanley Whittingham and Rajeev Gupta pp 5234–5243 DOI: 10.1021/ic900223f Supporting Info

Ferromagnetic Coupling by Spin Polarization in a Trinuclear Copper(II) Metallacyclophane with a Triangular Cage-Like Structure Marie-Claire Dul, Xavier Ottenwaelder, Emilio Pardo, Rodrigue Lescouzec, Yves Journaux, Lise-Marie Chamoreau, Rafael Ruiz-Garca, Joan Cano, Miguel Julve and Francesc Lloret pp 5244–5249 DOI: 10.1021/ic9002274 Supporting Info

Self-Assembly of Luminescent Alkynyl-Based Platinum−Cadmium Complexes Containing Auxiliary Diimine or Terpyridine Ligands. Jess R. Berenguer, Beln Gil, Julio Fernndez, Juan Fornis and Elena Lalinde pp 5250–5262 DOI: 10.1021/ic9002109 Supporting Info

Porous Metal-Organic Frameworks Based on an Anthracene Derivative: Syntheses, Structure Analysis, and Hydrogen Sorption Studies Shengqian Ma, Jason M. Simmons, Daofeng Sun, Daqiang Yuan and Hong-Cai Zhou pp 5263–5268 DOI: 10.1021/ic900217t Supporting Info

Synthesis of Lithium N-pentafluorophenyl, N′-trimethylsilyl 2-Pyridylamidinate and Its Cyclization to Lithium Tetrafluoro-2-(2-pyridyl)benzimidazolate via a Me3SiF Elimination. Coordination Chemistry, Reactivity, and Mechanism Sinai Aharonovich, Mark Botoshanski and Moris S. Eisen pp 5269–5278 DOI: 10.1021/ic9002065 Supporting Info

Blue-, Green- and Non-luminescent Crystals from One Reaction. Isolation and Structural Characterization of a Series of Gold(I)-Siver(I) Heterometallic Complexes Utilizing a Gold Carbene Metalloligand Containing Free Amino Groups Daniel Rios, Marilyn M. Olmstead and Alan L. Balch pp 5279–5287 DOI: 10.1021/ic900243v Supporting Info

Development of Five-Coordinate Zinc Mono- and Dithiolates as S-Donor Metalloligands: Formation of a Zn−W Coordination Polymer Elky Almaraz, William S. Foley, Jason A. Denny, Joseph H. Reibenspies, Melissa L. Golden and Marcetta Y. Darensbourg pp 5288–5295 DOI: 10.1021/ic900261s Supporting Info

High-Temperature Order−Disorder Transition in CoCr2Se4 and Trapping Co Disorder in Monoclinic CoCr2Se4: Structural Features of Cu1−xCoxCr2Se4 Phases Volodymyr Svitlyk and Yurij Mozharivskyj pp 5296–5302 DOI: 10.1021/ic900264x Supporting Info

Volatility, High Thermal Stability, and Low Melting Points in Heavier Alkaline Earth Metal Complexes Containing Tris(pyrazolyl)borate Ligands Mark J. Saly, Mary Jane Heeg and Charles H. Winter pp 5303–5312 DOI: 10.1021/ic900342j Supporting Info

Synthesis and Structural and Physical Properties of New Semiconducting Quaternary Tellurides: Ba4Ag3.95Ge2Te9 and Ba4Cu3.71Ge2Te9 Yanjie Cui, Abdeljalil Assoud and Holger Kleinke pp 5313–5319 DOI: 10.1021/ic9002884 Supporting Info

Donor-Dictated Interlocking Co-Complexation Reactions of LiNHDipp with Dimethylzinc: Synthesis and Structures of New Methyl(amido)zincates William Clegg, David V. Graham, Emma Herd, Eva Hevia, Alan R. Kennedy, Matthew D. McCall and Luca Russo pp 5320–5327 DOI: 10.1021/ic900313b Supporting Info

Structures from Powders: Polynuclear Hg(II) Complexes Containing the Flexible Bisimidazolylmethane Ligand Norberto Masciocchi, Alessandro Figini Albisetti, Angelo Sironi, Claudio Pettinari, Corrado Di Nicola and Riccardo Pettinari pp 5328–5337 DOI: 10.1021/ic900320h Supporting Info

Synthesis, Structural and Magnetochemical Studies of Iron Phosphonate Cages Based on {Fe3O}7+ Core Sumit Khanra, Sanjit Konar, Abraham Clearfield, Madeleine Helliwell, Eric J. L. McInnes, Evangelos Tolis, Floriana Tuna and Richard E. P. Winpenny pp 5338–5349 DOI: 10.1021/ic9003214 Supporting Info

The Sulfate Coordination of Np(IV), Np(V), and Np(VI) in Aqueous Solution Christoph Hennig, Atsushi Ikeda-Ohno, Satoru Tsushima and Andreas C. Scheinost pp 5350–5360 DOI: 10.1021/ic9003005 Supporting Info

Theoretical Analysis of Bonding in N-Heterocyclic Carbene−Rhodium Complexes Monika Srebro and Artur Michalak pp 5361–5369 DOI: 10.1021/ic900336r

Structures and Energetics of AlnHn2− (5 ≤ n ≤ 12) and AlnHn+2 (4 ≤ n ≤ 12): Are Alanes the Borane Analogues? Li-juan Fu, Hong-bin Xie and Yi-hong Ding pp 5370–5375 DOI: 10.1021/ic900401f Supporting Info

Experimental Insight into the Radiation Resistance of Zirconia-Based Americium Ceramics Renaud C. Belin, Philippe M. Martin, Philippe J. Valenza and Andreas C. Scheinost pp 5376–5381 DOI: 10.1021/ic900369b

Volatility and High Thermal Stability in Tantalum Complexes Containing Imido, Amidinate, and Halide or Dialkylamide Ligands Monika K. Wiedmann, Mary Jane Heeg and Charles H. Winter pp 5382–5391 DOI: 10.1021/ic900454g Supporting Info

Sensitivity of Ru(bpy)2dppz2+ Luminescence to DNA Defects Mi Hee Lim, Hang Song, Eric D. Olmon, Elizabeth E. Dervan and Jacqueline K. Barton pp 5392–5397 DOI: 10.1021/ic900407n

Investigation of Gas Adsorption Performances and H2 Affinities of Porous Metal-Organic Frameworks with Different Entatic Metal Centers Shengqian Ma, Daqiang Yuan, Jong-San Chang and Hong-Cai Zhou pp 5398–5402 DOI: 10.1021/ic900475q Supporting Info

Centric and Non-centric Ca3Au7.5Ge3.5: Electron-Poor Derivatives of La3Al11. Syntheses, Structures, and Bonding Analyses Qisheng Lin and John D. Corbett pp 5403–5411 DOI: 10.1021/ic900383d Supporting Info

Hydrothermal Syntheses and Characterizations of Thioarsenates [Fe(phen)3][As3S6]·dien·7H2O and [Mn2(phen)4(As2S5)]·phen·2H2O: A New Coordination Mode of the As2S54− Anion Yingli Pan, Qinyan Jin, Jiangfang Chen, Yong Zhang and Dingxian Jia pp 5412–5417 DOI: 10.1021/ic9003615 Supporting Info

Catalytic Dehydrogenation of Ammonia Borane at Ni Monocarbene and Dicarbene Catalysts Paul M. Zimmerman, Ankan Paul and Charles B. Musgrave pp 5418–5433 DOI: 10.1021/ic900417z Supporting Info

Antiferromagnetism and Spin Reorientation in “PbCrO3” ngel M. Arvalo-Lpez, Antonio J. Dos santos-Garca and Miguel . Alario-Franco pp 5434–5438 DOI: 10.1021/ic900423w Supporting Info

Stability and Reactivity of Grafted Cr(CO)3 Species on MOF Linkers: A Computational Study Jenny G. Vitillo, Elena Groppo, Silvia Bordiga, Sachin Chavan, Gabriele Ricchiardi and Adriano Zecchina pp 5439–5448 DOI: 10.1021/ic9004664 Supporting Info

Synthesis and Characterization of a Fluorotitanophosphate (NH4)0.16K1.84[Ti2F2(PO4)2(PO3OH)] with a Unique Lamella Framework Sihai Yang, Guobao Li, Wei Liu, Wei Wang, Zhimin Yan, Yining Huang, Fuhui Liao and Jianhua Lin pp 5449–5453 DOI: 10.1021/ic900504m Supporting Info

New Types of 3D Organically Templated Zn2+/Cd2+−Cu+ Mixed Metal Sulfites Pei-Xin Li, Chun-Li Hu, Qi-Pu Lin, Na Zhao and Jiang-Gao Mao pp 5454–5461 DOI: 10.1021/ic900487j Supporting Info

Imidazolin-2-iminato Complexes of Rare Earth Metals with Very Short Metal−Nitrogen Bonds: Experimental and Theoretical Studies Tarun K. Panda, Alexandra G. Trambitas, Thomas Bannenberg, Cristian G. Hrib, Sren Randoll, Peter G. Jones and Matthias Tamm pp 5462–5472 DOI: 10.1021/ic900503q Supporting Info

Magnetic Coupling between Copper(II) Ions Mediated by Hydrogen-Bonded (Neutral) Water Molecules Jinkui Tang, Jos Snchez Costa, Amalija Golobi, Bojan Kozlevar, Arturo Robertazzi, Attilio V. Vargiu, Patrick Gamez and Jan Reedijk pp 5473–5479 DOI: 10.1021/ic900507w Supporting Info

Synthesis and Structural Characterization of Five-Coordinate Aluminum Complexes Containing Diarylamido Diphosphine Ligands Pei-Ying Lee and Lan-Chang Liang pp 5480–5487 DOI: 10.1021/ic802030d Supporting Info

Rational Design and Assembly of a New Series of Cyanide-Bridged FeIII−MnII One-Dimensional Single Chain Complexes: Synthesis, Crystal Structures, and Magnetic Properties Daopeng Zhang, Hailong Wang, Yuting Chen, Zhong-Hai Ni, Laijin Tian and Jianzhuang Jiang pp 5488–5496 DOI: 10.1021/ic900483z Supporting Info

Incommensurate Stistaite—Order Made to Order S. Lidin, J. Christensen, K. Jansson, D. Fredrickson, R. Withers, L. Norn and S. Schmid pp 5497–5503 DOI: 10.1021/ic900496p

Paramagnetic Effects on the NMR Spectra of “Diamagnetic” Ruthenium(bis-phosphine)(bis-semiquinone) Complexes Boris Le Guennic, Tavon Floyd, Brandon R. Galan, Jochen Autschbach and Jerome B. Keister pp 5504–5511 DOI: 10.1021/ic802302v Supporting Info

Self-Assembly of the First Discrete 3d−4f−4f Triple-Stranded Helicate Thomas Riis-Johannessen, Grald Bernardinelli, Yaroslav Filinchuk, Sarah Clifford, Natalia Dalla Favera and Claude Piguet pp 5512–5525 DOI: 10.1021/ic900654m Supporting Info

Indium Complexes Supported by 1,ω-Dithiaalkanediyl-Bridged Bis(phenolato) Ligands: Synthesis, Structure, and Controlled Ring-Opening Polymerization of l-Lactide Ilja Peckermann, Andreas Kapelski, Thomas P. Spaniol and Jun Okuda pp 5526–5534 DOI: 10.1021/ic900161w Supporting Info

Asymmetric Synthesis of Diphosphine Ligands Containing Phosphorus and Carbon Stereogenic Centers by Means of a Chiral Palladium Complex Promoted Hydrophosphination Reaction Yi Zhang, Sumod A. Pullarkat, Yongxin Li and Pak-Hing Leung pp 5535–5539 DOI: 10.1021/ic900461t Supporting Info

On the Search for NNO-Donor Enantiopure Scorpionate Ligands and Their Coordination to Group 4 Metals Antonio Otero, Juan Fernndez-Baeza, Juan Tejeda, Agustn Lara-Snchez, Margarita Snchez-Molina, Sonia Franco, Isabel Lpez-Solera and Ana M. Rodrguez, Luis F. Snchez-Barba, Sonia Morante-Zarcero and Andrs Garcs pp 5540–5554 DOI: 10.1021/ic900352e Supporting Info

Experimental Evidence for the Participation of 5d GdIII Orbitals in the Magnetic Interaction in Ni−Gd Complexes Jean-Pierre Costes, Tomoka Yamaguchi, Masaaki Kojima and Laure Vendier pp 5555–5561 DOI: 10.1021/ic900142h Supporting Info

NHC-Derived Bis(amidiniophosphine) Ligands of Rh(I) Complexes: Versatile cis−trans Chelation Driven by an Interplay of Electrostatic and Orbital Effects Yves Canac, Nathalie Debono, Laure Vendier and Remi Chauvin pp 5562–5568 DOI: 10.1021/ic900348x

Synthesis of New Red-Emitting Single-Phase Europium Oxycarbonate Vilas G. Pol, Jose M. Calderon-Moreno, Monica Popa, Somobratra Acharya, Katsuhiko Ariga and P. Thiyagarajan pp 5569–5573 DOI: 10.1021/ic900290b

The First Structurally Characterized Metal (κ2N,P)-Phosphinohydrazides: The Key to Understanding the Intramolecular Rearrangement R2P−NR′−NR′−M → R′N═PR2−NR′−M. Metalloderivatives of Diisopropylphosphinohydrazines: Synthesis and Properties Alexander N. Kornev, Natalia V. Belina, Vyacheslav V. Sushev, Georgy K. Fukin, Evgenii V. Baranov, Yuriy A. Kurskiy, Andrei I. Poddelskii, Gleb A. Abakumov, Peter Lnnecke and Evamarie Hey-Hawkins pp 5574–5583 DOI: 10.1021/ic900135b Supporting Info

Mixed Valence Creutz−Taube Ion Analogues Incorporating Thiacrowns: Synthesis, Structure, Physical Properties, and Computational Studies Harry Adams, Paulo J. Costa, Mike Newell, Steven J. Vickers, Michael D. Ward, Vtor Flix and Jim A. Thomas p 5584 DOI: 10.1021/ic900536a Supporting Info

Nanomodulation of Molecular Nanomagnets Patrick L. Feng, Changhyun Koo, John J. Henderson, Paul Manning, Motohiro Nakano, Enrique del Barco, , Stephen Hill and David N. Hendrickson* p 5585 DOI: 10.1021/ic900828v

Intensely Luminescent Alkynyl-Phosphine Gold(I)−Copper(I) Complexes: Synthesis, Characterization, Photophysical, and Computational Studies Igor O. Koshevoy, Yi-Chih Lin, Antti J. Karttunen, Pi-Tai Chou, Pirjo Vainiotalo, Sergey P. Tunik, Matti Haukka and Tapani A. Pakkanen p 5586 DOI: 10.1021/ic900867k

Issue 13

Synthesis of Bis(imino)pyridine Iron Amide and Ammonia Compounds from an N−H Transfer Agent Amanda C. Bowman, Suzanne C. Bart, Frank W. Heinemann, Karsten Meyer and Paul J. Chirik pp 5587–5589 DOI: 10.1021/ic9003017 Supporting Info

Construction of Coordination-Driven Self-Assembled [5 + 5] Pentagons Using Metal−Carbonyl Dipyridine Ligands Liang Zhao, Koushik Ghosh, Yaorong Zheng, Matthew M. Lyndon, Taufika Islam Williams and Peter J. Stang pp 5590–5592 DOI: 10.1021/ic900649m Supporting Info

Highly Efficient Isobutyraldehyde-Mediated Epoxidation of Cyclic Alkenes with Dioxygen Catalyzed by a Novel Dimeric Manganese(II) Complex Containing an Easy-to-Prepare Flexible Carboxamide Ligand Hamid Reza Khavasi, Koroush Sasan, Mahtab Pirouzmand and Samad Nejad Ebrahimi pp 5593–5595 DOI: 10.1021/ic900334w Supporting Info

Structurally Characterized Iridium(III)-Containing Polytungstate and Catalytic Water Oxidation Activity Rui Cao, Huiyuan Ma, Yurii V. Geletii, Kenneth I. Hardcastle and Craig L. Hill pp 5596–5598 DOI: 10.1021/ic900538g Supporting Info

In Vitro Transcription Inhibition by Ruthenium(II) Polypyridyl Complexes with Electropositive Ancillary Ligands Feng Gao, Xing Chen, Jin-Quan Wang, Yu Chen, Hui Chao and Liang-Nian Ji pp 5599–5601 DOI: 10.1021/ic900902f Supporting Info

Structural and Dynamic Properties of BaInGeH: A Rare Solid-State Indium Hydride Michael J. Evans, Verina F. Kranak, Francisco J. Garcia-Garcia, Gregory P. Holland, Luke L. Daemen, Thomas Proffen, Myeong H. Lee, Otto F. Sankey and Ulrich Hussermann pp 5602–5604 DOI: 10.1021/ic9005423 Supporting Info

S-Nitrosothiol and Nitric Oxide Reactivity at Zinc Thiolates Matthew S. Varonka and Timothy H. Warren pp 5605–5607 DOI: 10.1021/ic900664r Supporting Info

Density Functional Theory Studies of Structural Deformation in Bis(alkynyl)diruthenium(III): Stronger Ru−Ru Bonding by Any Means Necessary Isiah Po-Chun Liu and Tong Ren pp 5608–5610 DOI: 10.1021/ic900795d Supporting Info

Highly Luminescent Homoleptic Europium Chelates Nail M. Shavaleev, Frdric Gumy, Rosario Scopelliti and Jean-Claude G. Bnzli pp 5611–5613 DOI: 10.1021/ic9006372 Supporting Info

Monodisperse F-Substituted Hydroxyapatite Single-Crystal Nanotubes with Amphiphilic Surface Properties Junfeng Hui, Guolei Xiang, Xiangxing Xu, Jing Zhuang and Xun Wang pp 5614–5616 DOI: 10.1021/ic900697b Supporting Info

Octacyanometalate-Based Ferrimagnetic MVMnIII (M = Mo, W) Bimetallic Chain Racemates with Slow Magnetic Relaxations Houng Sik Yoo, Hyun Hee Ko, Dae Won Ryu, Jin Wuk Lee, Jung Hee Yoon, Woo Ram Lee, Hyoung Chan Kim, Eui Kwan Koh and Chang Seop Hong pp 5617–5619 DOI: 10.1021/ic900879d Supporting Info

Versatile Methodology Toward NiN2S2 Complexes as Nickel Superoxide Dismutase Models: Structure and Proton Affinity Eric M. Gale, Ashis K. Patra and Todd C. Harrop pp 5620–5622 DOI: 10.1021/ic9009042 Supporting Info

Dramatic Solid-State Humidity-Induced Modification of the Magnetic Coupling in a Dimeric Fluorous Copper(II)−Carboxylate Complex Artur Motreff, Rosenildo Correa da Costa, Hassan Allouchi, Mathieu Duttine, Corine Mathonire, Carole Duboc and Jean-Marc Vincent pp 5623–5625 DOI: 10.1021/ic9005218 Supporting Info

New Porphyrins Bearing Pyridyl Peripheral Groups Linked by Secondary or Tertiary Sulfonamide Groups: Synthesis and Structural Characterization Janet Manono, Patricia A. Marzilli, Frank R. Fronczek and Luigi G. Marzilli pp 5626–5635 DOI: 10.1021/ic900600z Supporting Info

New Porphyrins Bearing Positively Charged Peripheral Groups Linked by a Sulfonamide Group to meso-Tetraphenylporphyrin: Interactions with Calf Thymus DNA Janet Manono, Patricia A. Marzilli and Luigi G. Marzilli pp 5636–5647 DOI: 10.1021/ic900385y Supporting Info

Microcrystalline Hexagonal Tungsten Bronze. 1. Basis of Ion Exchange Selectivity for Cesium and Strontium Christopher S. Griffith, Vittorio Luca, John V. Hanna, Kevin J. Pike, Mark E. Smith and Gordon S. Thorogood pp 5648–5662 DOI: 10.1021/ic801294x Supporting Info

Microcrystalline Hexagonal Tungsten Bronze. 2. Dehydration Dynamics Vittorio Luca, Christopher S. Griffith and John V. Hanna pp 5663–5676 DOI: 10.1021/ic801295c

Expanding the Coordination Cage: A Ruthenium(II)−Polypyridine Complex Exhibiting High Quantum Yields under Ambient Conditions Frank Schramm, Velimir Meded, Heike Fliegl, Karin Fink, Olaf Fuhr, Zhirong Qu, Wim Klopper, Stephen Finn, Tia E. Keyes and Mario Ruben pp 5677–5684 DOI: 10.1021/ic802040v Supporting Info

Redox Chemistry and Electronic Properties of 2,3,5,6-Tetrakis(2-pyridyl)pyrazine-Bridged Diruthenium Complexes Controlled by N,C,N′-BisCyclometalated Ligands Sipke H. Wadman, Remco W. A. Havenith, Frantiek Hartl, Martin Lutz, Anthony L. Spek, Gerard P. M. van Klink and Gerard van Koten pp 5685–5696 DOI: 10.1021/ic801897k Supporting Info

Biphenolate Phosphine Complexes of Tantalum Lan-Chang Liang, Liang-Chien Cheng, Tzung-Ling Tsai, Ching-Han Hu and Wen-Hsin Guo pp 5697–5703 DOI: 10.1021/ic802125z Supporting Info

Photophysical Characteristics and Reactivity of Bis(2,9-di-tert-butyl-1,10-phenanthroline)copper(I) Omar Green, Bhavesh A. Gandhi and Judith N. Burstyn pp 5704–5714 DOI: 10.1021/ic802361q Supporting Info

Synthesis of Rare-Earth Metal Amides Bearing an Imidazolidine-Bridged Bis(phenolato) Ligand and Their Application in the Polymerization of l-Lactide Zhongjian Zhang, Xiaoping Xu, Wenyi Li, Yingming Yao, Yong Zhang, Qi Shen and Yunjie Luo pp 5715–5724 DOI: 10.1021/ic802177y Supporting Info

Water-Free Rare Earth-Prussian Blue Type Analogues: Synthesis, Structure, Computational Analysis, and Magnetic Data of {LnIII(DMF)6FeIII(CN)6}∞ (Ln = Rare Earths Excluding Pm) Duane C. Wilson, Shengming Liu, Xuenian Chen, Edward A. Meyers, Xiaoguang Bao, Andrey V. Prosvirin, Kim R. Dunbar, Christopher M. Hadad and Sheldon G. Shore pp 5725–5735 DOI: 10.1021/ic8022369 Supporting Info

Synthesis and Nanoscale Characterization of (NH4)4ThF8 and ThNF G. W. Chinthaka Silva, Charles B. Yeamans, Gary S. Cerefice, Alfred P. Sattelberger and Kenneth R. Czerwinski pp 5736–5746 DOI: 10.1021/ic900632g

On the Transport of Vanadium in Blood Serum Daniele Sanna, Giovanni Micera and Eugenio Garribba pp 5747–5757 DOI: 10.1021/ic802287s Supporting Info

Cadmium(II) Complex Formation with Cysteine and Penicillamine Farideh Jalilehvand, Bonnie O. Leung and Vicky Mah pp 5758–5771 DOI: 10.1021/ic802278r Supporting Info

Three New Heterothiometallic Cluster Polymers with Fascinating Topologies Zhaorui Pan, Jiao Xu, Hegen Zheng, Kexuan Huang, Yizhi Li, Zijian Guo and Stuart R. Batten pp 5772–5778 DOI: 10.1021/ic802457j Supporting Info

Electronic Structure and Spin Exchange Interactions in Na2V3O7: a Vanadium(IV) Oxide Nanotubular Phase Antonio Rodrguez-Fortea, Miquel Llunell, Pere Alemany and Enric Canadell pp 5779–5789 DOI: 10.1021/ic900105u

Assessing the Dependence of 51V Az Value on the Aromatic Ring Orientation of VIVO2+ Pyridine Complexes Giovanni Micera, Vincent L. Pecoraro and Eugenio Garribba pp 5790–5796 DOI: 10.1021/ic9001779 Supporting Info

Detection of Aqueous Mercuric Ion with a Structurally Simple 8-Hydroxyquinoline Derived ON-OFF Fluorosensor Kiran G. Vaswani and Mark D. Kernen pp 5797–5800 DOI: 10.1021/ic9004517 Supporting Info

Effects of Cyclen and Cyclam on Zinc(II)- and Copper(II)-Induced Amyloid β-Peptide Aggregation and Neurotoxicity Tingting Chen, Xiaoyong Wang, Yafeng He, Changli Zhang, Ziyi Wu, Kuo Liao, Jianjun Wang and Zijian Guo pp 5801–5809 DOI: 10.1021/ic900025x

Radical Bonding: Structure and Stability of Bis(Phenalenyl) Complexes of Divalent Metals from across the Periodic Table Smaranda Craciun and Kelling J. Donald pp 5810–5819 DOI: 10.1021/ic900058q Supporting Info

Hetero-Metallic {3d-4f-5d} Complexes: Preparation and Magnetic Behavior of Trinuclear [(LMe2Ni−Ln){W(CN)8}] Compounds (Ln = Gd, Tb, Dy, Ho, Er, Y; LMe2 = Schiff base) and Variable SMM Characteristics for the Tb Derivative Jean-Pascal Sutter, Sbastien Dhers, Raghunathan Rajamani, S. Ramasesha, Jean-Pierre Costes, Carine Duhayon and Laure Vendier pp 5820–5828 DOI: 10.1021/ic900003m Supporting Info

Electronic Structure of the [Tris(dithiolene)chromium]z (z = 0, 1−, 2−, 3−) Electron Transfer Series and Their Manganese(IV) Analogues. An X-ray Absorption Spectroscopic and Density Functional Theoretical Study Priyabrata Banerjee, Stephen Sproules, Thomas Weyhermller, Serena DeBeer George and Karl Wieghardt pp 5829–5847 DOI: 10.1021/ic900154v Supporting Info

The Crucial Role of Polyatomic Anions in Molecular Architecture: Structural And Magnetic Versatility of Five Nickel(II) Complexes Derived from A N,N,O-Donor Schiff Base Ligand Pampa Mukherjee, Michael G. B. Drew, Carlos J. Gmez-Garca and Ashutosh Ghosh pp 5848–5860 DOI: 10.1021/ic9001863 Supporting Info

Investigation of Flexible Organic Ligands in the Molybdate System: Delicate Influence of a Peripheral Cluster Environment on the Isopolymolybdate Frameworks Bao-xia Dong and Qiang Xu pp 5861–5873 DOI: 10.1021/ic900128t Supporting Info

Coordination Diversity of Aluminum Centers Molded by Triazole Based Chalcogen Ligands Jocelyn Alcntara-Garca, Vojtech Jancik, Joaqun Barroso, Sandra Hidalgo-Bonilla, Raymundo Cea-Olivares, Rubn A. Toscano and Mnica Moya-Cabrera pp 5874–5883 DOI: 10.1021/ic900166u Supporting Info

Copper-, Cobalt-, and Manganese-Containing 17-Tungsto-2-Germanates Nadeen H. Nsouli, Amal H. Ismail, Inga S. Helgadottir, Michael H. Dickman, Juan M. Clemente-Juan and Ulrich Kortz pp 5884–5890 DOI: 10.1021/ic900180x Supporting Info

Nanometer Length-Dependent Triplet−Triplet Energy Transfers in Zinc(II)Porphyrin/trans-Bis(ethynylbenzene)Platinum(II) Oligomers Li Liu, Daniel Fortin and Pierre D. Harvey pp 5891–5900 DOI: 10.1021/ic900198h Supporting Info

Phosphates Sensing: Two Polyamino-Phenolic Zinc Receptors Able to Discriminate and Signal Phosphates in Water Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Annalisa Guerri, Eleonora Macedi, Mauro Micheloni, Paola Paoli, Roberto Pontellini and Patrizia Rossi pp 5901–5912 DOI: 10.1021/ic900231h Supporting Info

Binuclear Complexes of Bis-Chelating Ligands Based on [1,4]Dioxocino[6,5-b:7,8-b′]dipyridine Moieties Marcello Casalino, Vincenzo De Felice, Natascia Fraldi, Achille Panunzi and Francesco Ruffo pp 5913–5920 DOI: 10.1021/ic900239z Supporting Info

Synthesis, Characterization, and Reactivity of Alkyldisulfanido Zinc Complexes Erwan Galardon, Alain Tomas, Mohamed Selkti, Pascal Roussel and Isabelle Artaud pp 5921–5927 DOI: 10.1021/ic900238v Supporting Info

Comparative Activities of Nickel(II) and Zinc(II) Complexes of Asymmetric [NN′O] Ligands as 26S Proteasome Inhibitors Michael Frezza, Sarmad Sahiel Hindo, Dajena Tomco, Marco M. Allard, Qiuzhi Cindy Cui, Mary Jane Heeg, Di Chen, Q. Ping Dou and Cludio N. Verani pp 5928–5937 DOI: 10.1021/ic900276g Supporting Info

Electronic Structure and Magnetic Properties of Potassium Ozonide KO3 Miquel Llunell, Pere Alemany and Ibrio de P. R. Moreira pp 5938–5945 DOI: 10.1021/ic900287h

Synthesis, Crystal Structures, and Luminescent Properties of Phenoxo-Bridged Heterometallic Trinuclear Propeller- and Sandwich-Like Schiff-Base Complexes Hailong Wang, Daopeng Zhang, Zhong-Hai Ni, Xiyou Li, Laijin Tian and Jianzhuang Jiang pp 5946–5956 DOI: 10.1021/ic9002862 Supporting Info

Electronic Structures of Scandium Oxide Endohedral Metallofullerenes, Sc4(μ3-O)n@Ih-C80 (n = 2, 3) Ramn Valencia, Antonio Rodrguez-Fortea, Steven Stevenson, Alan L. Balch and Josep M. Poblet pp 5957–5961 Supporting Info

Synthesis and Physical Properties of Double Perovskite Pb2FeReO6 Kousuke Nishimura, Masaki Azuma, Shigeto Hirai, Mikio Takano and Yuichi Shimakawa pp 5962–5966 DOI: 10.1021/ic900297q

Directed Synthesis of Crystalline Plutonium(III) and (IV) Oxalates: Accessing Redox-Controlled Separations in Acidic Solutions Wolfgang Runde, Lia F. Brodnax, George Goff, Amanda C. Bean and Brian L. Scott pp 5967–5972 DOI: 10.1021/ic900344u Supporting Info

Binuclear Cobalt Thiocarbonyl Carbonyl Derivatives: Comparison with Homoleptic Binuclear Cobalt Carbonyls Zhong Zhang, Qian-shu Li, Yaoming Xie, R. Bruce King and Henry F. Schaefer , III pp 5973–5982 DOI: 10.1021/ic9003824 Supporting Info

Luminescent and Magnetic Cyano-Bridged Coordination Polymers Containing 4d−4f Ions: Toward Multifunctional Materials Elena Chelebaeva, Joulia Larionova, Yannick Guari, Rute A. S. Ferreira, Luis D. Carlos, Filipe A. Almeida Paz, Alexander Trifonov and Christian Gurin pp 5983–5995 DOI: 10.1021/ic900378d Supporting Info

Zn5Sb4In2−δ — a Ternary Derivative of Thermoelectric Zinc Antimonides Yang Wu, Sven Lidin, Thomas L. Groy, N. Newman and Ulrich Hussermann pp 5996–6003 DOI: 10.1021/ic900302a Supporting Info

Isolation and Structural Characterization of Two Very Large, and Largely Empty, Endohedral Fullerenes: Tm@C3v-C94 and Ca@C3v-C94 Yuliang Che, Hua Yang, Zhimin Wang, Hongxiao Jin, Ziyang Liu, Chunxin Lu, Tianming Zuo, Harry C. Dorn, Christine M. Beavers, Marilyn M. Olmstead and Alan L. Balch pp 6004–6010 Supporting Info

Synthesis, Properties, and Live-Cell Imaging Studies of Luminescent Cyclometalated Iridium(III) Polypyridine Complexes Containing Two or Three Biotin Pendants Kenneth Yin Zhang and Kenneth Kam-Wing Lo pp 6011–6025 DOI: 10.1021/ic900412n

2D and 3D Polymeric Wells−Dawson Polyoxometelates: Synthesis, Crystal Structures, and Cyclic Voltammetry of [(M(H2O)4)x][H6−2xP2W18−nMonO62] (M = CuII, CoII, NiII) Robila Belghiche, Ouahiba Bechiri, Mostefa Abbessi, Stphane Golhen, Yann Le Gal and Lahcne Ouahab pp 6026–6033 DOI: 10.1021/ic9003406 Supporting Info

Syntheses and Structures of Blue-Luminescent Mercury(II) Complexes with 2,6-Bis(imino)pyridyl Ligands Ruiqing Fan, Yulin Yang, Yanbin Yin, WuLiJi Hasi and Ying Mu pp 6034–6043 DOI: 10.1021/ic900339u Supporting Info

Shape Evolution of New-Phased Lepidocrocite VOOH from Single-Shelled to Double-Shelled Hollow Nanospheres on the Basis of Programmed Reaction-Temperature Strategy Changzheng Wu, Xiaodong Zhang, Bo Ning, Jinlong Yang and Yi Xie pp 6044–6054 DOI: 10.1021/ic900416v Supporting Info

Accessing the Different Redox States of α-Iminopyridines within Cobalt Complexes Connie C. Lu, Thomas Weyhermller, Eckhard Bill and Karl Wieghardt pp 6055–6064 DOI: 10.1021/ic9004328 Supporting Info

Synthesis and Thermostructural Studies of a CuFe1−xCrxO2 Delafossite Solid Solution with 0 ≤ x ≤ 1 M. Lalanne, A. Barnab, F. Mathieu and Ph. Tailhades pp 6065–6071 DOI: 10.1021/ic900437x

Synthesis and Reactivity of ortho-Carbaborane-Containing Chiral Aminohalophosphines Sven Stadlbauer, Ren Frank, Ilham Maulana, Peter Lnnecke, Barbara Kirchner and Evamarie Hey-Hawkins pp 6072–6082 DOI: 10.1021/ic900443c Supporting Info

The Tris(trifluoromethyl)methyl Phosphonium Ion, P(CF3)3CH3+, Preparation and Structure Oleg Shyshkov, Uwe Dieckbreder, Thomas Drews, Alexander Kolomeitsev, Gerd-Volker Rschenthaler and Konrad Seppelt pp 6083–6085 DOI: 10.1021/ic900414q Supporting Info

Cobalt(II) Sheet-Like Systems Based on Diacetic Ligands: from Subtle Structural Variances to Different Magnetic Behaviors Oscar Fabelo, Jorge Pasn, Laura Caadillas-Delgado, Fernando S. Delgado, Francesc Lloret, Miguel Julve and Catalina Ruiz-Prez pp 6086–6095 DOI: 10.1021/ic9004483

Switching between κ2 and κ3 Bis(pyrazol-1-yl)acetate Ligands by Tuning Reaction Conditions: Synthesis, Spectral, Electrochemical, Structural, and Theoretical Studies on Arene-Ru(II) Derivatives of Bis(azol-1-yl)acetate Ligands Fabio Marchetti, Claudio Pettinari, Adele Cerquetella, Augusto Cingolani, Riccardo Pettinari, Magda Monari, Riccardo Wanke, Maxim L. Kuznetsov and Armando J. L. Pombeiro pp 6096–6108 DOI: 10.1021/ic900463b Supporting Info

Bimetallic Iron(3+) Spin-Crossover Complexes Containing a 2,2′-Bithienyl Bridging bis-QsalH Ligand Brandon Djukic, Prashanth K. Poddutoori, Paul A. Dube, Takele Seda, Hilary A. Jenkins and Martin T. Lemaire pp 6109–6116 DOI: 10.1021/ic9004938 Supporting Info

Diruthenium Tetracarbonate Trianion, [RuII/III2(O2CO)4]3−, Based Molecule-Based Magnets: Three-Dimensional Network Structure and Two-Dimensional Magnetic Ordering Bretni S. Kennon, Jae-Hyuk Her, Peter W. Stephens and Joel S. Miller pp 6117–6123 DOI: 10.1021/ic900470h Supporting Info

Platinum−Germanium Compounds from the Reactions of (COD)PtMe2 (COD = 1,5-cyclooctadiene) with HGePh3 Richard D. Adams and Eszter Trufan pp 6124–6129 DOI: 10.1021/ic9004888 Supporting Info

Thermal- and Light-Induced Spin Crossover in Novel 2D Fe(II) Metalorganic Frameworks {Fe(4-PhPy)2[MII(CN)x]y}·sH2O: Spectroscopic, Structural, and Magnetic Studies M. Seredyuk, A. B. Gaspar, V. Ksenofontov, M. Verdaguer, F. Villain and P. Gtlich pp 6130–6141 DOI: 10.1021/ic900491r Supporting Info

Antiferro- and Ferromagnetic Interactions in Mn(II), Co(II), and Ni(II) Compounds with Mixed Azide−Carboxylate Bridges Yu Ma, Jian-Yong Zhang, Ai-Ling Cheng, Qian Sun, En-Qing Gao and Cai-Ming Liu pp 6142–6151 DOI: 10.1021/ic900472d Supporting Info

Bismuth−Palladium Heterometallic Carboxylate as a Single-Source Precursor for the Carbon-Supported Pd−Bi/C Catalysts Bo Li, Haitao Zhang, Lan Huynh, Chantal Diverchy, Sophie Hermans, Michel Devillers and Evgeny V. Dikarev pp 6152–6158 DOI: 10.1021/ic900505v Supporting Info

Cleavage of Ni-(μ2-S)-Ni Bridges in Dinuclear Nickel(II) Dithiolate Pincer Complexes and Related Reactions Deguang Huang, Liang Deng, Jibin Sun and R. H. Holm pp 6159–6166 DOI: 10.1021/ic900494u Supporting Info

Trinuclear Iron Carbonyl Thiocarbonyls: the Preference for Four- and Six-Electron Donor Bridging Thiocarbonyl Groups over Metal−Metal Multiple Bonding, while Satisfying the 18-Electron Rule Zhong Zhang, Qian-shu Li, Yaoming Xie, R. Bruce King and Henry F. Schaefer, , III pp 6167–6177 DOI: 10.1021/ic900518s Supporting Info

Benzothiazole- and Benzoxazole-Substituted Pyridine-2-Carboxylates as Efficient Sensitizers of Europium Luminescence Nail M. Shavaleev, Rosario Scopelliti, Frdric Gumy and Jean-Claude G. Bnzli pp 6178–6191 DOI: 10.1021/ic9005136 Supporting Info

Tri-, Tetra-, and Hexanuclear Copper(II) Phosphonates Containing N-Donor Chelating Ligands: Synthesis, Structure, Magnetic Properties, and Nuclease Activity Vadapalli Chandrasekhar, Tapas Senapati, E. Carolina Saudo and R. Clrac pp 6192–6204 DOI: 10.1021/ic900522u Supporting Info

Azo Isocyanide Gold(I) Liquid Crystals, Highly Birefringent and Photosensitive in the Mesophase Javier Arias, Manuel Bardaj, Pablo Espinet, Csar L. Folcia, Josu Ortega and Jess Etxebarra pp 6205–6210 DOI: 10.1021/ic9005295 Supporting Info

Octahedral Monodithiolene Complexes of Cobalt(III) and Chromium(III). Spectroscopic and Density Functional Theoretical Characterization of S,S′-Coordinated Benzene-1,2-dithiolate(1-) π Radicals. Carsten Milsmann, Eberhard Bothe, Eckhard Bill, Thomas Weyhermller and Karl Wieghardt pp 6211–6221 DOI: 10.1021/ic900515j Supporting Info

Second-Order Nonlinear Optical Properties of Polyoxometalate Salts of a Chiral Stilbazolium Derivative Jean-Daniel Compain, Pierre Mialane, Anne Dolbecq, Jrme Marrot, Anna Proust, Keitaro Nakatani, Pei Yu and Francis Scheresse pp 6222–6228 DOI: 10.1021/ic900519p Supporting Info

Specific Supramolecular Interactions between Zn2+-Salophen Complexes and Biologically Relevant Anions Manoli Cano, Laura Rodrguez, Joo Carlos Lima, Fernando Pina, Antonella Dalla Cort, Chiara Pasquini and Luca Schiaffino pp 6229–6235 DOI: 10.1021/ic900557n Supporting Info

Tellurasiloxane Cages Containing Te6Si4O12 and Te6Si6O15 Frameworks Vadapalli Chandrasekhar and Ramalingam Thirumoorthi pp 6236–6241 DOI: 10.1021/ic900562n Supporting Info

Microstructures, Surface Properties, and Topotactic Transitions of Manganite Nanorods Tao Gao, Frank Krumeich, Reinhard Nesper, Helmer Fjellvg and Poul Norby pp 6242–6250 DOI: 10.1021/ic900565m Supporting Info

Multielectron Redox Activity Facilitated by Metal−Metal Interactions in Early/Late Heterobimetallics: Co/Zr Complexes Supported by Phosphinoamide Ligands Bennett P. Greenwood, Scott I. Forman, Gerard T. Rowe, Chun-Hsing Chen, Bruce M. Foxman and Christine M. Thomas pp 6251–6260 DOI: 10.1021/ic900552b Supporting Info

EuTM2Ga8 (TM = Co, Rh, Ir) — A Contribution to the Chemistry of the CeFe2Al8-type Compounds O. Sichevych, M. Kohout, W. Schnelle, H. Borrmann, R. Cardoso-Gil, M. Schmidt, U. Burkhardt and Yu. Grin pp 6261–6270 DOI: 10.1021/ic900573w

Preparation, Structure, and Metallophilic Interactions of Dinuclear Silver(I) and Copper(I) Complexes of Selenium Diimides Maarit Risto, Teemu T. Takaluoma, Tom Bajorek, Raija Oilunkaniemi, Risto S. Laitinen and Tristram Chivers pp 6271–6279 DOI: 10.1021/ic900551f Supporting Info

New Topology in Azide-Bridged Cobalt(II) Complexes: the Weak Ferromagnet [Co2(N3)4(Hexamethylenetetramine)(H2O)]n Franz A. Mautner, Lars hrstrm, Beate Sodin and Ramon Vicente pp 6280–6286 DOI: 10.1021/ic9005373 Supporting Info

Can Electrospray Mass Spectrometry Quantitatively Probe Speciation? Hydrolysis of Uranyl Nitrate Studied by Gas-Phase Methods Nikos G. Tsierkezos, Jana Roithov, Detlef Schrder, Milan Onk and Petr Slavek pp 6287–6296 DOI: 10.1021/ic900575r Supporting Info

Formation and Calculations of the Simple Terminal Triplet Pnictinidene Molecules N÷MF3, P÷MF3, and As÷MF3 (M = Ti, Zr, Hf) Xuefeng Wang, Jonathan T. Lyon and Lester Andrews pp 6297–6302 DOI: 10.1021/ic900633k

Substituent Effect on Oxygen Atom Transfer Reactivity from Oxomolybdenum Centers: Synthesis, Structure, Electrochemistry, and Mechanism Partha Basu, Victor N. Nemykin and Raghvendra S. Sengar pp 6303–6313 DOI: 10.1021/ic900579s Supporting Info

Synthesis and Fundamental Properties of Stable Ph3SnSiH3 and Ph3SnGeH3 Hydrides: Model Compounds for the Design of Si−Ge−Sn Photonic Alloys Jesse B. Tice, Andrew V. G. Chizmeshya, Thomas L. Groy and John Kouvetakis pp 6314–6320 DOI: 10.1021/ic900612s Supporting Info

Comparative Study of Uranyl(VI) and -(V) Carbonato Complexes in an Aqueous Solution Atsushi Ikeda, Christoph Hennig, Satoru Tsushima, Koichiro Takao, Yasuhisa Ikeda, Andreas C. Scheinost and Gert Bernhard p 6321 DOI: 10.1021/ic900917v

Syntheses and Crystal Structures of Ruthenium and Rhodium Olefin Complexes Containing GaCp* Thomas Cadenbach, Christian Gemel, Timo Bollermann and Roland A. Fischer p 6322 DOI: 10.1021/ic901058y

Issue 14

Intermediates in Reactions of Copper(I) Complexes with N-Oxides: From the Formation of Stable Adducts to Oxo Transfer Sungjun Hong, Aalo K. Gupta and William B. Tolman pp 6323–6325 DOI: 10.1021/ic900435p Supporting Info

From Metalloligand to Interpenetrating Channels: Synthesis, Characterization, and Properties of a 2p−3d−4f Heterometallic Coordination Polymer {[Na5Cu8Sm4(NTA)8(ClO4)8(H2O)22]·ClO4·8H2O}n Jing-xin Ma, Xiao-feng Huang, You Song, Xue-qin Song and Wei-sheng Liu pp 6326–6328 DOI: 10.1021/ic900566v Supporting Info

Chair−Boat Form Transformation of Piperazine-Containing Ligand toward the Preparation of Dirhenium Metallacycles Chung-Chou Lee, Shu-Chun Hsu, Long-Li Lai and Kuang-Lieh Lu pp 6329–6331 DOI: 10.1021/ic900040a Supporting Info

Mono- and Terfluorene Oligomers as Versatile Sensitizers for the Luminescent Eu3+ Cation D. Samuel Oxley, Robert W. Walters, James E. Copenhafer, Tara Y. Meyer, Stphane Petoud and Harry M. Edenborn pp 6332–6334 DOI: 10.1021/ic9002324 Supporting Info

Synthesis of Novel Organic−Inorganic Hybrid Compounds: Lanthanide Phosphites Incorporating a Squarate Ligand Chih-Min Wang and Kwang-Hwa Lii pp 6335–6337 DOI: 10.1021/ic9006394 Supporting Info

Combining Dynamic Heteroleptic Complex Formation with Constitutional Dynamic Synthesis: A Facile Way to M3LL′ Cage Assemblies Jian Fan, Jan W. Bats and Michael Schmittel pp 6338–6340 DOI: 10.1021/ic9008366 Supporting Info

Single-Crystal-to-Single-Crystal Transformation in a One-Dimensional Ag−Eu Helical System Yue-Peng Cai, Xiu-Xia Zhou, Zheng-Yuan Zhou, Shi-Zheng Zhu, Praveen K. Thallapally and Jun Liu pp 6341–6343 DOI: 10.1021/ic9007125 Supporting Info

Stabilization of Imidosamarium(III) Cubane by Amidinates Cheng-Ling Pan, Wan Chen, Shuyan Song, Hongjie Zhang and Xingwei Li pp 6344–6346 DOI: 10.1021/ic900808f Supporting Info

Enhanced Electronic Coupling in a Molecular Pair of Dimolybdenum Units Bridged by a Tetrathioterephthalate Dianion Mei Juan Han, Chun Y. Liu and Peng Fei Tian pp 6347–6349 DOI: 10.1021/ic900956k Supporting Info

Silver−Adenine Metallamacrocyclic Hexamer Jitendra Kumar and Sandeep Verma pp 6350–6352 DOI: 10.1021/ic900811k Supporting Info

Concomitant Formation of N-Heterocyclic Carbene−Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions Jiseul Chun, Il Gu Jung, Hae Jin Kim, Mira Park, Myoung Soo Lah and Seung Uk Son pp 6353–6355 DOI: 10.1021/ic900846s Supporting Info

Spontaneous Resolution of Racemic Camphorates in the Formation of Three-Dimensional Metal−Organic Frameworks Shumei Chen, Jian Zhang and Xianhui Bu pp 6356–6358 DOI: 10.1021/ic900918z Supporting Info

Synthesis and Structure of Analogues for the Ni−Fe Site in Hydrogenase Enzymes Jianfeng Jiang, Myriam Maruani, Jonathan Solaimanzadeh, Wenfeng Lo, Stephen A. Koch and Michelle Millar pp 6359–6361 DOI: 10.1021/ic900929u Supporting Info

Oxygen−Cobalt Chemistry Using a Porphyrinogen Platform Dibyendu Bhattacharya, Suman Maji, Kuntal Pal and Sabyasachi Sarkar pp 6362–6370 DOI: 10.1021/ic802102k Supporting Info

Catalytic Properties of Cobalt(III)−Oxo Cubanes in the TBHP Oxidation of Benzylic Alcohols Rajesh Chakrabarty, Purabi Sarmah, Bapan Saha, Stutee Chakravorty and Birinchi K. Das pp 6371–6379 DOI: 10.1021/ic802115n Supporting Info

To What Extent Does the Zintl−Klemm Formalism Work? The Eu(Zn1−xGex)2 Series Tae-Soo You, Sven Lidin, Olivier Gourdon, Yaqiao Wu and Gordon J. Miller pp 6380–6390 DOI: 10.1021/ic900628k Supporting Info

Theoretical Interpretation of the Structural Variations along the Eu(Zn1−xGex)2 (0 ≤ x ≤ 1) Series Tae-Soo You and Gordon J. Miller pp 6391–6401 DOI: 10.1021/ic900629t Supporting Info

Synthesis and Phase Width of Quaternary Selenides Pb4InxM6−xSe13 (M = Bi, x = 2.1−2.8; Sb, x = 2) Ming-Fang Wang, Wen-Hen Huang and Chi-Shen Lee pp 6402–6408 DOI: 10.1021/ic8023875 Supporting Info

Excited-State Dynamics in a Dyad Comprising Terpyridine-Platinum(II) Ethynylene Linked to Pyrrolidino-[60]Fullerene Barbara Ventura, Andrea Barbieri, Alberto Zanelli, Francesco Barigelletti, Julie Batcha Seneclauze, Stphane Diring and Raymond Ziessel pp 6409–6416 DOI: 10.1021/ic900069r Supporting Info

Solvent-Free Fabrication of Rare LaCO3OH Luminescent Superstructures Vilas G. Pol, P. Thiyagarajan, Jose M. Calderon Moreno and Monica Popa pp 6417–6424 DOI: 10.1021/ic900824n

Emission Enhancement through Dual Donor Sensitization: Modulation of Structural and Spectroscopic Properties in a Series of Europium Tetracyanoplatinates Branson A. Maynard, Philip A. Smith, LeAnn Ladner, Ayesha Jaleel, Nuquie Beedoe, Carlos Crawford, Zerihun Assefa and Richard E. Sykora pp 6425–6435 DOI: 10.1021/ic900149v Supporting Info

High- and Low-Temperature Modifications of Sc3RuC4 and Sc3OsC4—Relativistic Effects, Structure, and Chemical Bonding Christian Vogt, Rolf-Dieter Hoffmann, Ute Ch. Rodewald, Georg Eickerling, Manuel Presnitz, Volker Eyert, Wolfgang Scherer and Rainer Pttgen pp 6436–6451 DOI: 10.1021/ic9002143 Supporting Info

A New Supramolecular Assembly Based on Triple-Dawson-Type Polyoxometalate and 3d-4f Heterometallic Cluster Yun-Wu Li, Yang-Guang Li, Yong-Hui Wang, Xiao-Jia Feng, Ying Lu and En-Bo Wang pp 6452–6458 DOI: 10.1021/ic9001362 Supporting Info

1,5-Naphthyridine As a New Linker for the Construction of Bridging Ligands and Their Corresponding Ru(II) Complexes Ajay N. Singh and Randolph P. Thummel pp 6459–6470 DOI: 10.1021/ic900400t Supporting Info

Biomineralization of Uniform Gallium Oxide Rods with Cellular Compatibility Danhong Yan, Guangfu Yin, Zhongbing Huang, Xiaoming Liao, Yunqing Kang, Yadong Yao, Baoqing Hao, Jianwen Gu and Dong Han pp 6471–6479 DOI: 10.1021/ic900420m

Assembly of Silver(I) Two- and Three-Dimensional Coordination Networks with Complementary Tridentate Heteroaryl Ethynide Ligands Liang Zhao and Thomas C. W. Mak pp 6480–6489 DOI: 10.1021/ic900346p Supporting Info

Synthesis of Ruthenium Carbonyl Complexes with Phosphine or Substituted Cp Ligands, and Their Activity in the Catalytic Deoxygenation of 1,2-Propanediol Prasenjit Ghosh, Paul J. Fagan, William J. Marshall, Elisabeth Hauptman and R. Morris Bullock pp 6490–6500 DOI: 10.1021/ic900413y Supporting Info

Photophysics of Heteroleptic Iridium(III) Complexes Of Current Interest; a Closer Look on Relaxation Dynamics Hsin-Sheng Duan, Pi-Tai Chou, Cheng-Chih Hsu, Jui-Yi Hung and Yun Chi pp 6501–6508 DOI: 10.1021/ic9003164 Supporting Info

Chlorinated Hypoelectronic Dimetallaborane Clusters: Synthesis, Characterization, and Electronic Structures of (η5-C5Me5W)2B5HnClm (n = 7, m = 2 and n = 8, m = 1) Satyanarayan Sahoo, K. Hari Krishna Reddy, Rajendra S. Dhayal, Shaikh M. Mobin, V. Ramkumar, E. D. Jemmis and Sundargopal Ghosh pp 6509–6516 DOI: 10.1021/ic900467d Supporting Info

Synthesis, Structure, and Luminescent Properties of Hybrid Inorganic−Organic Framework Materials Formed by Lead Aromatic Carboxylates: Inorganic Connectivity Variation from 0D to 3D Lei Zhang, Zhao-Ji Li, Qi-Pu Lin, Ye-Yan Qin, Jian Zhang, Pei-Xiu Yin, Jian-Kai Cheng and Yuan-Gen Yao pp 6517–6525 DOI: 10.1021/ic900425r Supporting Info

Synthesis and Characterization of the Ultramarine-Type Analog Na8−x[Si6Al6O24]·(S2,S3,CO3)1−2 Esteban Climent-Pascual, Julio Romero de Paz, Juan Rodrguez-Carvajal, Emmanuelle Suard and Regino Sez-Puche pp 6526–6533 DOI: 10.1021/ic900438c

Organometallic Complexes for Nonlinear Optics. 42. Syntheses, Linear, and Nonlinear Optical Properties of Ligated Metal-Functionalized Oligo(p-phenyleneethynylene)s Gulliver T. Dalton, Marie P. Cifuentes, Laurance A. Watson, Simon Petrie, Robert Stranger, Marek Samoc and Mark G. Humphrey pp 6534–6547 DOI: 10.1021/ic900469y Supporting Info

Redox-Switchable Second-Order Nonlinear Optical Responses of Push−Pull Monotetrathiafulvalene-Metalloporphyrins Chun-Guang Liu, Wei Guan, Ping Song, Li-Kai Yan and Zhong-Min Su pp 6548–6554 DOI: 10.1021/ic9004906

Technetium(IV) Halides Predicted from First-Principles Philippe F. Weck, Eunja Kim, Frdric Poineau, Efrain E. Rodriguez, Alfred P. Sattelberger and Kenneth R. Czerwinski pp 6555–6558 DOI: 10.1021/ic900476m Supporting Info

Highly Porous Metal-Organic Framework Containing a Novel Organosilicon Linker − A Promising Material for Hydrogen Storage Stephanie E. Wenzel, Michael Fischer, Frank Hoffmann and Michael Frba pp 6559–6565 DOI: 10.1021/ic900478z Supporting Info

Structure Determination of La18W10O57 Marie-Hlne Chambrier, Armel Le Bail, Stphanie Kodjikian, Emmanuelle Suard and Franois Goutenoire pp 6566–6572 DOI: 10.1021/ic9005482

Gold Tetrahedra as Building Blocks in K3Au5Tr (Tr = In, Tl) and Rb2Au3Tl and in Other Compounds: A Broad Group of Electron-Poor Intermetallic Phases Bin Li, Sung-Jin Kim, Gordon J. Miller and John D. Corbett pp 6573–6583 DOI: 10.1021/ic9004856 Supporting Info

Cyclopentadienyl/Alkoxo Ligand Exchange in Group 4 Metallocenes: A Convenient Route to Heterometallic Species Piotr Sobota, Anna Drg-Jarzbek, Łukasz John, Jzef Utko, Lucjan B. Jerzykiewicz and Marek Duczmal pp 6584–6593 DOI: 10.1021/ic900498x Supporting Info

As≡UF3 Molecule with a Weak Triple Bond to Uranium Lester Andrews and Xuefeng Wang, Bjrn O. Roos pp 6594–6598 DOI: 10.1021/ic9005696

Separation of the Oxide and Halide Part in the Oxohalide Fe3Te3O10Cl Due to High Lewis Acidity of the Cations Dong Zhang, Mats Johnsson, Helmuth Berger, Reinhard K. Kremer, Dirk Wulferding and Peter Lemmens pp 6599–6603 DOI: 10.1021/ic9005778 Supporting Info

Novel Bispidine Ligands and Their First-Row Transition Metal Complexes: Trigonal Bipyramidal and Trigonal Prismatic Geometries Peter Comba, Christina Haaf and Hubert Wadepohl pp 6604–6614 DOI: 10.1021/ic900571v Supporting Info

High Resolution Crystal Structure of the Methylcobalamin Analogues Ethylcobalamin and Butylcobalamin by X-ray Synchrotron Diffraction Luciana Hannibal, Clyde A. Smith, Jessica A. Smith, Armend Axhemi, Abby Miller, Sihe Wang, Nicola E. Brasch and Donald W. Jacobsen pp 6615–6622 DOI: 10.1021/ic900590p Supporting Info

KMBP2O8 (M = Sr, Ba): A New Kind of Noncentrosymmetry Borophosphate with the Three-Dimensional Diamond-like Framework Dan Zhao, Wen-Dan Cheng, Hao Zhang, Shu-Ping Huang, Zhi Xie, Wei-Long Zhang and Song-Lin Yang pp 6623–6629 DOI: 10.1021/ic900620x Supporting Info

Low-Dimensional Copper(II) Complexes with the Trinucleating Ligand 2,4,6-Tris(di-2-pyridylamine)-1,3,5-triazine: Synthesis, Crystal Structures, and Magnetic Properties† Consuelo Yuste, Laura Caadillas-Delgado, Ana Labrador, Fernando S. Delgado, Catalina Ruiz-Prez, Francesc Lloret and Miguel Julve pp 6630–6640 DOI: 10.1021/ic900599g Supporting Info

Magnesium Substitutions in Rare-Earth Metal Germanides with the Orthorhombic Gd5Si4-type Structure. Synthesis, Crystal Chemistry, and Magnetic Properties of RE5−xMgxGe4 (RE = Gd−Tm, Lu, and Y) Paul H. Tobash and Svilen Bobev , Joe D. Thompson and John L. Sarrao pp 6641–6651 DOI: 10.1021/ic900616c Supporting Info

Porous Manganese(II) 3-(2-Pyridyl)-5-(4-Pyridyl)-1,2,4-Triazolate Frameworks: Rational Self-Assembly, Supramolecular Isomerism, Solid-State Transformation, and Sorption Properties Jian-Bin Lin, Jie-Peng Zhang, Wei-Xiong Zhang, Wei Xue, Dong-Xu Xue and Xiao-Ming Chen pp 6652–6660 DOI: 10.1021/ic900621c Supporting Info

Fundamental Differences of Substrate Hydroxylation by High-Valent Iron(IV)-Oxo Models of Cytochrome P450 Laleh Tahsini, Mojtaba Bagherzadeh, Wonwoo Nam and Sam P. de Visser pp 6661–6669 DOI: 10.1021/ic900593c Supporting Info

Iron(II) Tris-[N4-substituted-3,5-di(2-pyridyl)-1,2,4-triazole] Complexes: Structural, Magnetic, NMR, and Density Functional Theory Studies Jonathan A. Kitchen, Nicholas G. White, Maruta Boyd, Boujemaa Moubaraki, Keith S. Murray, Peter D. W. Boyd and Sally Brooker pp 6670–6679 DOI: 10.1021/ic900634t Supporting Info

Syntheses, Structures and Solid-State Properties of MMX Mixed-Valence Chains, [NiII/III2(RCS2)4I]∞ (R = Et, n-Pr and n-Bu): Evidence of a Spin-Peierls Transition Minoru Mitsumi, Yuji Yoshida, Akihisa Kohyama, Yasutaka Kitagawa, Yoshiki Ozawa, Mototada Kobayashi, Koshiro Toriumi, Makoto Tadokoro, Naoshi Ikeda, Mitsutaka Okumura and Mohamedally Kurmoo pp 6680–6691 DOI: 10.1021/ic900630a Supporting Info

Lanthanide Complexes of Triethylenetetramine Tetra-, Penta-, and Hexaacetamide Ligands as Paramagnetic Chemical Exchange-Dependent Saturation Transfer Contrast Agents for Magnetic Resonance Imaging: Nona- versus Decadentate Coordination Dirk Burdinski, Jeroen A. Pikkemaat, Johan Lub, Peter de Peinder, Lidia Nieto Garrido and Thomas Weyhermller pp 6692–6712 DOI: 10.1021/ic900652y Supporting Info

Tridecanuclear [MnIII5LnIII8] Complexes Derived from N-tButyl-diethanolamine: Synthesis, Structures, and Magnetic Properties Ayuk M. Ako, Valeriu Mereacre, Rodolphe Clrac, Ian J. Hewitt, Yanhua Lan, Gernot Buth, Christopher E. Anson and Annie K. Powell pp 6713–6723 DOI: 10.1021/ic900645d

Synthesis and Properties of Well-Crystallized Layered Rare-Earth Hydroxide Nitrates from Homogeneous Precipitation Fengxia Geng, Yoshitaka Matsushita, Renzhi Ma, Hao Xin, Masahiko Tanaka, Nobuo Iyi and Takayoshi Sasaki pp 6724–6730 DOI: 10.1021/ic900669p Supporting Info

One-Dimensional Ce3+- and/or Tb3+-Doped X1-Y2SiO5 Nanofibers and Microbelts: Electrospinning Preparation and Luminescent Properties Lili Wang, Zhiyao Hou, Zewei Quan, Chunxia Li, Jun Yang, Hongzhou Lian, Piaoping Yang and Jun Lin pp 6731–6739 DOI: 10.1021/ic9006789

Weak Interactions between Trivalent Pnictogen Centers: Computational Analysis of Bonding in Dimers X3E···EX3 (E = Pnictogen, X = Halogen) Jani Moilanen, Chelladurai Ganesamoorthy, Maravanji S. Balakrishna and Heikki M. Tuononen pp 6740–6747 DOI: 10.1021/ic900635f Supporting Info

Effect of Temperature on the Complexation of Uranium(VI) with Fluoride in Aqueous Solutions Guoxin Tian and Linfeng Rao pp 6748–6754 DOI: 10.1021/ic900681x

Experimental and Theoretical Investigations of the Contact Ion Pairs Formed by Reactions of the Anions [(EPR2)2N]− (R = iPr, tBu; E = S, Se) with the Cations [(TePR2)2N]+ (R = iPr, tBu) Stuart D. Robertson, Tristram Chivers and Heikki M. Tuononen pp 6755–6762 DOI: 10.1021/ic900703e Supporting Info

Synthesis, Structure, and Reactivity of Two-Coordinate Mercury Alkyl Compounds with Sulfur Ligands: Relevance to Mercury Detoxification Jonathan G. Melnick, Kevin Yurkerwich and Gerard Parkin pp 6763–6772 DOI: 10.1021/ic900721g Supporting Info

Ab Initio Study of the Geometry, Stability, and Aromaticity of the Cyclic S2N3+ Cation Isomers and Their Isoelectronic Analogues Guo-Hua Zhang, Yong-Fang Zhao, Judy I. Wu and Paul v. R. Schleyer pp 6773–6780 DOI: 10.1021/ic900718t

Polynuclear Nickel(II) Complexes: A Magnetostructural Study of NiII4, NiII6, and NiII9 Species with Oxime Ligands Biplab Biswas, Ulrich Pieper, Thomas Weyhermller and Phalguni Chaudhuri pp 6781–6793 DOI: 10.1021/ic9007608 Supporting Info

Explorations of New Phases in the GaIII/InIII-CuII-SeIV-O System Fang Kong, Qi-Pu Lin, Fei-Yan Yi and Jiang-Gao Mao pp 6794–6803 DOI: 10.1021/ic900756u Supporting Info

Revisiting Tungsten Trioxide Hydrates (TTHs) Synthesis - Is There Anything New? Lisa M. Kuti, Surinderjit Singh Bhella and Venkataraman Thangadurai pp 6804–6811 DOI: 10.1021/ic900738m Supporting Info

Mono- and Bis- Methyltrioxorhenium(VII) Complexes with Salen Ligands: Synthesis, Properties, Applications Zhaoqing Xu, Ming-Dong Zhou, Markus Drees, Hugh Chaffey-Millar, Eberhardt Herdtweck, Wolfgang A. Herrmann and Fritz E. Khn pp 6812–6822 DOI: 10.1021/ic900761u Supporting Info

Experimental and Computational Study of the Bonding Properties of Mixed Bis−Ylides of Phosphorus and Sulfur Elena Serrano, Rafael Navarro, Tatiana Soler, Jorge J. Carb, Agust Lleds and Esteban P. Urriolabeitia pp 6823–6834 DOI: 10.1021/ic900765x Supporting Info

Structure and Physical Properties of New Iron Hydrogenophosphates: K2Fe(HP2O7)(H2PO4)2, LiH3Fe2(P2O7)2, and FeH2P2O7 V. Pralong, R. Baies, V. Caignaert and B. Raveau pp 6835–6844 DOI: 10.1021/ic900771c

Homometallic Uranium(VI) Phosphonoacetates Containing Interlayer Dipyridines Karah E. Knope and Christopher L. Cahill pp 6845–6851 DOI: 10.1021/ic9007735 Supporting Info

Dynamic Properties of a Hexadecamolybdenum Wheel: Studies in Solution and Density Functional Theory Calculations Ali Kachmar, Sbastien Floquet, Jean-Franois Lemonnier, Emmanuel Cadot, Marie-Madeleine Rohmer and Marc Bnard pp 6852–6859 DOI: 10.1021/ic900783k Supporting Info

Polymorphism and Inclusion Properties of Three-Dimensional Metal-Organometallic Frameworks Derived from a Terephthalate Sandwich Compound Sayon A. Kumalah and K. Travis Holman pp 6860–6872 DOI: 10.1021/ic900816h Supporting Info

Metal-Organic Frameworks with Direct Transition Metal-Sulfonate Interactions and Charge-Assisted Hydrogen Bonds Tori Z. Forbes and Slavi C. Sevov pp 6873–6878 DOI: 10.1021/ic9007922 Supporting Info

Demetalation of Silver(III) Corrolates Manuela Stefanelli, Jing Shen, Weihua Zhu, Marco Mastroianni, Federica Mandoj, Sara Nardis, Zhongping Ou, Karl M. Kadish, Frank R. Fronczek, Kevin M. Smith and Roberto Paolesse pp 6879–6887 DOI: 10.1021/ic900859a Supporting Info

Infrared Spectra and Density Functional Calculations of the SUO2 Molecule Xuefeng Wang and Lester Andrews, Colin J. Marsden pp 6888–6895 DOI: 10.1021/ic900869f

Thermal Decomposition Reactions as Tool for the Synthesis of New Metal Thiocyanate Diazine Coordination Polymers with Cooperative Magnetic Phenomena Mario Wriedt, Sina Sellmer and Christian Nther pp 6896–6903 DOI: 10.1021/ic9002498 Supporting Info

Photosensitization of Ruthenium Nitrosyls to Red Light with an Isoelectronic Series of Heavy-Atom Chromophores: Experimental and Density Functional Theory Studies on the Effects of O-, S- and Se-Substituted Coordinated Dyes Michael J. Rose and Pradip K. Mascharak pp 6904–6917 DOI: 10.1021/ic900899j Supporting Info

Poly[perfluorotitanate(IV)] Salts of [H3O]+, Cs+, [Me4N]+, and [Ph4P]+ and about the Existence of an Isolated [Ti2F9]− Anion in the Solid State Zoran Mazej and Evgeny Goreshnik pp 6918–6923 DOI: 10.1021/ic9009338

Bimetallic N-Heterocyclic Carbene−Iridium Complexes: Investigating Metal−Metal and Metal−Ligand Communication via Electrochemistry and Phosphorescence Spectroscopy Andrew G. Tennyson, Evelyn L. Rosen, Mary S. Collins, Vincent M. Lynch and Christopher W. Bielawski pp 6924–6933 DOI: 10.1021/ic900391q Supporting Info

Structural Variations within Group 1 (Li−Cs)+(2,2,6,6-Tetramethyl-1-piperidinyloxy)− Complexes Made via Metallic Reduction of the Nitroxyl Radical Liam Balloch, Allison M. Drummond, Pablo Garca-lvarez, David V. Graham, Alan R. Kennedy, Jan Klett, Robert E. Mulvey, Charles T. O’Hara, Philip J. A. Rodger and Iain D. Rushworth pp 6934–6944 DOI: 10.1021/ic900609e Supporting Info

Selective Arylation Reactions of Bismuth−Transition Metal Salicylate Complexes Vitalie Stavila, John H. Thurston and Kenton H. Whitmire pp 6945–6951 DOI: 10.1021/ic9010357 Supporting Info

Preparation of Nb-Substituted Titanates by a Novel Sol−Gel Assisted Solid State Reaction Haiyan Song, Anja O. Sjstad, Ørnulv B. Vistad, Tao Gao and Poul Norby pp 6952–6959 DOI: 10.1021/ic900181c Supporting Info

Efficient Catalytic Phosphate Ester Cleavage by Binuclear Zinc(II) Pyrazolate Complexes as Functional Models of Metallophosphatases Larysa V. Penkova, Anna Macig, Elena V. Rybak-Akimova, Matti Haukka, Vadim A. Pavlenko, Turganbay S. Iskenderov, Henryk Kozłowski, Franc Meyer and Igor O. Fritsky pp 6960–6971 DOI: 10.1021/ic900520j Supporting Info

Mononuclear Platinum(II) Complexes Incorporating κ2-Carboxylate Ligands: Synthesis, Structure, and Reactivity Marc-Etienne Moret, Sebastian F. Keller, J. Chris Slootweg and Peter Chen pp 6972–6978 DOI: 10.1021/ic900677c Supporting Info

Oxidation of a Water-Soluble Phosphine and Some Spectroscopic Probes with Nitric Oxide and Nitrous Acid in Aqueous Solutions Andreja Bakac, Margaret Schouten, Alicia Johnson, Wenjing Song, Oleg Pestovsky and Ewa Szajna-Fuller pp 6979–6985 DOI: 10.1021/ic900688g

Theoretical Study of Structure, Bonding, and Electronic Behavior of Low-Valent Bismuth Cyclopentadienyl and Pentamethylcyclopentadienyl Half-Sandwich Compounds Kirill Yu. Monakhov and Gerald Linti pp 6986–6996 DOI: 10.1021/ic9006229 Supporting Info

Issue 15

Three-Dimensional Lanthanide Anionic Metal−Organic Frameworks with Tunable Luminescent Properties Induced by Cation Exchange Wen-Guan Lu, Long Jiang, Xiao-Long Feng and Tong-Bu Lu pp 6997–6999 DOI: 10.1021/ic900506z Supporting Info

Solution Structure of Physiological Cu(His)2: Novel Considerations into Imidazole Coordination Yamini P. Ginotra and Prasad P. Kulkarni pp 7000–7002 DOI: 10.1021/ic9010983

Dioxygen Activation by Mononuclear Copper Enzymes: Insights from a Tripodal Ligand Mimicking Their CuM Coordination Sphere Aurlien de la Lande, Dennis Salahub, Vicent Moliner, Hlne Grard, Jean-Philip Piquemal and Olivier Parisel pp 7003–7005 DOI: 10.1021/ic900567z Supporting Info

Alkylaluminum Derivatives of Diphenic Acid: Novel Aluminum Carboxylates Wanda Ziemkowska, Micha Cyraski and Antoni Kunicki pp 7006–7008 DOI: 10.1021/ic900799m Supporting Info

Subtle Modification of 2,2-Dipicolylamine Lowers the Affinity and Improves the Turn-On of Zn(II)-Selective Fluorescent Sensors Brian A. Wong, Simone Friedle and Stephen J. Lippard pp 7009–7011 DOI: 10.1021/ic900990w Supporting Info

Long-Range Order in the One-Dimensional Cobalt(II)−Radical Coordination Polymer Magnet Probed by Muon-Spin Rotation and Relaxation Takayuki Ishida, Yoshitomo Okamura and Isao Watanabe pp 7012–7014 DOI: 10.1021/ic9009948

Octanuclear Aluminum(III) and Iron(III) Phosphonate Cages Encapsulating Two NaI Ions Zi-Yi Du, Yu-Hui Sun, Qing-Yan Liu, Yong-Rong Xie and He-Rui Wen pp 7015–7017 DOI: 10.1021/ic901130a Supporting Info

Sodium Ion Mobility in NaxCoO2 (0.6 < x < 0.75) Cobaltites Studied by 23Na MAS NMR Dany Carlier, Maxime Blangero, Michel Mntrier, Michal Pollet, Jean-Pierre Doumerc and Claude Delmas pp 7018–7025 DOI: 10.1021/ic900026c

Multifrequency EPR Studies of [Cu1.5Cu1.5]+ for Cu2(μ-NR2)2 and Cu2(μ-PR2)2 Diamond Cores Neal P. Mankad, Seth B. Harkins, William. E. Antholine and Jonas C. Peters pp 7026–7032 DOI: 10.1021/ic801864z Supporting Info

Systematic Study of Spin Crossover and Structure in [Co(terpyRX)2](Y)2 Systems (terpyRX = 4′-alkoxy-2,2′:6′,2′′-terpyridine, X = 4, 8, 12, Y = BF4−, ClO4−, PF6−, BPh4−) Pia Nielsen, Hans Toftlund, Andrew D. Bond, John F. Boas, John R. Pilbrow, Graeme R. Hanson, Christopher Noble, Mark J. Riley, Suzanne M. Neville, Boujemaa Moubaraki and Keith S. Murray pp 7033–7047 DOI: 10.1021/ic802252k Supporting Info

In Situ Phase Separation Following Dehydration in Bimetallic Sulfates: A Variable-Temperature X-Ray Diffraction Study Diptikanta Swain and Tayur N Guru Row pp 7048–7058 DOI: 10.1021/ic801308u Supporting Info

A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7 Sheng-Ping Guo, Guo-Cong Guo, Ming-Sheng Wang, Jian-Ping Zou, Gang Xu, Guo-Jian Wang, Xi-Fa Long and Jin-Shun Huang pp 7059–7065 DOI: 10.1021/ic802443n Supporting Info

Reduction of Titanium Dioxide to Metallic Titanium Conducted under the Autogenic Pressure of the Reactants Michal Eshed, Alexander Irzh and Aharon Gedanken pp 7066–7069 DOI: 10.1021/ic900087c

Apical Ligand Substitution, Shape Recognition, Vapor-Adsorption Phenomenon, and Microcalorimetry for a Pillared Bilayer Porous Framework That Shrinks or Expands in Crystal-to-Crystal Manners upon Change in the Cobalt(II) Coordination Environment Ming-Hua Zeng, Sheng Hu, Qing Chen, Gang Xie, Qi Shuai, Sheng-Li Gao and Li-Yuan Tang pp 7070–7079 DOI: 10.1021/ic801794e Supporting Info

Transition-Metal Tris-Bipyridines Containing Three Dithienylcyclopentenes: Synthesis, Photochromic, and Electrochromic Properties Yu-Wu Zhong, Neus Vil, Jay C. Henderson and Hctor D. Abrua pp 7080–7085 DOI: 10.1021/ic802272q Supporting Info

Structural, UV−Visible, and Electrochemical Studies on 2,3-Dicyano-5,6-di-2-pyridylpyrazine, [(CN)2Py2Pyz], Related Species and Its Complexes [(CN)2Py2PyzMCl2] (M = PtII, PdII) Xiaohui Cai, Maria Pia Donzello, Elisa Viola, Corrado Rizzoli, Claudio Ercolani and Karl M. Kadish pp 7086–7098 DOI: 10.1021/ic8023277 Supporting Info

Fast Synthesis, Formation Mechanism, and Control of Shell Thickness of CuS Hollow Spheres Haitao Zhu, Jixin Wang and Daxiong Wu pp 7099–7104 DOI: 10.1021/ic900201p Supporting Info

Catching CO2 in a Bowl J. A. Tossell pp 7105–7110 DOI: 10.1021/ic802454w

Single-Crystal-to-Single-Crystal Transformation in Unusual Three-Dimensional Manganese(II) Frameworks Exhibiting Unprecedented Topology and Homospin Ferrimagnet Jiong-Peng Zhao, Bo-Wen Hu, Qian Yang, Tong-Liang Hu and Xian-He Bu pp 7111–7116 DOI: 10.1021/ic900893m Supporting Info

Macrocyclic Diamide Ligand Systems: Potential Chelators for 64Cu- and 68Ga-Based Positron Emission Tomography Imaging Agents Peter J. Barnard, Jason P. Holland, Simon R. Bayly, Thaddeus J. Wadas, Carolyn J. Anderson and Jonathan R. Dilworth pp 7117–7126 DOI: 10.1021/ic900307f Supporting Info

Theoretical Study of Dioxygen Induced Inhibition of [FeFe]-Hydrogenase Martin T. Stiebritz and Markus Reiher pp 7127–7140 DOI: 10.1021/ic9002127

Reactivity of NH4H2PO4 toward LaCl3 in LiCl-KCl Melt Flux. Step by Step Formation of Monazite-Like LaPO4. Damien Hudry, Aydar Rakhmatullin, Catherine Bessada, Isabelle Bardez, Florence Bart, Stphane Jobic and Philippe Deniard pp 7141–7150 DOI: 10.1021/ic9003142

Hard and Soft Acids and Bases: Small Molecules James L. Reed pp 7151–7158 DOI: 10.1021/ic900368f

Making a Robust Carbon−Cobalt(III) Bond Erik Larsen, Anders Østergaard Madsen, Pauli Kofod and Yong Sheng Song pp 7159–7164 DOI: 10.1021/ic900397r Supporting Info

PM3: A Multifunctional Microporous MOF with Recyclable Framework and High H2 Binding Energy Anjian Lan, Kunhao Li, Haohan Wu, Lingzhu Kong, Nour Nijem, David H. Olson, Thomas J. Emge, Yves J. Chabal, David C. Langreth, Maochun Hong and Jing Li pp 7165–7173 DOI: 10.1021/ic9002115 Supporting Info

Two EE-Azido-Bridged Nickel(II) Layered Compounds: Vigorous Twisted Torsion Angle Ni−N3−Ni Results in Ferromagnetic Behavior Ru-Yin Li, Bing-Wu Wang, Xin-Yi Wang, Xiu-Teng Wang, Zhe-Ming Wang and Song Gao pp 7174–7180 DOI: 10.1021/ic9003092 Supporting Info

Synthesis and Reversible Reductive Coupling of Cationic, Dinitrogen-Derived Diazoalkane Complexes John J. Curley, Tetsuro Murahashi and Christopher C. Cummins pp 7181–7193 DOI: 10.1021/ic900495s Supporting Info

Conformation Preference of a Flexible Cyclohexanetetracarboxylate Ligand in Three New Metal-Organic Frameworks: Structures, Magnetic and Luminescent Properties Rongming Wang, Jian Zhang and Lijuan Li pp 7194–7200 DOI: 10.1021/ic900390y Supporting Info

Speciation and Structural Study of U(IV) and -(VI) in Perchloric and Nitric Acid Solutions Atsushi Ikeda-Ohno, Christoph Hennig, Satoru Tsushima, Andreas C. Scheinost, Gert Bernhard and Tsuyoshi Yaita pp 7201–7210 DOI: 10.1021/ic9004467 Supporting Info

One-Step and Two-Step Spin-Crossover Iron(II) Complexes of ((2-Methylimidazol-4-yl)methylidene)histamine Tetsuya Sato, Koshiro Nishi, Seiichiro Iijima, Masaaki Kojima and Naohide Matsumoto pp 7211–7229 DOI: 10.1021/ic9006197 Supporting Info

Luminescent Boron-Contained Ladder-Type π-Conjugated Compounds Zuolun Zhang, Hai Bi, Yu Zhang, Dandan Yao, Hongze Gao, Yan Fan, Hongyu Zhang, Yue Wang, Yanping Wang, Zhenyu Chen and Dongge Ma pp 7230–7236 DOI: 10.1021/ic900673s Supporting Info

Cerium(III), Europium(III), and Ytterbium(III) Complexes with Alcohol Donor Groups as Chemical Exchange Saturation Transfer Agents for MRI Ching-Hui Huang and Janet R. Morrow pp 7237–7243 DOI: 10.1021/ic900696f Supporting Info

Long-Distance Magnetic Interaction of Exchange-Coupled Copper Dimers with Nitronyl Nitroxide and tert-Butyl Nitroxide Radicals Martin Jung, Ajay Sharma, Dariush Hinderberger, Sebastian Braun, Ulrich Schatzschneider and Eva Rentschler pp 7244–7250 DOI: 10.1021/ic9006857

Magnetic and Spectroscopic Properties of Mixed Valence Manganese(III,IV) Dimers: A Systematic Study Using Broken Symmetry Density Functional Theory Maylis Orio, Dimitrios A. Pantazis, Taras Petrenko and Frank Neese pp 7251–7260 DOI: 10.1021/ic9005899 Supporting Info

SnO2 Nanostructures-TiO2 Nanofibers Heterostructures: Controlled Fabrication and High Photocatalytic Properties Changhua Wang, Changlu Shao, Xintong Zhang and Yichun Liu pp 7261–7268 DOI: 10.1021/ic9005983

Sustained Water Oxidation by [Mn4O4]7+ Core Complexes Inspired by Oxygenic Photosynthesis Robin Brimblecombe, Derrick R. J. Kolling, Alan M. Bond, G. Charles Dismukes, Gerhard F. Swiegers and Leone Spiccia pp 7269–7279 DOI: 10.1021/ic9006982 Supporting Info

Imidazole-Containing (N3S)-NiII Complexes Relating to Nickel Containing Biomolecules Roxanne M. Jenkins, Michael L. Singleton, Elky Almaraz, Joseph H. Reibenspies and Marcetta Y. Darensbourg pp 7280–7293 DOI: 10.1021/ic900778k Supporting Info

Electrochemical and Electronic Structure Investigations of the [S3N3]• Radical and Kinetic Modeling of the [S4N4]n/[S3N3]n (n = 0, −1) Interconversion Ren T. Boer, Tristram Chivers, Tracey L. Roemmele and Heikki M. Tuononen pp 7294–7306 DOI: 10.1021/ic900742q Supporting Info

Photon-Initiated Homolysis of Peroxynitrous Acid Manuel Sturzbecher-Hhne, Thomas Nauser, Reinhard Kissner and Willem H. Koppenol pp 7307–7312 DOI: 10.1021/ic900614e

Synthesis and Reactivity of [closo-1-CB9H9-1-N2]: Functional Group Interconversion at the Carbon Vertex of the {closo-1-CB9} Cluster Bryan Ringstrand, Piotr Kaszynski and Andreas Franken pp 7313–7329 DOI: 10.1021/ic9007476 Supporting Info

Heteronuclear and Homonuclear Cu2+ and Zn2+ Complexes with Multihistidine Peptides Based on Zebrafish Prion-like Protein Daniela Valensin, Łukasz Szyrwiel, Francesca Camponeschi, Magdalena Rowiska-yrek, Elena Molteni, Elzbieta Jankowska, Aneta Szymanska, Elena Gaggelli, Gianni Valensin and Henryk Kozłowski pp 7330–7340 DOI: 10.1021/ic9008202 Supporting Info

Postsynthetic Modification: A Versatile Approach Toward Multifunctional Metal-Organic Frameworks Sergio J. Garibay, Zhenqiang Wang, Kristine K. Tanabe and Seth M. Cohen pp 7341–7349 DOI: 10.1021/ic900796n Supporting Info

A New Series of Ionic Liquids Based on the Difluorophosphate Anion Kazuhiko Matsumoto and Rika Hagiwara pp 7350–7358 DOI: 10.1021/ic9008009 Supporting Info

Cyclic Arsenic−Nitrogen Cations Axel Schulz and Alexander Villinger pp 7359–7367 DOI: 10.1021/ic900821h Supporting Info

New Variant of Highly Symmetric Layered Perovskite with Coordinated NO3− Ligand: Hydrothermal Synthesis, Structure, and Characterization of Cs2PbCl2(NO3)2 Min Kyung Kim, Vinna Jo and Kang Min Ok pp 7368–7372 DOI: 10.1021/ic900845u Supporting Info

Facile Access to the Hydrazone Functionalized PdGeS Cluster [{RNGe(μ-S)3}4Pd6] from the Thiogermanate Anion [{RNGe}2(μ-S)2S2]2− Mohammad Reza Halvagar, Zohreh Hassanzadeh Fard, Lin Xiong and Stefanie Dehnen pp 7373–7377 DOI: 10.1021/ic900853e Supporting Info

Synthesis, Structure, and Olefin Polymerization Activity of Titanium Complexes Bearing Asymmetric Tetradentate [OSNO]-Type Bis(phenolato) Ligands Geert-Jan M. Meppelder, Hong-Tao Fan, Thomas P. Spaniol and Jun Okuda pp 7378–7388 DOI: 10.1021/ic900903b Supporting Info

Synthesis of Longtime Water/Air-Stable Ni Nanoparticles and Their High Catalytic Activity for Hydrolysis of Ammonia−Borane for Hydrogen Generation Jun-Min Yan, Xin-Bo Zhang, Song Han, Hiroshi Shioyama and Qiang Xu pp 7389–7393 DOI: 10.1021/ic900921m Supporting Info

Transformations of N-Confused Porphyrin Triggered by Insertion of Silicon(IV) Janusz Skonieczny, Lechosław Latos-Grazyski and Ludmiła Szterenberg pp 7394–7407 DOI: 10.1021/ic900914y Supporting Info

Single-Ion Entropies, Sion°, of Solids—A Route to Standard Entropy Estimation Leslie Glasser, H. Donald Brooke Jenkins pp 7408–7412 DOI: 10.1021/ic9009543 Supporting Info

Tetranuclear Coordination Assemblies Based on Half-Sandwich Ruthenium(II) Complexes: Noncovalent Binding to DNA and Cytotoxicity Ftima Linares, Miguel A. Galindo, Simona Galli, M. Angustias Romero, Jorge A. R. Navarro and Elisa Barea pp 7413–7420 DOI: 10.1021/ic900980y Supporting Info

4-(2-Tetrathiafulvalenyl-ethenyl)pyridine (TTF−CH═CH−Py) Radical Cation Salts Containing Poly(β-diketonate) Rare Earth Complexes: Synthesis, Crystal Structure, Photoluminescent and Magnetic Properties Fabrice Pointillart, Olivier Maury, Yann Le Gal, Stphane Golhen, Olivier Cador and Lahcne Ouahab pp 7421–7429 DOI: 10.1021/ic901052b Supporting Info

Octahedral Monodithiolene Complexes of Iron: Characterization of S,S′-Coordinated Dithiolate(1−) π Radical Monoanions: A Spectroscopic and Density Functional Theoretical Investigation Carsten Milsmann, Goutam Kumar Patra, Eckhard Bill, Thomas Weyhermller, Serena DeBeer George and Karl Wieghardt pp 7430–7445 DOI: 10.1021/ic900936p Supporting Info

Effect of an In-Plane Ligand on the Electronic Structures of Bromo-Bridged Nano-Wire Ni−Pd Mixed-Metal Complexes, [Ni1−xPdx(bn)2Br]Br2 (bn = 2S,3S-Diaminobutane) Mari Sasaki, Hashen Wu, Daisuke Kawakami, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Brian K. Breedlove, Masahiro Yamashita, Hideo Kishida, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka and Shinichi Kuroda pp 7446–7451 DOI: 10.1021/ic901067z Supporting Info

Heterobimetallic Bismuth(III)/Molybdenum(VI) and Antimony(III)/Molybdenum(VI) Calix[5]arene Complexes. Progress toward Modeling the SOHIO Catalyst Daniel Mendoza-Espinosa and Tracy A. Hanna pp 7452–7456 DOI: 10.1021/ic901103r Supporting Info

Dissolution/Reorganization toward the Destruction/Construction of Porous Cobalt(II)− and Nickel(II)−Carboxylate Coordination Polymers Miao-Tzu Ding, Jing-Yun Wu, Yen-Hsiang Liu and Kuang-Lieh Lu pp 7457–7465 DOI: 10.1021/ic900037g Supporting Info

Thermodynamic and Kinetic Studies on Reactions of FeIII(meso-[tetra(3-sulfonatomesityl)porphin]) with NO in an Ionic Liquid. Trace Impurities Can Change the Mechanism! Matthias Schmeisser and Rudi van Eldik pp 7466–7475 DOI: 10.1021/ic9006247 Supporting Info

Stereodirective Effects in Mixed Substituent Vinyloxycyclotriphosphazenes Kenneth R. Carter, Michael Calichman and Christopher W. Allen pp 7476–7481 DOI: 10.1021/ic9006923

Asymmetric Synthesis of Bis(tertiary arsines): Highly Stereoselective Alkylations of Diastereomers of a Chiral Phosphine-Stabilized Bis(arsenium triflate) Michelle L. Weir, Ian A. Cade, Nathan L. Kilah, Xiangting Zhou and S. Bruce Wild pp 7482–7490 DOI: 10.1021/ic900797y Supporting Info

Ligand Modifications for Tailoring the Binuclear Microenvironments in Schiff-Base Calixpyrrole Pacman Complexes Elham Askarizadeh, Aline M. J. Devoille, Davar M. Boghaei, Alexandra M. Z. Slawin and Jason. B. Love pp 7491–7500 DOI: 10.1021/ic900871g

Issue 16

Two-Photon Plasma Membrane Imaging in Live Cells by an Amphiphilic, Water-Soluble Cyctometalated Platinum(II) Complex Chi-Kin Koo, Ka-Leung Wong, Cornelia Wing-Yin Man, Hoi-Lam Tam, Sai-Wah Tsao, Kok-Wai Cheah and Michael Hon-Wah Lam pp 7501–7503 DOI: 10.1021/ic9007679 Supporting Info

Heteropoly-13-Palladates(II) [PdII13(AsVPh)8O32]6− and [PdII13SeIV8O32]6− Natalya V. Izarova, Michael H. Dickman, Rosa Ngo Biboum, Bineta Keita, Louis Nadjo, Vasanth Ramachandran, Naresh S. Dalal and Ulrich Kortz pp 7504–7506 DOI: 10.1021/ic900953a Supporting Info

Hydrogen Activation by Biomimetic Diiron Dithiolates Matthew T. Olsen, Bryan E. Barton and Thomas B. Rauchfuss pp 7507–7509 DOI: 10.1021/ic900850u Supporting Info

Formation and Structures of Germanium(II) Aryloxo/Oxo Clusters Rebecca A. Green, Curtis Moore, Arnold L. Rheingold and Charles S. Weinert pp 7510–7512 DOI: 10.1021/ic900915q Supporting Info

CuI Complexes with a Noninnocent PNP Ligand: Selective Dearomatization and Electrophilic Addition Reactivity Jarl Ivar van der Vlugt, Evgeny A. Pidko, Dieter Vogt, Martin Lutz and Anthony L. Spek pp 7513–7515 DOI: 10.1021/ic901032c Supporting Info

Second-Harmonic Generation and Crystal Structure of the Diamond-like Semiconductors Li2CdGeS4 and Li2CdSnS4 Jonathan W. Lekse, Meghann A. Moreau, Katie L. McNerny, Jeongho Yeon, P. Shiv Halasyamani and Jennifer A. Aitken pp 7516–7518 DOI: 10.1021/ic9010339 Supporting Info

A Large-Surface-Area Boracite-Network-Topology Porous MOF Constructed from a Conjugated Ligand Exhibiting a High Hydrogen Uptake Capacity Xi-Sen Wang, Shengqian Ma, Daqiang Yuan, Ji Woong Yoon, Young Kyu Hwang, Jong-San Chang, Xiaoping Wang, Mads Ry Jørgensen, Yu-Sheng Chen and Hong-Cai Zhou pp 7519–7521 DOI: 10.1021/ic901073w Supporting Info

Side-on Coordination of a P−P Bond in Heterobinuclear Tetraphosphorus Complexes with a [Si(μ,η2:2-P4)Ni] Core and Nickel(I) Centers Yun Xiong, Shenglai Yao, Eckhard Bill and Matthias Driess pp 7522–7524 DOI: 10.1021/ic901088c Supporting Info

Heteroligand Molecular “Stirrups” Using Conformationally Flexible Ditopic Pyridyl−Pyrazolyl Ligands Jinzhen Lu, David R. Turner, Lindsay P. Harding and Stuart R. Batten pp 7525–7527 DOI: 10.1021/ic9010967 Supporting Info

A Remarkable Member of the Polyoxometalates: The Eight-Nickel-Capped α-Keggin Polyoxoazonickelate Lanjun Dong, Rudan Huang, Yongge Wei and Wei Chu pp 7528–7530 DOI: 10.1021/ic9012872 Supporting Info

An Unusual Binary Phosphorus−Tellurium Anion and Its Seleno- and Thio- Analogues: P4Ch22− (Ch = S, Se, Te) Christiane Rotter, Michael Schuster and Konstantin Karaghiosoff pp 7531–7533 DOI: 10.1021/ic901149m Supporting Info

Synthesis of Binuclear Complexes Bound in an Enlarged Tetraphosphamacrocycle: Two Diphosphine Metal Units Linked in Front-to-Front Style Tsutomu Mizuta, Yuta Inami, Kazuyuki Kubo and Katsuhiko Miyoshi pp 7534–7536 DOI: 10.1021/ic9013224 Supporting Info

High-Pressure Phase Transition to the Gd2S3 Structure in Sc2O3: A New Trend in Dense Structures in Sesquioxides Hitoshi Yusa, Taku Tsuchiya, Nagayoshi Sata and Yasuo Ohishi pp 7537–7543 DOI: 10.1021/ic9001253

Syntheses, X-ray Structures, and Physicochemical Properties of Phenoxo-Bridged Dinuclear Nickel(II) Complexes: Kinetics of Transesterification of 2-Hydroxypropyl-p-nitrophenylphosphate Sukanta Mandal, V. Balamurugan, Francesc Lloret and Rabindranath Mukherjee pp 7544–7556 DOI: 10.1021/ic8018937 Supporting Info

Elucidation of the Magnetism of [Co2PdCl2(dpa)4]: Origin of a Large Temperature Domain of TIP Behavior W. Van den Heuvel and L. F. Chibotaru pp 7557–7563 DOI: 10.1021/ic900014j

Mechanistic Study of LiNH2BH3 Formation from (LiH)4 + NH3BH3 and Subsequent Dehydrogenation Tae Bum Lee and Michael L. McKee pp 7564–7575 DOI: 10.1021/ic9001835 Supporting Info

Surfactant-Assisted Hydrothermal Synthesis of Eu3+-Doped White Light Hydroxyl Sodium Yttrium Tungstate Microspheres and Their Conversion to NaY(WO4)2 Fang Lei, Bing Yan, Hao Hong Chen and Jing Tai Zhao pp 7576–7584 DOI: 10.1021/ic900699h

Neutron Diffraction Study of the in Situ Oxidation of UO2 Lionel Desgranges, Gianguido Baldinozzi, Gurvan Rousseau, Jean-Claude Nipce and Gilbert Calvarin pp 7585–7592 DOI: 10.1021/ic9000889 Supporting Info

Heteroleptic Arene Ruthenium Complexes Based on meso-Substituted Dipyrrins: Synthesis, Structure, Reactivity, and Electrochemical Studies Mahendra Yadav, Ashish Kumar Singh, Biswajit Maiti and Daya Shankar Pandey pp 7593–7603 DOI: 10.1021/ic9000957 Supporting Info

Biomimetic Model Featuring the NH Proton and Bridging Hydride Related to a Proposed Intermediate in Enzymatic H2 Production by Fe-Only Hydrogenase Ming-Hsi Chiang, Yu-Chiao Liu, Shu-Ting Yang and Gene-Hsiang Lee pp 7604–7612 DOI: 10.1021/ic900564q Supporting Info

Energy Transfers in Monomers, Dimers, and Trimers of Zinc(II) and Palladium(II) Porphyrins Bridged by Rigid Pt-Containing Conjugated Organometallic Spacers Diana Bellows, Shawkat M. Aly, Claude P. Gros, Maya El Ojaimi, Jean-Michel Barbe, Roger Guilard and Pierre D. Harvey pp 7613–7629 DOI: 10.1021/ic900840w Supporting Info

Design and Synthesis of Coumarin-Based Zn2+ Probes for Ratiometric Fluorescence Imaging Shin Mizukami, Satoshi Okada, Satoshi Kimura and Kazuya Kikuchi pp 7630–7638 DOI: 10.1021/ic900247r Supporting Info

Kinetic and Mechanistic Studies of Geometrical Isomerism in Neutral Square-Planar Methylpalladium Complexes Bearing Unsymmetrical Bidentate Ligands of α-Aminoaldimines Feng-Zhao Yang, Yu-Heng Wang, Mu-Chieh Chang, Kuo-Hsuan Yu, Shou-Ling Huang, Yi-Hung Liu, Yu Wang, Shiuh-Tzung Liu and Jwu-Ting Chen pp 7639–7644 DOI: 10.1021/ic900296y Supporting Info

Dehydrogenation of LGeH by a Lewis N-Heterocyclic Carbene Borane Pair under the Formation of L′Ge and its Reactions with B(C6F5)3 and Trimethylsilyl Diazomethane: An Unprecedented Rearrangement of a Diazocompound to an Isonitrile Anukul Jana, Ina Objartel, Herbert W. Roesky and Dietmar Stalke pp 7645–7649 DOI: 10.1021/ic900341r Supporting Info

Color Properties and Structural Phase Transition in Penta- And Hexacoordinate Isothiocyanato Ni(II) Compounds T. V. Brinzari, C. Tian, G. J. Halder, J. L. Musfeldt, M.-H. Whangbo and J. A. Schlueter pp 7650–7658 DOI: 10.1021/ic802120n Supporting Info

Insight into Ramsdellite Li2Ti3O7 and Its Proton-Exchange Derivative Alodia Orera, M. Teresa Azcondo, Flaviano Garca-Alvarado, Jess Sanz, Isabel Sobrados, Juan Rodrguez-Carvajal and Ulises Amador pp 7659–7666 DOI: 10.1021/ic900398j

Mechanistic Investigations of the Reaction of an Iron(III) Octa-Anionic Porphyrin Complex with Hydrogen Peroxide and the Catalyzed Oxidation of Diammonium-2,2′-azinobis(3-ethylbenzothiazoline-6-sulfonate) Ariane Brausam, Siegfried Eigler, Norbert Jux and Rudi van Eldik pp 7667–7678 DOI: 10.1021/ic9005955 Supporting Info

Behavior of P−Pt and P−Pd Bonds in Phosphido Complexes toward Electrophilic Fragments Ester Alonso, Juan Fornis, Consuelo Fortuo, Agust Lleds, Antonio Martn and Ainara Nova pp 7679–7690 DOI: 10.1021/ic900415m Supporting Info

Structural, Luminescent, and Magnetic Properties of Three Novel Three-Dimensional Metal-Organic Frameworks Based on Hexadentate N,N′-bis(4-picolinoyl)hydrazine Zhen-Lan Fang, Rong-Min Yu, Jian-Gang He, Qi-Sheng Zhang, Zhen-Guo Zhao and Can-Zhong Lu pp 7691–7697 DOI: 10.1021/ic9004533 Supporting Info

Impact of Constitutional Isomers of (BMes2)phenylpyridine on Structure, Stability, Phosphorescence, and Lewis Acidity of Mononuclear and Dinuclear Pt(II) Complexes Ying-Li Rao and Suning Wang pp 7698–7713 DOI: 10.1021/ic9007069 Supporting Info

On the Reactivity of F3S≡NXeF+: Syntheses and Structural Characterizations of [F4S═N−Xe---N≡SF3][AsF6], a Rare Example of a N−Xe−N Linkage, and [F3S(N≡SF3)2][AsF6] Gregory L. Smith and Gary J. Schrobilgen pp 7714–7728 DOI: 10.1021/ic900651n Supporting Info

Oxidation of the Natural Amino Acids by a Ferryl Complex: Kinetic and Mechanistic Studies with Peptide Model Compounds Ahmed I. Abouelatta, Ashley A. Campanali, Anil R. Ekkati, Mark Shamoun, Suneth Kalapugama and Jeremy J. Kodanko pp 7729–7739 DOI: 10.1021/ic900527c Supporting Info

Injection, Transport, Absorption and Phosphorescence Properties of a Series of Blue-Emitting Ir(III) Emitters in OLEDs: a DFT and Time-Dependent DFT Study Xiao-Na Li, Zhi-Jian Wu, Zhen-Jun Si, Hong-Jie Zhang, Liang Zhou and Xiao-Juan Liu pp 7740–7749 DOI: 10.1021/ic900585p Supporting Info

Ground-State Electronic Structure of Vanadium(III) Trisoxalate in Hydrated Compounds Kevin R. Kittilstved, Lilit Aboshyan Sorgho, Nahid Amstutz, Philip L.W. Tregenna-Piggott and Andreas Hauser pp 7750–7764 DOI: 10.1021/ic900613p Supporting Info

New Family of Ferric Spin Clusters Incorporating Redox-Active ortho-Dioxolene Ligands Yanyan Mulyana, Ayman Nafady, Arindam Mukherjee, Roland Bircher, Boujemaa Moubaraki, Keith S. Murray, Alan M. Bond, Brendan F. Abrahams and Colette Boskovic pp 7765–7781 DOI: 10.1021/ic900729d Supporting Info

CdCu3(OH)6(NO3)2: An S = 1/2 Kagom Antiferromagnet Emily A. Nytko, Matthew P. Shores, Joel S. Helton and Daniel G. Nocera pp 7782–7786 DOI: 10.1021/ic900665j Supporting Info

Displacement Kinetics of η2-Bound Furan and 2,3-Dihydrofuran from Mn and Cr Centers: Evidence for the Partial Dearomatization of the Furan Ligand Jeremy R. Andreatta, G. Benjamin Cieslinski, Madeeha Batool, Xue-Zhong Sun, Michael W. George, Edward N. Brothers, Donald J. Darensbourg and Ashfaq A. Bengali pp 7787–7793 DOI: 10.1021/ic900724f Supporting Info

Copper Corroles Are Inherently Saddled Abraham B. Alemayehu, Emmanuel Gonzalez, Lars Kristian Hansen and Abhik Ghosh pp 7794–7799 DOI: 10.1021/ic900744v Supporting Info

Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)·2H2O Yongjiang Wang, Shilie Pan, Xuelin Tian, Zhongxiang Zhou, Gang Liu, Jide Wang and Dianzeng Jia pp 7800–7804 DOI: 10.1021/ic900700u Supporting Info

Thiol-Dependent Membrane Transport of Selenium through an Integral Protein of the Red Blood Cell Membrane Mamoru Haratake, Masafumi Hongoh, Masahiro Ono and Morio Nakayama pp 7805–7811 DOI: 10.1021/ic900988j

Synthesis, Structure, and Magnetism of a Polyoxometalate with Coordinatively Unsaturated d-Electron-Transition Metal Centers Zhen Luo, Paul Kgerler, Rui Cao and Craig L. Hill pp 7812–7817 DOI: 10.1021/ic9007729 Supporting Info

Closo versus Hypercloso Metallaboranes: A DFT Study Oottikkal Shameema and Eluvathingal D. Jemmis pp 7818–7827 DOI: 10.1021/ic900741y Supporting Info

Investigation of the Reactivity of Pt Phosphinito and Molybdocene Nitrile Hydration Catalysts With Cyanohydrins Takiya J. Ahmed, Brandy R. Fox, Spring Melody M. Knapp, Robert B. Yelle, J. Jerrick Juliette and David R. Tyler pp 7828–7837 DOI: 10.1021/ic900734d Supporting Info

Prediction of the Spin Transition Temperature in FeII One-Dimensional Coordination Polymers: an Anion Based Database Marinela M. Drtu, Aurelian Rotaru, Damien Gillard, Jorge Linares, Epiphane Codjovi, Bernard Tinant and Yann Garcia pp 7838–7852 DOI: 10.1021/ic900814b Supporting Info

Strong Metal Ion Size Based Selectivity of the Highly Preorganized Ligand PDA (1,10-Phenanthroline-2,9-dicarboxylic Acid) with Trivalent Metal Ions. A Crystallographic, Fluorometric, and Thermodynamic Study Neil J. Williams, Nolan E. Dean, Donald G. VanDerveer, Robert C. Luckay and Robert D. Hancock pp 7853–7863 DOI: 10.1021/ic900737q

Detailed Spectroscopic, Thermodynamic, and Kinetic Studies on the Protolytic Equilibria of FeIIIcydta and the Activation of Hydrogen Peroxide Ariane Brausam, Joachim Maigut, Roland Meier, Petra . Szilgyi, Hans-Jrgen Buschmann, Werner Massa, Zoltn Homonnay and Rudi van Eldik pp 7864–7884 DOI: 10.1021/ic900834z Supporting Info

Axial Ligand Exchange Reactions of meso-Aryl Subporphyrins—Axially Fluoro-Substituted Subporphyrin and a μ-Oxo Dimer and Trimer of Subporphyrins Soji Shimizu, Atsushi Matsuda and Nagao Kobayashi pp 7885–7890 DOI: 10.1021/ic900880b Supporting Info

Experimental and Computational Studies of Binding of Dinitrogen, Nitriles, Azides, Diazoalkanes, Pyridine, and Pyrazines to M(PR3)2(CO)3 (M = Mo, W; R = Me, iPr). Patrick Achord, Etsuko Fujita, James T. Muckerman, Brian Scott, George C. Fortman, Manuel Temprado, Xiaochen Cai, Burjor Captain, Derek Isrow, John J. Weir, James Eric McDonough and Carl D. Hoff pp 7891–7904 DOI: 10.1021/ic900764e Supporting Info

Unsymmetrical FeIIICoII and GaIIICoII Complexes as Chemical Hydrolases: Biomimetic Models for Purple Acid Phosphatases (PAPs) Fernando R. Xavier, Ademir Neves, Annelise Casellato, Rosely A. Peralta, Adailton J. Bortoluzzi, Bruno Szpoganicz, Patricia C. Severino, Hernn Terenzi, Zbigniew Tomkowicz, Sergei Ostrovsky, Wolfgang Haase, Andrew Ozarowski, Jerzy Krzystek, Joshua Telser, Gerhard Schenk and Lawrence R. Gahan pp 7905–7921 DOI: 10.1021/ic900831q Supporting Info

Intramolecular Rotation of Iron(II) Dithiaethyneporphyrin Double-Decker Complex: 1H NMR Studies Anna Berlicka and Lechosław Latos-Grayski pp 7922–7930 DOI: 10.1021/ic900973d Supporting Info

Synthesis of Designed Conductive One-Dimensional Coordination Polymers of Ni(II) with 6-Mercaptopurine and 6-Thioguanine Pilar Amo-Ochoa, Oscar Castillo, Simone S. Alexandre, Lorena Welte, Pedro J. de Pablo, Ma Isabel Rodrguez-Tapiador, Julio Gmez-Herrero and Flix Zamora pp 7931–7936 DOI: 10.1021/ic900896w Supporting Info

Surprisingly Bright Near-Infrared Luminescence and Short Radiative Lifetimes of Ytterbium in Hetero-Binuclear Yb−Na Chelates Nail M. Shavaleev, Rosario Scopelliti, Frdric Gumy and Jean-Claude G. Bnzli pp 7937–7946 DOI: 10.1021/ic900888m Supporting Info

Oxidation of Carbon Monoxide Cocatalyzed by Palladium(0) and the H5PV2Mo10O40 Polyoxometalate Probed by Electron Paramagnetic Resonance and Aerobic Catalysis Hila Goldberg, Ilia Kaminker, Daniella Goldfarb and Ronny Neumann pp 7947–7952 DOI: 10.1021/ic900868t Supporting Info

Kinetic and Thermodynamic Stability of the Group 13 Trihydrides Brian Vest, Karl Klinkhammer, Christian Thierfelder, Matthias Lein and Peter Schwerdtfeger pp 7953–7961 DOI: 10.1021/ic900997p

Electrochemical Fluorination of La2CuO4: A Mild “Chimie Douce” Route to Superconducting Oxyfluoride Materials M. H. Delville, D. Barbut, A. Wattiaux, J. M. Bassat, M. Mntrier, C. Labrugre, J. C. Grenier and J. Etourneau pp 7962–7969 DOI: 10.1021/ic900912d

New Heterometallic Carboxylate Frameworks: Synthesis, Structure, Robustness, Flexibility, and Porosity Jie-Peng Zhang, Sujit K. Ghosh, Jian-Bin Lin and Susumu Kitagawa pp 7970–7976 DOI: 10.1021/ic900919w Supporting Info

Synthesis and Characterization of the Dinuclear Polyhydrides [Os2H7(PPhiPr2)4]+ and [Os2H6(PPhiPr2)4] Bradley G. Anderson, Sarah A. Hoyte and John L. Spencer pp 7977–7983 DOI: 10.1021/ic900111s Supporting Info

Synthesis of Tetranuclear Rhodium and Iridium Complexes Directed by 6-Mercaptopyridin-2-ol: Electrochemical Behavior, Chemical Oxidation, and Coordination Chemistry Pablo J. Alonso, Oscar Bened, Mara J. Fabra, Fernando J. Lahoz, Luis A. Oro and Jess J. Prez-Torrente pp 7984–7993 DOI: 10.1021/ic9005289 Supporting Info

Speciation of Ferriprotoporphyrin IX in Aqueous and Mixed Aqueous Solution Is Controlled by Solvent Identity, pH, and Salt Concentration Constance Asher, Katherine A. de Villiers and Timothy J. Egan pp 7994–8003 DOI: 10.1021/ic900647y Supporting Info

Monomeric, Dimeric, and Trimeric Calcium Compounds Containing Substituted Pyrrolyl and Ketiminate Ligands: Synthesis and Structural Characterization Shih-Mao Ho, Ching-Sheng Hsiao, Amitabha Datta, Chen-Hsiung Hung, Ling-Chueh Chang, Ting-Yu Lee and Jui-Hsien Huang pp 8004–8011 DOI: 10.1021/ic900265c Supporting Info

Theoretical Methods Enlighten Magnetic Properties of a Family of Mn6 Single-Molecule Magnets Eduard Cremades, Joan Cano, Eliseo Ruiz, Gopalan Rajaraman, Constantinos J. Milios and Euan K. Brechin pp 8012–8019 DOI: 10.1021/ic900992r Supporting Info

Ligand Exchange Reactions and Hydroamination with Tris(oxazolinyl)borato Yttrium Compounds Andrew V. Pawlikowski, Arkady Ellern and Aaron D. Sadow pp 8020–8029 DOI: 10.1021/ic900689k Supporting Info

Homoleptic Ruthenium Complex Bearing Dissymmetrical 4-Carboxy-4′-pyrrolo-2,2′-bipyridine for Efficient Sensitization of TiO2 in Solar Cells Arnald Grabulosa, Marc Beley, Philippe C. Gros, Silvia Cazzanti, Stefano Caramori and Carlo A. Bignozzi pp 8030–8036 DOI: 10.1021/ic9009256

Synthesis, Structure, and Reactivity of Low-Coordinate 1,1,3,3-Tetraethylguanidinate Complexes Scott D. Bunge, Jeffrey A. Bertke and Travis L. Cleland pp 8037–8043 DOI: 10.1021/ic9007153 Supporting Info

129I Mssbauer Spectroscopic Study of a Metallic MMX Chain System Atsushi Kobayashi, Shinji Kitao, Makoto Seto, Ryuichi Ikeda and Hiroshi Kitagawa pp 8044–8049 DOI: 10.1021/ic9007558

Copper(I) Cyanide Networks: Synthesis, Structure, and Luminescence Behavior. Part 2. Piperazine Ligands and Hexamethylenetetramine Mi Jung Lim, Courtney A. Murray, Tristan A. Tronic, Kathryn E. deKrafft, Amanda N. Ley, Jordan C. deButts, Robert D. Pike, Haiyan Lu and Howard H. Patterson p 8050 DOI: 10.1021/ic901380b

Issue 17

Salen-Based [Zn2Ln3] Complexes with Fluorescence and Single-Molecule-Magnet Properties Carolyn E. Burrow, Tara J. Burchell, Po-Heng Lin, Fatemah Habib, Wolfgang Wernsdorfer, Rodolphe Clrac and Muralee Murugesu pp 8051–8053 DOI: 10.1021/ic9007944 Supporting Info

Water-Soluble Macrocycles Synthesized via the Weak-Link Approach Michael J. Wiester and Chad A. Mirkin pp 8054–8056 DOI: 10.1021/ic900983v Supporting Info

Interpenetrating Polyhedral MOF with a Primitive Cubic Network Based on Supermolecular Building Blocks Constructed of a Semirigid C3-Symmetric Carboxylate Ligand Xiaoliang Zhao, Haiyan He, Tuoping Hu, Fangna Dai and Daofeng Sun pp 8057–8059 DOI: 10.1021/ic901004m Supporting Info

Quaternary Tin(IV) Antimony(III) Sulfide Decorated with Lanthanum(III) Ethylenediamine Complexes: [La(en)4SbSnS5]2·0.5H2O Mei-Ling Feng, Dong Ye and Xiao-Ying Huang pp 8060–8062 DOI: 10.1021/ic901044k Supporting Info

Modeling the Direct Activation of Dihydrogen by a P2C2 Cyclic Biradical: Formation of a Cyclic Bis(P−H λ5-phosphorane) Shigekazu Ito, Joji Miura, Noboru Morita, Masaaki Yoshifuji and Anthony J. Arduengo, III pp 8063–8065 DOI: 10.1021/ic901072z Supporting Info

Isolated Co15 Clusters and Their Assembly into a 3D Network: Conformation-Directed Synthesis Zhi-Guo Gu and Slavi C. Sevov pp 8066–8068 DOI: 10.1021/ic9010778 Supporting Info

Magnesium-Based 3D Metal−Organic Framework Exhibiting Hydrogen-Sorption Hysteresis Zhiyong Guo, Guanghua Li, Liang Zhou, Shenqqun Su, Yongqian Lei, Song Dang and Hongjie Zhang pp 8069–8071 DOI: 10.1021/ic901056d Supporting Info

Rhenium(V) Complexes with Pentadentate P,N,O Ligands Ali Barandov and Ulrich Abram pp 8072–8074 DOI: 10.1021/ic901152y Supporting Info

2,2′-Bipyrrolidine versus 1,2-Diaminocyclohexane as Chiral Cores for Helically Wrapping Diamine−Diolate Ligands Ekaterina Sergeeva, Jacob Kopilov, Israel Goldberg and Moshe Kol pp 8075–8077 DOI: 10.1021/ic901367k Supporting Info

Stability of a Ferryl−Peptide Conjugate Is Controlled by a Remote Substituent Nitinkumar D. Jabre, Lew Hryhorczuk and Jeremy J. Kodanko pp 8078–8080 DOI: 10.1021/ic9013653 Supporting Info

Germylene and Silylene Complexes of Molybdenum via E−H (E = Ge, Si) Bond Activations: Steric Influences on Intramolecular MoH···E Interactions Akihiro Shinohara, Jennifer McBee and T. Don Tilley pp 8081–8083 DOI: 10.1021/ic901168s Supporting Info

Photochromic Ruthenium Sulfoxide Complexes: Evidence for Isomerization Through a Conical Intersection Beth Anne McClure, Nicholas V. Mockus, Dennis P. Butcher,, Jr., Daniel A. Lutterman, Claudia Turro, Jeffrey L. Petersen and Jeffrey J. Rack pp 8084–8091 DOI: 10.1021/ic900421v Supporting Info

pH-Dependent Syntheses, Structural and Spectroscopic Characterization, and Chemical Transformations of Aqueous Co(II)−Quinate Complexes: An Effort to Delve into the Structural Speciation of the Binary Co(II)−Quinic Acid System M. Menelaou, A. Konstantopai, C. Mateescu, H. Zhao, C. Drouza, N. Lalioti and A. Salifoglou pp 8092–8105 DOI: 10.1021/ic801500x Supporting Info

A Structurally Diverse Series of Aluminum Chloride Alkoxides [ClxAl(μ-OR)y]n (R = nBu, cHex, Ph, 2,4-tBu2C6H3) Zdenek Moravec, Radek Sluka, Marek Necas, Vojtech Jancik and Jiri Pinkas pp 8106–8114 DOI: 10.1021/ic802251g Supporting Info

Second-Order Nonlinear Optical Properties of Trisubstituted Keggin and Wells−Dawson Polyoxometalates: Density Functional Theory Investigation of the Inorganic Donor-Conjugated Bridge−Acceptor Structure Chun-Guang Liu, Wei Guan, Ping Song, Zhong-Min Su, Chan Yao and En-Bo Wang pp 8115–8119 DOI: 10.1021/ic900829z

Electrochemical, Linear Optical, and Nonlinear Optical Properties and Interpretation by Density Functional Theory Calculations of (4-N,N-Dimethylaminostyryl)-Pyridinium Pendant Group Associated with Polypyridinic Ligands and Respective Multifunctional Metal Complexes (RuII or ZnII) Frdric Dumur, Cdric R. Mayer, Khuyen Hoang-Thi, Isabelle Ledoux-Rak, Fabien Miomandre, Gilles Clavier, Eddy Dumas, Rachel Mallet-Renault, Michel Frigoli, Joseph Zyss and Francis Scheresse pp 8120–8133 DOI: 10.1021/ic900060d Supporting Info

Three-Coordinate, Phosphine-Ligated Azadipyrromethene Complexes of Univalent Group 11 Metals Thomas S. Teets, James B. Updegraff, III, Arthur J. Esswein and Thomas G. Gray pp 8134–8144 DOI: 10.1021/ic900208a Supporting Info

Donor−Acceptor “Dressing” of “Naked” Group 13−15 Cubanes Alexey Y. Timoshkin pp 8145–8153 DOI: 10.1021/ic900270c Supporting Info

Oxygen Atom Transfer Reactions of Iridium and Osmium Complexes: Theoretical Study of Characteristic Features and Significantly Large Differences Between These Two Complexes Atsushi Ishikawa, Yoshihide Nakao, Hirofumi Sato and Shigeyoshi Sakaki pp 8154–8163 DOI: 10.1021/ic900285b Supporting Info

Authentic-Blue Phosphorescent Iridium(III) Complexes Bearing Both Hydride and Benzyl Diphenylphosphine; Control of the Emission Efficiency by Ligand Coordination Geometry Yuan-Chieh Chiu, Chen-Huey Lin, Jui-Yi Hung, Yun Chi, Yi-Ming Cheng, Kang-Wei Wang, Min-Wen Chung, Gene-Hsiang Lee and Pi-Tai Chou pp 8164–8172 DOI: 10.1021/ic900607s Supporting Info

Combined Mssbauer Spectral and Density Functional Theory Determination of the Magnetic Easy-Axis in Two High-Spin Iron(II) 2-Pyrazinecarboxylate Complexes Gary J. Long, Stefania Tanase, Franoise Remacle, Ganga Periyasamy and Fernande Grandjean pp 8173–8179 DOI: 10.1021/ic9003609 Supporting Info

Synthesis and Characterization of One-Dimensional and Molecular M(tren)InAsS4 (M = Mn, Co, and Zn) Compounds with a Noncondensed AsS33− Unit Zhenqing Wang, Hongjie Zhang and Cheng Wang pp 8180–8185 DOI: 10.1021/ic900456t Supporting Info

Donor-Set-Induced Coordination Sphere and Oxidation-State Switching in the Copper Complexes of O2S2X (X = S, O and NH) Macrocycles Minhye Jo, Joobeom Seo, Moo Lyong Seo, Kyu Seong Choi, Seong Keuck Cha, Leonard F. Lindoy and Shim Sung Lee pp 8186–8191 DOI: 10.1021/ic901009r Supporting Info

Cap for Copper(I) Ions! Metallosupramolecular Solid and Solution State Structures on the Basis of the Dynamic Tetrahedral [Cu(phenAr2)(py)2]+ Motif Michael Schmittel, Bice He, Jian Fan, Jan W. Bats, Marianne Engeser, Marc Schlosser and Hans-Jrg Deiseroth pp 8192–8200 DOI: 10.1021/ic900657w Supporting Info

Complexation of Metal Ions of Higher Charge by the Highly Preorganized Tetradentate Ligand 2,9-Bis(hydroxymethyl)-1,10-Phenanthroline. A Crystallographic and Thermodynamic Study Raymond T. Gephart, III, Neil J. Williams, Joseph H. Reibenspies, Alvaro S. De Sousa and Robert D. Hancock pp 8201–8209 DOI: 10.1021/ic900650d

Toward the Synthesis of High Boron Content Polyanionic Multicluster Macromolecules Pau Farrs, Ana Maria Cioran, Vclav cha, Francesc Teixidor, Bohumil tbr, Bohumr Grner and Clara Vias pp 8210–8219 DOI: 10.1021/ic9006907

Crystal Growth, Structural Properties, and Photophysical Characterization of Ln4Na2K2M2O13 (M = Nb, Ta; Ln = Nd, Sm, Eu, Gd) Thomas-C. Jagau, Irina P. Roof, Mark D. Smith and Hans-Conrad zur Loye pp 8220–8226 DOI: 10.1021/ic9006873 Supporting Info

Reinvestigation of the Uranium(3.5+) Rare-Earth Oxysulfides “(UO)2LnS3” (Ln = Yb, Y) Geng Bang Jin, Eun Sang Choi and James A. Ibers pp 8227–8232 DOI: 10.1021/ic900860c Supporting Info

Soluble Redox-Active Polymetallic Chains [{Ru0(CO)(L)(bpy)}m]n (bpy = 2,2′-bipyridine, L = PrCN, Cl−; m = 0, −1): Electrosynthesis and Characterization Frantiek Hartl, Anna K. Renfrew, Frdric Lafolet, Taasje Mahabiersing, Maria Jos Calhorda, Sylvie Chardon-Noblat, Matti Haukka and Alain Deronzier pp 8233–8244 DOI: 10.1021/ic9008043 Supporting Info

Simple and Reproducible Procedure to Prepare Self-Nanostructured NiO Films for the Fabrication of P-Type Dye-Sensitized Solar Cells Loc Lepleux, Benoit Chavillon, Yann Pellegrin, Errol Blart, Laurent Cario, Stphane Jobic and Fabrice Odobel pp 8245–8250 DOI: 10.1021/ic900866g

High-Pressure Structural Transitions of Sc2O3 by X-ray Diffraction, Raman Spectra, and Ab Initio Calculations Dan Liu, Weiwei Lei, Yinwei Li, Yanming Ma, Jian Hao, Xiaohui Chen, Yunxia Jin, Dedi Liu, Shidan Yu, Qiliang Cui and Guangtian Zou pp 8251–8256 DOI: 10.1021/ic900889v Supporting Info

Two Variants of the 1/2[110]p(203)p Crystallographic Shear Structures: The Phasoid Sr0.61Pb0.18(Fe0.75Mn0.25)O2.29 Christophe Lepoittevin, Joke Hadermann, Sylvie Malo, Olivier Prez, Gustaaf Van Tendeloo and Maryvonne Hervieu pp 8257–8262 DOI: 10.1021/ic900762s

Three-Component Noncovalent Assembly Consisting of a Central Tetrakis-4-pyridyl Porphyrin and Two Lateral Gable-Like Bis-Zn Porphyrins Maryline Beyler, Valrie Heitz, Jean-Pierre Sauvage, Barbara Ventura, Lucia Flamigni and Kari Rissanen pp 8263–8270 DOI: 10.1021/ic900887q Supporting Info

Nature of Insulating-Phase Transition and Degradation of Structure and Electrochemical Reactivity in an Olivine-Structured Material, LiFePO4 Min-Sang Song, Yong-Mook Kang, Yong-Il Kim, Kyu-Sung Park and Hyuk-Sang Kwon pp 8271–8275 DOI: 10.1021/ic9009114 Supporting Info

Lanthanide (Eu3+, Tb3+)/β-Diketone Modified Mesoporous SBA-15/Organic Polymer Hybrids: Chemically Bonded Construction, Physical Characterization, and Photophysical Properties Ya-Juan Li and Bing Yan pp 8276–8285 DOI: 10.1021/ic900971h

The Coordination of the Tetraselenidoantimonate [SbSe4]3− Anion with Trivalent Lanthanide Ions Tuned by Ethylene Polyamines Dingxian Jia, Qinyan Jin, Jiangfang Chen, Yingli Pan and Yong Zhang pp 8286–8293 DOI: 10.1021/ic900901t Supporting Info

Combination Chemistry of Hexa-Copper-Substituted Polyoxometalates Driven by the CuII−Polyhedra Distortion: From Tetramer, 1D Chain to 3D Framework Bing Li, Jun-Wei Zhao, Shou-Tian Zheng and Guo-Yu Yang pp 8294–8303 DOI: 10.1021/ic900931r Supporting Info

Synthesis and Characterization of Alkali-Metal Salts of 2,2′- and 2,4′-Bipyridyl Radicals and Dianions Edward Gore-Randall, Mark Irwin, Mark S. Denning and Jose M. Goicoechea pp 8304–8316 DOI: 10.1021/ic9009459 Supporting Info

A High-Spin Organometallic Fe−S Compound: Structural and Mssbauer Spectroscopic Studies of [Phenyltris((tert-butylthio)methyl)borate]Fe(Me) Codrina V. Popescu, Michael T. Mock, Sebastian A. Stoian, William G. Dougherty, Glenn P. A. Yap and Charles G. Riordan pp 8317–8324 DOI: 10.1021/ic900939c Supporting Info

Characterization of Two Distinct Adducts in the Reaction of a Nonheme Diiron(II) Complex with O2 Jonathan R. Frisch, Van V. Vu, Marlne Martinho, Eckard Mnck and Lawrence Que, Jr. pp 8325–8336 DOI: 10.1021/ic900961k Supporting Info

Synthesis, Electronic and Crystal Structures, and Physical Studies of the Superconductor Cs1Mo12S14, Final Step of the Condensation of the Mo6L8iL6a Unit Patrick Gougeon, Diala Salloum, Jrme Cuny, Laurent Le Polls, Marie Le Floch, Rgis Gautier and Michel Potel pp 8337–8341 DOI: 10.1021/ic900960g Supporting Info

Molecular Oxygen and Sulfur Reactivity of a Cyclotriveratrylene Derived Trinuclear Copper(I) Complex Debabrata Maiti, Julia S. Woertink, Reza A. Ghiladi, Edward I. Solomon and Kenneth D. Karlin pp 8342–8356 DOI: 10.1021/ic900975y Supporting Info

Flux Synthesis of Salt-Inclusion Uranyl Silicates: [K3Cs4F][(UO2)3(Si2O7)2] and [NaRb6F][(UO2)3(Si2O7)2] Cheng-Shiuan Lee, Sue-Lein Wang, Yen-Hung Chen and Kwang-Hwa Lii pp 8357–8361 DOI: 10.1021/ic901001n Supporting Info

Effective Control of Ligation and Geometric Isomerism: Direct Comparison of Steric Properties Associated with Bis-mesityl and Bis-diisopropylphenyl m-Terphenyl Isocyanides Treffly B. Ditri, Brian J. Fox, Curtis E. Moore, Arnold L. Rheingold and Joshua S. Figueroa pp 8362–8375 DOI: 10.1021/ic9010828 Supporting Info

New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra Myung-Ho Choi, Sang-Hwan Kim, Hong-Young Chang, P. Shiv Halasyamani and Kang Min Ok pp 8376–8382 DOI: 10.1021/ic901064q Supporting Info

Detailed Evaluation of the Geometric and Electronic Structures of One-Electron Oxidized Group 10 (Ni, Pd, and Pt) Metal(II)-(Disalicylidene)diamine Complexes Yuichi Shimazaki, T. Daniel P. Stack and Tim Storr pp 8383–8392 DOI: 10.1021/ic901003q Supporting Info

Influence of Sulf-Oxygenation on CO/L Substitution and Fe(CO)3 Rotation in Thiolate-Bridged Diiron Complexes Bin Li, Tianbiao Liu, Michael L. Singleton and Marcetta Y. Darensbourg pp 8393–8403 DOI: 10.1021/ic901093c Supporting Info

Manipulating Self-Assembly in Silver(I) Complexes of 1,3-Di-N-pyrazolylorganyls Brendan J. Liddle, Daniel Hall, Sergey V. Lindeman, Mark D. Smith and James R. Gardinier pp 8404–8414 DOI: 10.1021/ic900982m Supporting Info

Cationic Dimetallic Gold Hydride Complex Stabilized by a Xantphos-Phosphole ligand: Synthesis, X-ray Crystal Structure, and Density Functional Theory Study Aurlie Escalle, Guilhem Mora, Fabien Gagosz, Nicolas Mzailles, Xavier F. Le Goff, Yves Jean and Pascal Le Floch pp 8415–8422 DOI: 10.1021/ic901014r Supporting Info

Stereospecific Formation of Dinuclear Vanadium(V) Tartrato Complexes Jana Glikov, Peter Schwendt, Jozef Tatiersky, Alan S. Tracey and Zdirad k pp 8423–8430 DOI: 10.1021/ic901024p Supporting Info

1,3-Diazido-2-(azidomethyl)-2-propylammonium Salts Young-Hyuk Joo and Jean’ne M. Shreeve pp 8431–8438 DOI: 10.1021/ic901019p Supporting Info

Synthesis, Structure, and Magnetic Properties of Na3LnMn3O3(AsO4)3 (Ln = La, Sm, and Gd): A New 3d-4f Series Exhibiting One-Dimensional Manganese(III) Oxide Chains Connected via LnO9 Units J. Palmer West, Shiou-Jyh Hwu and Wendy L. Queen pp 8439–8444 DOI: 10.1021/ic901043g Supporting Info

Photoinduced Release of Zn2+ with ZinCleav-1: a Nitrobenzyl-Based Caged Complex H. M. Dhammika Bandara, Daniel P. Kennedy, Elif Akin, Christopher D. Incarvito and Shawn C. Burdette pp 8445–8455 DOI: 10.1021/ic901062n Supporting Info

Nickel(II) Complexes of Monofunctionalized Pyridine-Azamacrocycles: Synthesis, Structures, Pendant Arm “On-Off” Coordination Equilibria, and Peroxidase-like Activity Voltaire G. Organo, Alexander S. Filatov, Justin S. Quartararo, Zachary M. Friedman and Elena V. Rybak-Akimova pp 8456–8468 DOI: 10.1021/ic901083u Supporting Info

Circularly Polarized Luminescence in Enantiopure Europium and Terbium Complexes with Modular, All-Oxygen Donor Ligands Michael Seitz, King Do, Andrew J. Ingram, Evan G. Moore, Gilles Muller and Kenneth N. Raymond pp 8469–8479 DOI: 10.1021/ic901079s Supporting Info

New Class of Single-Source Precursors for the Synthesis of Main Group−Transition Metal Oxides: Heterobimetallic Pb−Mn β-Diketonates Haitao Zhang, Jen-Hsien Yang, Roman V. Shpanchenko, Artem M. Abakumov, Joke Hadermann, Rodolphe Clrac and Evgeny V. Dikarev pp 8480–8488 DOI: 10.1021/ic901107s Supporting Info

Intermetallic Charge Transfer in A-Site-Ordered Double Perovskite BiCu3Fe4O12 Youwen Long, Takashi Saito, Takenori Tohyama, Kengo Oka, Masaki Azuma and Yuichi Shimakawa pp 8489–8492 DOI: 10.1021/ic901128k

Sitting-Atop Metallo-Porphyrin Complexes: Experimental and Theoretical Investigations on Such Elusive Species Giovanna De Luca, Andrea Romeo, Luigi Mons Scolaro, Giampaolo Ricciardi and Angela Rosa pp 8493–8507 DOI: 10.1021/ic9012153 Supporting Info

The Unique Palladium-Centered Pentagonal Antiprismatic Cationic Bismuth Cluster: A Comparison of Related Metal-Centered 10-Vertex Pnictogen Cluster Structures by Density Functional Theory R. B. King, I. Silaghi-Dumitrescu and M. M. U pp 8508–8514 DOI: 10.1021/ic901293h Supporting Info

Luminescence Study of Eu(III) Analogues of Esterase-Activated Magnetic Resonance Contrast Agents Marco Giardiello and Mark P. Lowe pp 8515–8522 DOI: 10.1021/ic901284t Supporting Info

Bis(oxazolinylmethyl)pyrrole Derivatives and Their Coordination as Chiral “Pincer” Ligands to Rhodium Felix Konrad, Julio Lloret Fillol, Hubert Wadepohl and Lutz H. Gade pp 8523–8535 DOI: 10.1021/ic901189k Supporting Info

Sexithiophenes Mediated by MM Quadruple Bonds: MM = Mo2, MoW, and W2 Brian G. Alberding, Malcolm H. Chisholm, Yagnaseni Ghosh, Terry L. Gustafson, Yao Liu and Claudia Turro pp 8536–8543 DOI: 10.1021/ic901303a Supporting Info

Size-Controlled Submicrometer Hollow Spheres Constituted of ZnO Nanoplates from Layered Zinc Hydroxide Makoto Moriya, Kyohei Yoshikawa, Wataru Sakamoto and Toshinobu Yogo pp 8544–8549 DOI: 10.1021/ic900864a Supporting Info

Methanol as a Reaction Medium and Reagent in Substrate Reactions of Rhodium Porphyrins Shan Li, Sounak Sarkar and Bradford B. Wayland pp 8550–8558 DOI: 10.1021/ic900900k

Reactivity of Neutral Mo(S2C6H4)3 in Aqueous Media: an Alternative Functional Model of Sulfite Oxidase. Francisco Prez Pla, Antonio Cervilla, Mara Piles and Elisa Llopis pp 8559–8568 DOI: 10.1021/ic802128r Supporting Info

Molybdenum Triamidoamine Systems. Reactions Involving Dihydrogen Relevant to Catalytic Reduction of Dinitrogen Dennis G. H. Hetterscheid, Brian S. Hanna and Richard R. Schrock pp 8569–8577 DOI: 10.1021/ic900468n

Synthesis, Characterization, Absorption Spectra, and Luminescence Properties of Multinuclear Species Made of Ru(II) and Ir(III) Chromophores Marco Cavazzini, Silvio Quici, Chiara Scalera, Fausto Puntoriero, Giuseppina La Ganga and Sebastiano Campagna pp 8578–8592 DOI: 10.1021/ic9006108 Supporting Info

Syntheses of the Terpyridine−Bipyridine Linked Binary Ligands and Structural and Redox Properties of Their Cobalt Complexes Hiroki Kon and Toshi Nagata pp 8593–8602 DOI: 10.1021/ic900932j Supporting Info

Primary Phosphines Studied by Gas-Phase Electron Diffraction and Quantum Chemical Calculations. Are They Different from Amines? Robert Noble-Eddy, Sarah L. Masters, David W. H. Rankin, Derek A. Wann, Heather E. Robertson, Brahim Khater and Jean-Claude Guillemin pp 8603–8612 DOI: 10.1021/ic901018s Supporting Info

Synthesis and Structures of Group 11 Metal Triazenide Complexes: Ligand Supported Metallophilic Interactions Andrew L. Johnson, Alexander M. Willcocks and Stephen P. Richards pp 8613–8622 DOI: 10.1021/ic901051f Supporting Info

Phosphines Bearing Alkyne Substituents: Synthesis and Hydrophosphination Polymerization Sharonna Greenberg and Douglas W. Stephan pp 8623–8631 DOI: 10.1021/ic9012284 Supporting Info

Recognition of Li+ by a Salophen−UO2 Homodimeric Complex Massimo Cametti, Laura Ilander and Kari Rissanen pp 8632–8637 DOI: 10.1021/ic901136b Supporting Info

Platinum(II) and Palladium(II) Complexes of Chiral P−Cl Functionalized Bis-phosphino ortho-Carbaboranes Ilham Maulana, Peter Lnnecke and Evamarie Hey-Hawkins pp 8638–8645 DOI: 10.1021/ic9011907

Correction to Visible Light-Driven Hydrogen Production from Aqueous Protons Catalyzed by Molecular Cobaloxime Catalysts Pingwu Du, Jacob Schneider, Genggeng Luo, William W. Brennessel and Richard Eisenberg p 8646 DOI: 10.1021/ic9015228

Issue 18

Monometallic Lanthanoid Assembly Showing Ferromagnetism with a Curie Temperature of 11 K Koji Nakabayashi and Shin-ichi Ohkoshi pp 8647–8649 DOI: 10.1021/ic900625a Supporting Info

An Unprecedentedly Huge Square-Grid Copper(II)−Organic Framework Material Built from a Bulky Pyrene-Derived Elongated Cross-Shaped Scaffold Chen-Chuan Tsai, Tzuoo-Tsair Luo, Jen-Fu Yin, Hong-Cheu Lin and Kuang-Lieh Lu pp 8650–8652 DOI: 10.1021/ic900786b Supporting Info

A 12-Connected Dodecanuclear Copper Cluster with Yellow Luminescence Xi Liu and Kun-Lin Huang pp 8653–8655 DOI: 10.1021/ic900611u Supporting Info

Strong Hydrogen Binding within a 3D Microporous Metal−Organic Framework Di-Chang Zhong, Jian-Bin Lin, Wen-Guan Lu, Long Jiang and Tong-Bu Lu pp 8656–8658 DOI: 10.1021/ic900968d Supporting Info

Assembly of a 1D Coordination Polymer through in Situ Formation of a New Ligand by Double C−C Coupling on CHCl3 under Solvothermal Conditions Guo-Bi Li, Jun-Min Liu, Zhi-Quan Yu, Wei Wang and Cheng-Yong Su pp 8659–8661 DOI: 10.1021/ic9011263 Supporting Info

Complementary Dynamic Assembly around an Iron(III) Cation Galina Melman, Pavan Vimal and Artem Melman pp 8662–8664 DOI: 10.1021/ic901151n Supporting Info

Activation of Tellurium with Zintl Ions: 1/∞{[Ge5Te10]4−}, An Inorganic Polymer with Germanium in Three Different Oxidation States Qichun Zhang, Gerasimos Armatas and Mercouri G. Kanatzidis pp 8665–8667 DOI: 10.1021/ic901282g Supporting Info

Copolymerization of Epoxides and Carbon Dioxide. Evidence Supporting the Lack of Dual Catalysis at a Single Metal Site Donald J. Darensbourg and Shawn B. Fitch pp 8668–8677 DOI: 10.1021/ic900780a Supporting Info

Different Routes for Amination of Platinum(II)-Bound Cyanoguanidine Alexander G. Tskhovrebov, Nadezhda A. Bokach, Matti Haukka and Vadim Yu. Kukushkin pp 8678–8688 DOI: 10.1021/ic900263e Supporting Info

One-Step Synthesis of White-Light-Emitting Quantum Dots at Low Temperature Chien-Chih Shen and Wei-Lung Tseng pp 8689–8694 DOI: 10.1021/ic9006422 Supporting Info

Metal-Assisted Oxazolidine/Oxazine Ring Formation in Dinuclear Zinc(II) Complexes: Synthesis, Structural Aspects, and Bioactivity Arpita Banerjee, Subhalakshmi Ganguly, Tanmay Chattopadhyay, Kazi Sabnam Banu, Amarendra Patra, Santanu Bhattacharya, Ennio Zangrando and Debasis Das pp 8695–8702 DOI: 10.1021/ic900643h Supporting Info

Glycine-Templated Manganese Sulfate with New Topology and Canted Antiferromagnetism Zhehui Weng, Zilu Chen and Fupei Liang pp 8703–8708 DOI: 10.1021/ic9006444 Supporting Info

91Zr Nuclear Magnetic Resonance Spectroscopy of Solid Zirconium Halides at High Magnetic Field O. Pauvert, F. Fayon, A. Rakhmatullin, S. Krmer, M. Horvati, D. Avignant, C. Berthier, M. Deschamps, D. Massiot and C. Bessada pp 8709–8717 DOI: 10.1021/ic9007119 Supporting Info

Grafting Reaction of Organotin Complexes on Silica Catalyzed by Tungstic Heteropolyacids Nicolas Legagneux, Aimery de Mallmann, Eva Grinenval, Jean-Marie Basset and Frdric Lefebvre pp 8718–8722 DOI: 10.1021/ic9006586

Infrared spectroscopic observation of the radical •XeF3 generated in solid argon Eugenii Ya. Misochko, Alexander V. Akimov, Vasilii A. Belov and Daniil A. Tyurin pp 8723–8728 DOI: 10.1021/ic9007312

Pathways of Water Oxidation Catalyzed by Ruthenium “Blue Dimers” Characterized by 18O-Isotopic Labeling Jonathan L. Cape, William F. Siems and James K. Hurst pp 8729–8735 DOI: 10.1021/ic900826q Supporting Info

Variable Coordination Behavior of New Hybrid Pyrazole Ligand: Synthesis and Characterization of Several ZnII, CdII, HgII, PdII, PtII, and NiII Complexes Miguel Guerrero, Josefina Pons, Teodor Parella, Merc Font-Bardia, Teresa Calvet and Josep Ros pp 8736–8750 DOI: 10.1021/ic900908n Supporting Info

Crystallography of Chevrel Phases, MMo6T8 (M = Cd, Na, Mn, and Zn, T = S, Se) and Their Cation Mobility E. Levi, G. Gershinsky, D. Aurbach and O. Isnard pp 8751–8758 DOI: 10.1021/ic900805g Supporting Info

Luminescence and Time-Resolved Infrared Study of Dyads Containing (Diimine)Ru(4,4′-diethylamido-2,2′-bipyridine)2 and (Diimine)Ru(CN)4 Moieties: Solvent-Induced Reversal of the Direction of Photoinduced Energy-Transfer Timothy L. Easun, Wassim Z. Alsindi, Nina Deppermann, Michael Towrie, Kate L. Ronayne, Xue-Zhong Sun, Michael D. Ward and Michael W. George pp 8759–8770 DOI: 10.1021/ic900924w Supporting Info

Iron(III) Complexes of Tripodal Monophenolate Ligands as Models for Non-Heme Catechol Dioxygenase Enzymes: Correlation of Dioxygenase Activity with Ligand Stereoelectronic Properties Ramasamy Mayilmurugan, Kusalendiran Visvaganesan, Eringathodi Suresh and Mallayan Palaniandavar pp 8771–8783 DOI: 10.1021/ic900969n Supporting Info

Structures and Spin States of Bis(tridentate)-Type Mononuclear and Triple Helicate Dinuclear Iron(II) Complexes of Imidazole-4-carbaldehyde azine Yukinari Sunatsuki, Ryohei Kawamoto, Kunihiro Fujita, Hisashi Maruyama, Takayoshi Suzuki, Hiroyuki Ishida, Masaaki Kojima, Seiichiro Iijima and Naohide Matsumoto pp 8784–8795 DOI: 10.1021/ic900977m Supporting Info

Heterometallic Aggregates of Copper(I) with Metalloligand Sn(edt)2 (edt = ethane-1,2-dithiolate): Syntheses and Structures of [Sn(edt)2Cl(μ-I)(μ3-I)(CuPPh3)3], [Sn(edt)2(μ-Br)2(μ3-Br)2(CuPPh3)4], and [{Sn(edt)2}3(μ-OH)3Cu5(PPh3)8][PF6]2 Yan-Gong Han, Chao Xu, Taike Duan, Fang-Hui Wu, Qian-Feng Zhang and Wa-Hung Leung pp 8796–8802 DOI: 10.1021/ic9009515 Supporting Info

Complex Formation and Molecular Structure of Neptunyl(VI) and -(V) Acetates Koichiro Takao, Shinobu Takao, Andreas C. Scheinost, Gert Bernhard and Christoph Hennig pp 8803–8810 DOI: 10.1021/ic900981q Supporting Info

Lewis Acidities and Hydride, Fluoride, and X− Affinities of the BH3−nXn Compounds for (X = F, Cl, Br, I, NH2, OH, and SH) from Coupled Cluster Theory Daniel J. Grant and David A. Dixon, Donald Camaioni and Robert G. Potter, Karl O. Christe pp 8811–8821 DOI: 10.1021/ic901092x Supporting Info

Magnetic Circular Dichroism Study of a Dicobalt(II) Complex with Mixed 5- and 6-Coordination: A Spectroscopic Model for Dicobalt(II) Hydrolases James A. Larrabee, W. Rainey Johnson and Adam S. Volwiler pp 8822–8829 DOI: 10.1021/ic901000d Supporting Info

Synthesis, Electronic Structure, and Structural Characterization of the New, “Non-Innocent” 4,5-Dithio-Catecholate Ligand, Its Metal Complexes, and Their Oxidized 4,5-Dithio-o-quinone Derivatives Dimitri Coucouvanis, Alok R. Paital, Qinwei Zhang, Nicolai Lehnert, Reinhart Ahlrichs, Karin Fink, Dieter Fenske, Annie K. Powell and Yanhua Lan pp 8830–8844 DOI: 10.1021/ic901002y Supporting Info

Mononuclear and Polynuclear Copper(II) Complexes Derived from Pyridylalkylaminomethylphenol Polypodal Ligands Jorge Manzur and Hector Mora, Andrs Vega, Diego Venegas-Yazigi, Miguel A. Novak, Jos Ricardo Sabino, Vernica Paredes-Garca, Evgenia Spodine pp 8845–8855 DOI: 10.1021/ic901026x Supporting Info

New Insights into Solvolysis and Reorganization Energy from Gas-Phase, Electrochemical, and Theoretical Studies of Oxo-Tp*MoV Molecules Aaron K. Vannucci, Rae Ana Snyder, Nadine E. Gruhn, Dennis L. Lichtenberger and John H. Enemark pp 8856–8862 DOI: 10.1021/ic9011058 Supporting Info

Alkali-Metal-Mediated Manganation(II) of Naphthalenes: Constructing Metalla-Anthracene and Metalla-Phenanthrene Structures Victoria L. Blair, William Clegg, Robert E. Mulvey and Luca Russo pp 8863–8870 DOI: 10.1021/ic901068w Supporting Info

Bioinorganic Magnetic Core−Shell Nanocomposites Carrying Antiarthritic Agents: Intercalation of Ibuprofen and Glucuronic Acid into Mg−Al−Layered Double Hydroxides Supported on Magnesium Ferrite Ahmet Nedim Ay, Birgl Zmreoglu-Karan, Abidin Temel and Vicente Rives pp 8871–8877 DOI: 10.1021/ic901097a

Stability, Water Exchange, and Anion Binding Studies on Lanthanide(III) Complexes with a Macrocyclic Ligand Based on 1,7-Diaza-12-crown-4: Extremely Fast Water Exchange on the Gd3+ Complex Zoltn Plinks, Adrin Roca-Sabio, Marta Mato-Iglesias, David Esteban-Gmez, Carlos Platas-Iglesias, Andrs de Blas, Teresa Rodrguez-Blas and va Tth pp 8878–8889 DOI: 10.1021/ic9011197 Supporting Info

Four New Lanthanide−Nitronyl Nitroxide (LnIII = PrIII, SmIII, EuIII, TmIII) Complexes and a TbIII Complex Exhibiting Single-Molecule Magnet Behavior Jin-Xia Xu, Yue Ma, Dai-zheng Liao, Gong-Feng Xu, Jinkui Tang, Chao Wang, Na Zhou, Shi-Ping Yan, Peng Cheng and Li-Cun Li pp 8890–8896 DOI: 10.1021/ic901169p Supporting Info

Construction of Metal−Organic Oxides from Molybdophosphonate Clusters and Copper-Bipyrimidine Building Blocks N. Gabriel Armatas, Wayne Ouellette, Kelly Whitenack, Joshua Pelcher, Hongxue Liu, Erin Romaine, Charles J. O’Connor and Jon Zubieta pp 8897–8910 DOI: 10.1021/ic901133k Supporting Info

Highly Organized Structures and Unusual Magnetic Properties of Paddlewheel Copper(II) Carboxylate Dimers Containing the π−π Stacking, 1,8-Naphthalimide Synthon Daniel L. Reger, Agota Debreczeni, Bryn Reinecke, Vitaly Rassolov and Mark D. Smith, Radu F. Semeniuc pp 8911–8924 DOI: 10.1021/ic901138h Supporting Info

Mixed (Phthalocyaninato)(Porphyrinato) Rare Earth Double-Decker Complexes with C4 Chirality: Synthesis, Resolution, and Absolute Configuration Assignment Yang Zhou, Yuexing Zhang, Hailong Wang, Jianzhuang Jiang, Yongzhong Bian, Atsuya Muranaka and Nagao Kobayashi pp 8925–8933 DOI: 10.1021/ic9011795 Supporting Info

Unsymmetrical Calixcrowns Incorporating Hard and Soft Loops as a New Scaffold for Multinuclear Endo/Exocyclic Complexation and Networking Jai Young Lee, So Young Lee, Sunhong Park, Jongchul Kwon, Wonbo Sim and Shim Sung Lee pp 8934–8939 DOI: 10.1021/ic901314b Supporting Info

Ligand-Mediated Interconversion of Multiply-Interpenetrating Frameworks in CuI/ReVII-Oxide Hybrids Haisheng Lin and Paul A. Maggard pp 8940–8946 DOI: 10.1021/ic900735n Supporting Info

Synthesis, Structure, and Characterization of Two Photoluminescent Zirconium Phosphate−Quinoline Compounds Lei Liu, Jinping Li, Jinxiang Dong, Dubravka iak, Christian Baerlocher and Lynne B. McCusker pp 8947–8954 DOI: 10.1021/ic901196f Supporting Info

Dimethylammonium Hexanoate Stabilized Rhodium(0) Nanoclusters Identified as True Heterogeneous Catalysts with the Highest Observed Activity in the Dehydrogenation of Dimethylamine−Borane Mehmet Zahmakiran and Saim zkar pp 8955–8964 DOI: 10.1021/ic9014306 Supporting Info

Synthesis and Reactivity of the 17 e− Complex [ReIIBr4(CO)2]2−: A Convenient Entry into Rhenium(II) Chemistry Fabio Zobi, Lukas Kromer, Bernhard Spingler and Roger Alberto pp 8965–8970 DOI: 10.1021/ic901031x Supporting Info

Carbon Dioxide Activation by “Non-nucleophilic” Lead Alkoxides Eric C. Y. Tam, Nick C. Johnstone, Lorenzo Ferro, Peter B. Hitchcock and J. Robin Fulton pp 8971–8976 DOI: 10.1021/ic900134f Supporting Info

Synthesis and Structure of an “Iron-Doped” Copper Selenide Cluster Molecule: [Cu30Fe2Se6(SePh)24(dppm)4] Andreas Eichhfer, Jolanta Olkowska-Oetzel, Dieter Fenske, Karin Fink, Valeriu Mereacre, Annie K. Powell and Gernot Buth pp 8977–8984 DOI: 10.1021/ic900890n

Cu2+ Coordination Properties of a 2-Pyridine Heptaamine Tripod: Characterization and Binding Mechanism Alejandra Sornosa Ten, Nicolas Humbert, Begoa Verdejo, Jos M. Llinares, Mourad Elhabiri, Julia Jezierska, Conxa Soriano, Henryk Kozlowski, Anne-Marie Albrecht-Gary and Enrique Garca-Espaa pp 8985–8997 DOI: 10.1021/ic9010955 Supporting Info

Synthesis and Linkage Isomerization of Thiolato-Bridged RuIIAgIRuII Trinuclear Complex with d-Penicillaminate Motoshi Tamura, Masakazu Yamagishi, Tatsuya Kawamoto, Asako Igashira-Kamiyama, Kiyoshi Tsuge and Takumi Konno pp 8998–9004 DOI: 10.1021/ic901181x Supporting Info

Building Blocks for Molecule-Based Magnets: Radical Anions and Dianions of Substituted 3,6-Dimethylenecyclohexane-1,2,4,5-tetrones as Paramagnetic Bridging Ligands Andrzej W. Misioek, Andrew S. Ichimura, Robert A. Gentner, Rui H. Huang, Vanessa P. McCaffrey and James E. Jackson pp 9005–9017 DOI: 10.1021/ic901390n Supporting Info

Persistent Radical Effect in Action: Kinetic Studies of Copper-Catalyzed Atom Transfer Radical Addition in the Presence of Free-Radical Diazo Initiators as Reducing Agents Marielle Nicole C. Balili and Tomislav Pintauer pp 9018–9026 DOI: 10.1021/ic901359a

Anionic Mixed Thiolate−Sulfide-Bridged Roussin’s Red Esters [(NO)2Fe(μ-SR)(μ-S)Fe(NO)2]− (R = Et, Me, Ph): A Key Intermediate for Transformation of Dinitrosyl Iron Complexes (DNICs) to [2Fe-2S] Clusters Tsai-Te Lu, Hsiao-Wen Huang and Wen-Feng Liaw pp 9027–9035 DOI: 10.1021/ic9012679 Supporting Info

Soft−Hard Acid−Base Interactions: Probing Coordination Preferences of Sulfur and Selenium in Mixed Chalcophosphates in the Family APbPS4−xSex (A = K, Rb, Cs; x = 0−4) Alexander Rothenberger, Collin Morris, Hsien-Hau Wang, Duck Young Chung and Mercouri G. Kanatzidis pp 9036–9040 DOI: 10.1021/ic901283k Supporting Info

Photochemical Mineralization of Europium, Titanium, and Iron Oxyhydroxide Nanoparticles in the Ferritin Protein Cage Michael T. Klem, Jesse Mosolf, Mark Young and Trevor Douglas p 9041 DOI: 10.1021/ic901346s Supporting Info

Correction to Heteronuclear and Homonuclear Cu2+ and Zn2+ Complexes with Multihistidine Peptides Based on Zebrafish Prion-like Protein Daniela Valensin, Łukasz Szyrwiel, Francesca Camponeschi, Magdalena Rowiska-yrek, Elena Molteni, Elzbieta Jankowska, Aneta Szymanska, Elena Gaggelli, Gianni Valensin and Henryk Kozłowski p 9042 DOI: 10.1021/ic9016678

Issue 19

Ligand-Based Reactivity of a Platinum Bisdithiolene: Double Diene Addition Yields a New C2-Chiral Chelate Ligand Mitchell J. Kerr, Daniel J. Harrison, Alan J. Lough and Ulrich Fekl pp 9043–9045 DOI: 10.1021/ic901116c Supporting Info

Synthesis and Crystal Structure of NZP-Type Thorium−Zirconium Phosphate Albina I. Orlova, Valeriy Yu. Volgutov, Germn R. Castro, Santiago Garca-Granda, Sergei A. Khainakov and Jos R. Garca pp 9046–9047 DOI: 10.1021/ic9013812 Supporting Info

Electroconductive Porous Coordination Polymer Cu[Cu(pdt)2] Composed of Donor and Acceptor Building Units Shinya Takaishi, Miyuki Hosoda, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Yasuyuki Nakanishi, Yasutaka Kitagawa, Kizashi Yamaguchi, Atsushi Kobayashi and Hiroshi Kitagawa pp 9048–9050 DOI: 10.1021/ic802117q Supporting Info

Effect of Magnetic Dipole−Dipole Interactions on the Spin Orientation and Magnetic Ordering of the Spin-Ladder Compound Sr3Fe2O5 Hyun-Joo Koo, Hongjun Xiang, Changhoon Lee and Myung-Hwan Whangbo pp 9051–9053 DOI: 10.1021/ic9007526 Supporting Info

Stoichiometric CeCuOS − A Well-Behaved Ce(III) Layered Oxysulfide Michael J. Pitcher, Catherine F. Smura and Simon J Clarke pp 9054–9056 DOI: 10.1021/ic9012262 Supporting Info

Rechargeable Batteries Driven by Redox Reactions of Mn12 Clusters with Structural Changes: XAFS Analyses of the Charging/Discharging Processes in Molecular Cluster Batteries Hirofumi Yoshikawa, Shun Hamanaka, Yasuhito Miyoshi, Yoshihiko Kondo, Satoru Shigematsu, Nao Akutagawa, Masaharu Sato, Toshihiko Yokoyama and Kunio Awaga pp 9057–9059 DOI: 10.1021/ic901288h Supporting Info

Metal−Organic Framework Assembled from T-Shaped and Octahedral Nodes: A Mixed-Linker Strategy To Create a Rare Anatase TiO2 Topology Jennifer M. Verduzco, Haemi Chung, Chunhua Hu and Wonyoung Choe pp 9060–9062 DOI: 10.1021/ic9009916 Supporting Info

Tripodal Tetrahedral Titanium Coordination in the Silica-Grafted Titania Epoxidation Catalysts: Is Not It Only a Myth? Selective Formation of [Cy7Si7O12Ti]2(μ-OR)2(μ-ROH) Cores on Thermal “Dissociation” of Alkoxytitanasilsesquioxanes Olle Viotti, Gulaim A. Seisenbaeva and Vadim G. Kessler pp 9063–9065 DOI: 10.1021/ic901503y Supporting Info

One-Dimensional Cyanide-Bridged MnIIIWV Bimetallic Complexes: Metamagnetism, Spontaneous Resolution, and Slow Magnetic Relaxation Seok Woo Choi, Dae Won Ryu, Jin Wuk Lee, Jung Hee Yoon, Hyoung Chan Kim, Hyosug Lee, Beong Ki Cho and Chang Seop Hong pp 9066–9068 DOI: 10.1021/ic901610j Supporting Info

Synthesis and Characterization of a Benzene−Dimolybdenum Complex with a New Bridging Mode Yuji Kajita, Takahiko Ogawa, Jun Matsumoto and Hideki Masuda pp 9069–9071 DOI: 10.1021/ic901360c Supporting Info

Template-Free Hydrothermal Synthesis and Photocatalytic Performances of Novel Bi2SiO5 Nanosheets Ruigen Chen, Jinhong Bi, Ling Wu, Wanjun Wang, Zhaohui Li and Xianzhi Fu pp 9072–9076 DOI: 10.1021/ic901084s

Multifunctional DNA Interactions of Ru−Pt Mixed Metal Supramolecular Complexes with Substituted Terpyridine Ligands Avijita Jain, Jing Wang, Emily R. Mashack, Brenda S. J. Winkel and Karen J. Brewer pp 9077–9084 DOI: 10.1021/ic900190a

Synthesis Temperature Effect on the Structural Features and Optical Absorption of Zn1−xCoxAl2O4 Oxides M. Gaudon, A. Apheceixborde, M. Mntrier, A. Le Nestour and A. Demourgues pp 9085–9091 DOI: 10.1021/ic900482v

Combined Low Temperature Rapid Scan and 1H NMR Mechanistic Study of the Protonation and Subsequent Benzene Elimination from a (Diimine)platinum(II) Diphenyl Complex Relevant to Arene C−H Activation Jerome Parmene, Ivana Ivanovi-Burmazovi, Mats Tilset and Rudi van Eldik pp 9092–9103 DOI: 10.1021/ic9005746 Supporting Info

Syntheses, Structures, and Photochemistry of Manganese Nitrosyls Derived from Designed Schiff Base Ligands: Potential NO Donors That Can Be Activated by Near-Infrared Light C. Gianna Hoffman-Luca, Aura A. Eroy-Reveles, Jose Alvarenga and Pradip K. Mascharak pp 9104–9111 DOI: 10.1021/ic900604j Supporting Info

Boron Containing Two-Photon Absorbing Chromophores. 2. Fine Tuning of the One- and Two-Photon Photophysical Properties of Pyrazabole Based Fluorescent Bioprobes Ali Hayek, Frdric Bolze, Cyril Bourgogne, Patrice L. Baldeck, Pascal Didier, Youri Arntz, Yves Mly and Jean-Franois Nicoud pp 9112–9119 DOI: 10.1021/ic900627g

Mixed-Ligand Copper(II) Maltolate Complexes: Synthesis, Characterization, DNA Binding and Cleavage, and Cytotoxicity Archika Barve, Avinash Kumbhar, Menakshi Bhat, Bimba Joshi, Ray Butcher, Uddhavesh Sonawane and Rajendra Joshi pp 9120–9132 DOI: 10.1021/ic9004642 Supporting Info

Syntheses, Structures, and Fluorescent Properties of 2-(1H-Imidazol-2-yl)phenols and Their Neutral Zn(II) Complexes Abiodun Omokehinde Eseola, Wen Li, Rong Gao, Min Zhang, Xiang Hao, Tongling Liang, Nelson Okpako Obi-Egbedi and Wen-Hua Sun pp 9133–9146 DOI: 10.1021/ic9008703 Supporting Info

Investigation of the New P′3-Na0.60VO2 Phase: Structural and Physical Properties Olivier Szajwaj, Etienne Gaudin, Franois Weill, Jacques Darriet and Claude Delmas pp 9147–9154 DOI: 10.1021/ic9008653

Density Functional Theory Calculations on Mssbauer Parameters of Nonheme Iron Nitrosyls Kathrin H. Hopmann, Abhik Ghosh and Louis Noodleman pp 9155–9165 DOI: 10.1021/ic9008784 Supporting Info

Heterometallic Complexes Based on the Mixed Bridging Ligands of Tricyanometalate and Terephthalate: Syntheses, Structures, and Magnetic Properties Xiao-Ming Li, Cai-Feng Wang, Yong Ji, Ling-Chen Kang, Xin-Hui Zhou, Jing-Lin Zuo and Xiao-Zeng You pp 9166–9173 DOI: 10.1021/ic900757s Supporting Info

Synthesis and Structural Characterization of Aluminum Iminophosphonamide Complexes Bijan Nekoueishahraki, Herbert W. Roesky, Gerald Schwab, Daniel Stern and Dietmar Stalke pp 9174–9179 DOI: 10.1021/ic9011179 Supporting Info

Morphology-Controlled Synthesis of Barium Titanate Nanostructures Kuan-Chih Huang, Tung-Ching Huang and Wen-Feng Hsieh pp 9180–9184 DOI: 10.1021/ic900854x

Synthesis and Structural Examination of Complexes of Am(IV) and Other Tetravalent Actinides with Lacunary Heteropolyanion α2-P2W17O6110− Marina N. Sokolova, Alexander M. Fedosseev, Grigory B. Andreev, Nina A. Budantseva, Alexander B. Yusov and Philippe Moisy pp 9185–9190 DOI: 10.1021/ic900710c Supporting Info

Homo- and Heterometallic Complexes of Tetra-(Di-Substituted Hydroxybenzyl)-N,N′-Ethylenediamine Derivatives Timothy J. Boyle, Harry D. Pratt, III, Leigh Anna M. Ottley, Todd M. Alam, Sarah K. McIntyre and Mark A. Rodriguez, Joshua Farrell, Charles F. Campana pp 9191–9204 DOI: 10.1021/ic900691a Supporting Info

Spin-Canting and Metamagnetic Behavior in a New Species from the Hydrothermal Co(II)-trans-3-Pyridylacrylate System Kartik Chandra Mondal, George E. Kostakis, Yanhua Lan, Christopher E. Anson and Annie K. Powell pp 9205–9213 DOI: 10.1021/ic900886y Supporting Info

Ligand Reactivity in Diarylamido/Bis(Phosphine) PNP Complexes of Mn(CO)3 and Re(CO)3 Alexander T. Radosevich, Jonathan G. Melnick, Sebastian A. Stoian, Deborha Bacciu, Chun-Hsing Chen, Bruce M. Foxman, Oleg V. Ozerov and Daniel G. Nocera pp 9214–9221 DOI: 10.1021/ic9010218 Supporting Info

From 0D dimer to 2D Network—Supramolecular Assembly of Organic Derivatized Polyoxometalates with Remote Hydroxyl via Hydrogen Bonding Longsheng Wang, Li Zhu, Panchao Yin, Weiwei Fu, Jiake Chen, Jian Hao, Fengping Xiao, Chunlin Lv, Jin Zhang, Lu Shi, Qiang Li and Yongge Wei pp 9222–9235 DOI: 10.1021/ic900985w Supporting Info

Synthesis and Coordination Properties of Quinoline Pendant Arm Derivatives of [9]aneN3 and [9]aneN2S as Fluorescent Zinc Sensors Marta Mameli, M. Carla Aragoni, Massimiliano Arca, Marta Atzori, Andrea Bencini, Carla Bazzicalupi, Alexander J. Blake, Claudia Caltagirone, Francesco A. Devillanova, Alessandra Garau, Michael B. Hursthouse, Francesco Isaia, Vito Lippolis and Barbara Valtancoli pp 9236–9249 DOI: 10.1021/ic901012w Supporting Info

Investigation in the Binary System Yb−Ga: Crystal Structure of the Ga-Rich Compound YbGa3.34 Monique Tillard and Claude Belin pp 9250–9257 DOI: 10.1021/ic901059q Supporting Info

Electrochemically-Induced TCNQ/Mn[TCNQ]2(H2O)2 (TCNQ = 7,7,8,8-Tetracyanoquinodimethane) Solid−Solid Interconversion: Two Voltammetrically Distinct Processes That Allow Selective Generation of Nanofiber or Nanorod Network Morphologies Ayman Nafady, Alan M. Bond and Anthony P. O’Mullane pp 9258–9270 DOI: 10.1021/ic9011394 Supporting Info

Complex Superstructures of Mo2P4O15 Sarah E. Lister, Ivana Radosavljevi Evans and John S. O. Evans pp 9271–9281 DOI: 10.1021/ic901090p Supporting Info

Low-Temperature N−O Bond Cleavage in Nitrosyl Ligands Induced by the Unsaturated Dimolybdenum Anion [Mo2(η5-C5H5)2(μ-PPh2)(μ-CO)2]− M. Esther Garca, Daniel Garca-Viv, Sonia Meln, Miguel A. Ruiz, Claudia Graiff and Antonio Tiripicchio pp 9282–9293 DOI: 10.1021/ic901120x Supporting Info

Sodium and Potassium Ion Directed Self-Assembled Multinuclear Assembly of Divalent Nickel or Copper and l-Leucine Derived Ligand Mrigendra Dubey, Rik Rani Koner and Manabendra Ray pp 9294–9302 DOI: 10.1021/ic9011444 Supporting Info

Identification of the Minimal Copper(II)-Binding α-Synuclein Sequence Mark S. Jackson and Jennifer C. Lee pp 9303–9307 DOI: 10.1021/ic901157w Supporting Info

Structures and Reactivity Patterns of Group 9 Metallocorroles Joshua H. Palmer, Atif Mahammed, Kyle M. Lancaster, Zeev Gross and Harry B. Gray pp 9308–9315 DOI: 10.1021/ic901164r Supporting Info

Aryl Bridged 1-Hydroxypyridin-2-one: Effect of the Bridge on the Eu(III) Sensitization Process Anthony D’Alo, Evan G. Moore, Gza Szigethy, Jide Xu and Kenneth N. Raymond pp 9316–9324 DOI: 10.1021/ic901161z Supporting Info

Mn4, Mn6, and Mn11 Clusters from the Use of Bulky Diphenyl(pyridine-2-yl)methanol Taketo Taguchi, Matthew R. Daniels, Khalil A. Abboud and George Christou pp 9325–9335 DOI: 10.1021/ic901306k Supporting Info

The Crystal Structure of α-K3AlF6: Elpasolites and Double Perovskites with Broken Corner-Sharing Connectivity of the Octahedral Framework Artem M. Abakumov, Graham King, Veronika K. Laurinavichute, Marina G. Rozova, Patrick M. Woodward and Evgeny V. Antipov pp 9336–9344 DOI: 10.1021/ic9013043 Supporting Info

Magnetic and 57Fe Mssbauer Study of the Single Molecule Magnet Behavior of a Dy3Fe7 Coordination Cluster Ghulam Abbas, Yanhua Lan, Valeriu Mereacre, Wolfgang Wernsdorfer, Rodolphe Clrac, Gernot Buth, Moulay T. Sougrati, Fernande Grandjean, Gary J. Long, Christopher E. Anson and Annie K. Powell pp 9345–9355 DOI: 10.1021/ic901248r Supporting Info

Synthesis, Structural Characterization, and Biological Evaluation of Oxorhenium(V) Complexes with a Novel Type of Thiosemicarbazones Derived from N-[N′,N′-Dialkylamino(thiocarbonyl)]benzimidoyl Chlorides Hung Huy Nguyen, Jesudas J. Jegathesh, Pedro I. da S. Maia, Victor M. Deflon, Ronald Gust, Silke Bergemann and Ulrich Abram pp 9356–9364 DOI: 10.1021/ic901160v Supporting Info

Structural and NMR Characterization of Sm(III), Eu(III), and Yb(III) Complexes of an Amide Based Polydentate Ligand Exhibiting Paramagnetic Chemical Exchange Saturation Transfer Abilities Jason D. Dorweiler, Victor N. Nemykin, Amanda N. Ley, Robert D. Pike and Steven M. Berry pp 9365–9376 DOI: 10.1021/ic901191a Supporting Info

Toward Unidirectional Rotary Motion in Nickelacarboranes: Characterization of Diastereomeric Nickel Bis(Dicarbollide) Complexes Derived from the [Nido-7-CH3-7,8-C2B9H11]− Anion Robert D. Kennedy, Carolyn B. Knobler and M. Frederick Hawthorne pp 9377–9384 DOI: 10.1021/ic901175e Supporting Info

Single-Electron Transfer in Palladium Complexes of 1,4-Naphthoquinone-Containing Bis(pyrazol-1-yl)methane Ligands Sebastian Scheuermann, Biprajit Sarkar, Michael Bolte, Jan W. Bats, Hans-Wolfram Lerner and Matthias Wagner pp 9385–9392 DOI: 10.1021/ic9013015 Supporting Info

Structural, Magnetic, and Mssbauer Spectral Study of the Electronic Spin-State Transition in [Fe{HC(3-Mepz)2(5-Mepz)}2](BF4)2 Daniel L. Reger, J. Derek Elgin, Elizabeth A. Foley, Mark D. Smith, Fernande Grandjean and Gary J. Long pp 9393–9401 DOI: 10.1021/ic901259e Supporting Info

Chromium Acetylide Complex Based Ferrimagnet and Weak Ferromagnet Junichi Nishijo, Ken Judai, Shigenori Numao and Nobuyuki Nishi pp 9402–9408 DOI: 10.1021/ic901295d Supporting Info

Syntheses, Structures, and Magnetic Properties of Nickel-Doped Lepidocrocite Titanates Tao Gao, Poul Norby, Hiroshi Okamoto and Helmer Fjellvg pp 9409–9418 DOI: 10.1021/ic901251w Supporting Info

A New Tripodal Ligand System with Steric and Electronic Modularity for Uranium Coordination Chemistry Suzanne C. Bart, Frank W. Heinemann, Christian Anthon, Christina Hauser and Karsten Meyer pp 9419–9426 DOI: 10.1021/ic9012697 Supporting Info

Synthesis, Structural Characterization, and Quadruplex DNA Binding Studies of Platinum(II)-Terpyridine Complexes Kogularamanan Suntharalingam, Andrew J. P. White and Ramon Vilar pp 9427–9435 DOI: 10.1021/ic901319n Supporting Info

Nitrogen-Atom Transfer from [PW11O39RuVIN]4− to PPh3 Claire Besson, Yurii V. Geletii, Franoise Villain, Richard Villanneau, Craig L. Hill and Anna Proust pp 9436–9443 DOI: 10.1021/ic901345u

Ruthenium(II) Arene Anticancer Complexes with Redox-Active Diamine Ligands Tijana Bugarcic, Abraha Habtemariam, Robert J. Deeth, Francesca P. A. Fabbiani, Simon Parsons and Peter J. Sadler pp 9444–9453 DOI: 10.1021/ic9013366 Supporting Info

Electrochemical and Chemical Reduction of Disulfur Dinitride: Formation of [S4N4]−•, EPR Spectroscopic Characterization of the [S2N2H]• Radical, and X-ray Structure of [Na(15-crown-5)][S3N3] Tracey L. Roemmele, Jari Konu, Ren T. Boer and Tristram Chivers pp 9454–9462 DOI: 10.1021/ic9014114 Supporting Info

Phosphine- and Carbene-Ligated Silver Acetate: Easily-Accessed Synthons for Reactions with Silylated Nucleophiles David V. Partyka and Nihal Deligonul pp 9463–9475 DOI: 10.1021/ic901371g Supporting Info

Trinuclear C3-Symmetric Extension of Jacobsen’s Catalyst: Synthesis, Characterization, and Catalytic Properties of a Chiral Trinuclear MnIII Triplesalen Complex Chandan Mukherjee, Anja Stammler, Hartmut Bgge and Thorsten Glaser pp 9476–9484 DOI: 10.1021/ic901325y Supporting Info

Bioreduction of U(VI)−Phthalate to a Polymeric U(IV)−Phthalate Colloid Gustavo J. Vazquez, Cleveland J. Dodge and Arokiasamy J. Francis pp 9485–9490 DOI: 10.1021/ic900694k

Synthesis and Structural Analysis of Titanatranes Bearing Terminal Substituted Aryloxo Ligands of the type [Ti(OAr){(O-2,4-Me2C6H2-6-CH2)2(OCH2CH2)N}]n (n = 1, 2): Effect of Aryloxo Substituents in the Ethylene Polymerization Prabhuodeyara M. Gurubasavaraj and Kotohiro Nomura pp 9491–9500 DOI: 10.1021/ic9008398 Supporting Info

Photocytotoxic 3d-Metal Scorpionates with a 1,8-Naphthalimide Chromophore Showing Photoinduced DNA and Protein Cleavage Activity Sovan Roy, Sounik Saha, Ritankar Majumdar, Rajan R. Dighe and Akhil R. Chakravarty pp 9501–9509 DOI: 10.1021/ic9015355 Supporting Info

New Zinc Complexes bearing κ2-Heteroscorpionate Ligands: Influence of Second-Sphere Bonding Interactions on Reactivity and Properties Stefano Milione, Carmine Capacchione, Cinzia Cuomo, Maria Strianese, Valerio Bertolasi and Alfonso Grassi pp 9510–9518 DOI: 10.1021/ic901091e Supporting Info

Rhenium−Bismuth Carbonyl Cluster Compounds Richard D. Adams and William C. Pearl, Jr. pp 9519–9525 DOI: 10.1021/ic901176x Supporting Info

Synthesis, Synchrotron X-ray Diffraction, and Kinetic Studies on the Formation of a Novel Thiolatocobalamin of Captopril: Evidence for cis-trans Isomerization in the β-Axial Ligand. Riya Mukherjee, Andrew McCaddon, Clyde A. Smith and Nicola E. Brasch pp 9526–9534 DOI: 10.1021/ic900891y Supporting Info

Di- and Tri-Zinc Catalysts for the Low-Pressure Copolymerization of CO2 and Cyclohexene Oxide Michael R. Kember, Andrew J. P. White and Charlotte K. Williams pp 9535–9542 DOI: 10.1021/ic901109e Supporting Info

Hydrostannylation of Ketones and Alkynes with LSnH [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3] Anukul Jana, Herbert W. Roesky and Carola Schulzke pp 9543–9548 DOI: 10.1021/ic9012069 Supporting Info

Tetrazole-5-carboxylic Acid Based Salts of Earth Alkali and Transition Metal Cations Vera Hartdegen, Thomas M. Klaptke and Stefan M. Sproll pp 9549–9556 DOI: 10.1021/ic901413n Supporting Info

Sequential Construction of One, Two, or Three Dithiolene Ligands from Alkynes and Sulfur in Dinuclear Cyclopentadienyl Molybdenum Complexes Harry Adams, Matthew N. Bancroft, Michael J. Morris and Andrea E. Riddiough pp 9557–9566 DOI: 10.1021/ic901243m Supporting Info

Design and Synthesis of a Stable Supramolecular Trigonal Prism Formed by the Self-Assembly of a Linear Tetrakis(Zn2+−cyclen) Complex and Trianionic Trithiocyanuric Acid in Aqueous Solution and Its Complexation with DNA (Cyclen = 1,4,7,10-Tetraazacyclododecane) Mohd Zulkefeli, Tetsuya Sogon, Kei Takeda, Eiichi Kimura and Shin Aoki pp 9567–9578 DOI: 10.1021/ic901407d Supporting Info

Relative Binding Affinity of Thiolate, Imidazolate, Phenoxide, and Nitrite Toward the {Fe(NO)2} Motif of Dinitrosyl Iron Complexes (DNICs): The Characteristic Pre-Edge Energy of {Fe(NO)2}9 DNICs Ming-Che Tsai, Fu-Te Tsai, Tsai-Te Lu, Ming-Li Tsai, Yin-Ching Wei, I-Jui Hsu, Jyh-Fu Lee and Wen-Feng Liaw pp 9579–9591 DOI: 10.1021/ic901675p Supporting Info

Issue 20

A Fluorogenic, Nucleic Acid Directed “Click” Reaction Elmar Jentzsch and Andriy Mokhir pp 9593–9595 DOI: 10.1021/ic9006795 Supporting Info

Effects of Clioquinol on Metal-Triggered Amyloid-β Aggregation Revisited Allana M. Mancino, Sarmad S. Hindo, Akiko Kochi and Mi Hee Lim pp 9596–9598 DOI: 10.1021/ic9014256 Supporting Info

A Terminal Molybdenum Arsenide Complex Synthesized from Yellow Arsenic John J. Curley, Nicholas A. Piro and Christopher C. Cummins pp 9599–9601 DOI: 10.1021/ic9016068 Supporting Info

X-ray Absorption Fine Structures of Uranyl(V) Complexes in a Nonaqueous Solution Koichiro Takao, Satoru Tsushima, Shinobu Takao, Andreas C. Scheinost, Gert Bernhard, Yasuhisa Ikeda and Christoph Hennig pp 9602–9604 DOI: 10.1021/ic901487r Supporting Info

β-Agostic Silylamido and Silyl-Hydrido Compounds of Molybdenum and Tungsten Stanislav K. Ignatov, Andrey Y. Khalimon, Nicholas H. Rees, Alexei G. Razuvaev, Philip Mountford and Georgii I. Nikonov pp 9605–9622 DOI: 10.1021/ic900591e Supporting Info

Observation of Magnetic Bistability in Polymorphs of the [Ni(dmit)2]− Complexes Shuangquan Zang, Xiaoming Ren, Yang Su, You Song, Wenjun Tong, Zhaoping Ni, Hanhua Zhao, Song Gao and Qingjin Meng pp 9623–9630 DOI: 10.1021/ic900090e Supporting Info

On the Viability of Cyclometalated Ru(II) Complexes for Light-Harvesting Applications Paolo G. Bomben, Kiyoshi C. D. Robson, Pavel A. Sedach and Curtis P. Berlinguette pp 9631–9643 DOI: 10.1021/ic900653q Supporting Info

Systematic Manipulation of the Light-Harvesting Properties for Tridentate Cyclometalated Ruthenium(II) Complexes Bryan D. Koivisto, Kiyoshi C. D. Robson and Curtis P. Berlinguette pp 9644–9652 DOI: 10.1021/ic9007137 Supporting Info

Platinum(II) Terpyridyl Acetylide Complexes on Platinized TiO2: Toward the Photogeneration of H2 in Aqueous Media Paul Jarosz, Pingwu Du, Jacob Schneider, Soo-Hyun Lee, David McCamant and Richard Eisenberg pp 9653–9663 DOI: 10.1021/ic9001913 Supporting Info

Synthesis and Characterization of Luminescent Rhenium(I) Tricarbonyl Diimine Complexes with a Triarylboron Moiety and the Study of Their Fluoride Ion-Binding Properties Siu-Tung Lam, Nianyong Zhu and Vivian Wing-Wah Yam pp 9664–9670 DOI: 10.1021/ic900803a Supporting Info

Structure and Properties of Alkali Cobalt Double Oxides A0.6CoO2 (A = Li, Na, and K) Michal Pollet, Maxime Blangero, Jean-Pierre Doumerc, Rodolphe Decourt, Dany Carlier, Catherine Denage and Claude Delmas pp 9671–9683 DOI: 10.1021/ic900386q

Photooxidation of a Platinum-Anthracene Pincer Complex: Formation and Structures of PtII-Anthrone and -Ketal Complexes Jian Hu, Huan Xu, Minh-Hai Nguyen and John H. K. Yip pp 9684–9692 DOI: 10.1021/ic900479w Supporting Info

Multiphase Transformations Controlled by Ostwald’s Rule in Nanostructured Ce0.5Zr0.5O2 Powders Prepared by a Modified Pechini Route Alejandro Vrez, Julian Jolly, Patricia Oliete, Maria Luisa Sanjun, Ester Garca-Gonzalez, Teresa Jardiel and Jess Sanz pp 9693–9699 DOI: 10.1021/ic900837r

Solvation Effects on Isomeric Preferences of Curium(III) Complexes with Multidentate phosphonopropionic Acid Ligands: CmH2PPA2+ and CmHPPA+ Complexes Zhiji Cao, K. Balasubramanian, Michael G. Calvert and Heino Nitsche pp 9700–9714 DOI: 10.1021/ic901054h

Structure Determination of Two Modulated γ-Brass Structures in the Zn−Pd System through a (3 + 1)-Dimensional Space Description Olivier Gourdon, Zunbeltz Izaola, Luis Elcoro, Vaclav Petricek and Gordon J. Miller pp 9715–9722 DOI: 10.1021/ic900830y Supporting Info

Design and Synthesis of Highly Luminescent Near-Infrared-Emitting Water-Soluble CdTe/CdSe/ZnS Core/Shell/Shell Quantum Dots Wenjin Zhang, Guanjiao Chen, Jian Wang, Bang-Ce Ye and Xinhua Zhong pp 9723–9731 DOI: 10.1021/ic9010949

Synthesis of Anatase TiO2 Nanoshuttles by Self-Sacrificing of Titanate Nanowires Hongkang Wang, Wei Shao, Feng Gu, Ling Zhang, Mengkai Lu and Chunzhong Li pp 9732–9736 DOI: 10.1021/ic901235n Supporting Info

Structural Phase Transformations of Mg3N2 at High Pressure: Experimental and Theoretical Studies Jian Hao, Yinwei Li, Qiang Zhou, Dan liu, Min Li, Fangfei Li, Weiwei Lei, Xiaohui Chen, Yanming Ma, Qiliang Cui, Guangtian Zou, Jing Liu and Xiaodong Li pp 9737–9741 DOI: 10.1021/ic901324n

Electronic Properties of a Cytosine Decavanadate: Toward a Better Understanding of Chemical and Biological Properties of Decavanadates Nada Bonjakovi-Pavlovi, Anne Spasojevi-de Bir, Isabel Tomaz, Nouzha Bouhmaida, Fernando Avecilla, Ubavka B. Mio, Joo Costa Pessoa and Nour Eddine Ghermani pp 9742–9753 DOI: 10.1021/ic9008575 Supporting Info

Electronic Structures of [RuII(cyclam)(Et2dtc)]+, [Ru(cyclam)(tdt)]+, and [Ru(cyclam)(tdt)]2+: An X-ray Absorption Spectroscopic and Computational Study (tdt = toluene-3,4-dithiolate; Et2dtc = N,N-diethyldithiocarbamate(1-)) Carsten Milsmann, Eckhard Bill, Thomas Weyhermller, Serena DeBeer George and Karl Wieghardt pp 9754–9766 DOI: 10.1021/ic9011845 Supporting Info

Reactions of the Unsaturated Complex [Mo2(η5-C5H5)2(μ-PEt2)2(CO)2] with [Au(PR3)]+ Cations: Kinetic Preference of the Mo−P Bonds as the Site of Attack of the Gold(I) Electrophile M. Angeles Alvarez, M. Esther Garca, Daniel Garca-Viv, M. Eugenia Martnez and Miguel A. Ruiz pp 9767–9778 DOI: 10.1021/ic901340w Supporting Info

Synthesis, Structures, Spectroscopic and Electrochemical Properties of Dinitrosyl Iron Complexes with Bipyridine, Terpyridine, and 1,10-Phenathroline Rongming Wang, Ximeng Wang, Eric B. Sundberg, Phuongmei Nguyen, Gian Paola G. Grant, Chaitali Sheth, Qiang Zhao, Steve Herron, Katherine A. Kantardjieff and Lijuan Li pp 9779–9785 DOI: 10.1021/ic901368t Supporting Info

Reaction of a 14-Vertex Carborane with Nucleophiles: Formation of nido-C2B12, nido-C2B11, and closo-CB11 Carborane Anions Jian Zhang, Fangrui Zheng, Hoi-Shan Chan and Zuowei Xie pp 9786–9791 DOI: 10.1021/ic901335w Supporting Info

Electronic Structure of the A8Tr11 (A = K, Rb, Cs; Tr = Ga, In, Tl) Zintl Phases: Possible Chemical Reasons Behind Their Activated versus Non Activated Conductivity Manuel Cobin, Pere Alemany, Alberto Garca and Enric Canadell pp 9792–9799 DOI: 10.1021/ic9013637 Supporting Info

Sensitive Valence Structures of [(pap)2Ru(Q)]n (n = +2, +1, 0, −1, −2) with Two Different Redox Noninnocent Ligands, Q = 3,5-Di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine and pap = 2-Phenylazopyridine Dipanwita Das, Tapan Kumar Mondal, Shaikh M. Mobin and Goutam Kumar Lahiri pp 9800–9810 DOI: 10.1021/ic901343j Supporting Info

Proton NMR Study of Cr−Co Heterometallic Wheel Complexes E. Carolina Saudo, Thomas B. Faust, Christopher A. Muryn, Robin G. Pritchard, Grigore A. Timco and Richard E. P. Winpenny pp 9811–9818 DOI: 10.1021/ic901418z Supporting Info

Rare Sandwich-Type Polyoxomolybdates Constructed from Di-/Tetra-Nuclear Transition-Metal Clusters and Trivacant Keggin Germanomolybdate Fragments Suzhi Li, Junwei Zhao, Pengtao Ma, Juan Du, Jingyang Niu and Jingping Wang pp 9819–9830 DOI: 10.1021/ic901330y Supporting Info

Spin Maximization from S = 11 to S = 16 in Mn7 Disk-Like Clusters: Spin Frustration Effects and Their Computational Rationalization Theocharis C. Stamatatos, Dolos Foguet-Albiol, Katye M. Poole, Wolfgang Wernsdorfer, Khalil A. Abboud, Ted A. O’Brien and George Christou pp 9831–9845 DOI: 10.1021/ic901393m Supporting Info

Chloro and Azido Diruthenium Complexes Bearing Electron-Rich N,N′,N′′-Triphenylguanidinate Ligands Jzsef S. Pap, Jamie L. Snyder, Paula M. B. Piccoli and John F. Berry pp 9846–9852 DOI: 10.1021/ic901419w Supporting Info

Syntheses and Photophysical Behavior of Porphyrin Isomer Sn(IV) Complexes Daisuke Maeda, Hisashi Shimakoshi, Masaaki Abe and Yoshio Hisaeda pp 9853–9860 DOI: 10.1021/ic901401t Supporting Info

Discovering the Complex Chemistry of a Simple NiII/H3L System: Magnetostructural Characterization and DFT Calculations of Di- and Polynuclear Nickel(II) Compounds Matilde Fondo, Noelia Ocampo, Ana M. Garca-Deibe, Eliseo Ruz, Javier Tercero and Jess Sanmartn pp 9861–9873 DOI: 10.1021/ic9014916 Supporting Info

Isostructural Bis-1,2,3-Thiaselenazolyl Dimers Alicea A. Leitch, Xueyang Yu, Craig M. Robertson, Richard A. Secco, John S. Tse and Richard T. Oakley pp 9874–9882 DOI: 10.1021/ic901563n Supporting Info

Ammonia Borane Hydrogen Release in Ionic Liquids Daniel W. Himmelberger, Laif R. Alden, Martin E. Bluhm and Larry G. Sneddon pp 9883–9889 DOI: 10.1021/ic901560h Supporting Info

Tetrakis(thiadiazole)porphyrazines. 6. Spectroelectrochemical and Density Functional Theory Studies of the Anions [TTDPzM]n− (n = 1−4; M = ZnII, MgII(H2O), CuII, 2HI) Maria Pia Donzello, Claudio Ercolani, Xiaohui Cai, Karl M. Kadish, Giampaolo Ricciardi and Angela Rosa pp 9890–9903 DOI: 10.1021/ic9014288 Supporting Info

Twofold Coordinated Ground-State and Eightfold High-Pressure Phases of Heavy Transition Metal Nitrides MN2 (M = Os, Ir, Ru, and Rh) Yinwei Li, Hui Wang, Quan Li, Yanming Ma, Tian Cui and Guangtian Zou pp 9904–9909 DOI: 10.1021/ic9014702

Heterolytic Cleavage of Disulfides by Frustrated Lewis Pairs Meghan A. Dureen, Gregory C. Welch, Thomas M. Gilbert and Douglas W. Stephan pp 9910–9917 DOI: 10.1021/ic901590s Supporting Info

Energetic Nitrogen-Rich Cu(II) and Cd(II) 5,5′-Azobis(tetrazolate) Complexes Guo-Hong Tao, Brendan Twamley and Jean’ne M. Shreeve pp 9918–9923 DOI: 10.1021/ic901492r Supporting Info

Synthesis, Characterization, and Electrochemistry of a Series of Iron(II) Complexes Containing Self-Assembled 1,5-Diaza-3,7-diphosphabicyclo[3.3.1]nonane Ligands Andrew D. Burrows, Ross W. Harrington, Andrew S. Kirk, Mary F. Mahon, Frank Marken, John E. Warren and Michael K. Whittlesey pp 9924–9935 DOI: 10.1021/ic900874f Supporting Info

Synthesis, Structure, and Reaction Chemistry of Samarium(II), Europium(II), and Ytterbium(II) Complexes of the Unsymmetrical Benzamidinate Ligand [PhC(NSiMe3)(NC6H3Pri2-2,6)]− Shuang Yao, Hoi-Shan Chan, Chi-Keung Lam and Hung Kay Lee pp 9936–9946 DOI: 10.1021/ic901327m Supporting Info

Electrochemistry and Spectroscopy of Organometallic Terpyridine Nickel Complexes Claudia Hamacher, Natascha Hurkes, Andr Kaiser, Axel Klein and Andreas Schren pp 9947–9951 DOI: 10.1021/ic900753r Supporting Info

Crystal Structures and Characterizations of Mixed Valence 12 l-Perovskites Ba4EuM3O12 (M = Ru and Ir) Yuki Shimoda, Yoshihiro Doi, Makoto Wakeshima and Yukio Hinatsu pp 9952–9957 DOI: 10.1021/ic9009652 Supporting Info

Issue 21

Formation of a 3D Porous Ferric Arsenate Containing Novel Cubane-like Fe4F4 Building Units Zhuihui Yi, Chao Yang, Wujiong Xia, Xianzhu Xu and Xiao Zhang pp 9959–9961 DOI: 10.1021/ic900892q Supporting Info

Open-Framework Germanate Built from the Hexagonal Packing of Rigid Cylinders Charlotte Bonneau, Junliang Sun, Rebeca Sanchez-Smith, Bing Guo, Daliang Zhang, Andrew Kentaro Inge, Mattias Edn and Xiaodong Zou pp 9962–9964 DOI: 10.1021/ic900940s Supporting Info

Origin of the Unusual Stability of B12 and B13+ Clusters Boggavarapu Kiran, G. Gopa Kumar, Minh T. Nguyen, Anil K. Kandalam and Puru Jena pp 9965–9967 DOI: 10.1021/ic901410h Supporting Info

Molecular Supertetrahedron Decorated with Exposed Sulfonate Groups Built from Mixed-Valence Tetranuclear Fe33+Fe2+(μ3-Ο)(μ3-SO4)3(−CO2)3 Clusters Ioanna Papadaki, Christos D. Malliakas, Thomas Bakas and Pantelis N. Trikalitis pp 9968–9970 DOI: 10.1021/ic901145d Supporting Info

Synthesis and Gas Sorption Properties of a Metal-Azolium Framework (MAF) Material Jeong Yong Lee, John M. Roberts, Omar K. Farha, Amy A. Sarjeant, Karl A. Scheidt and Joseph T. Hupp pp 9971–9973 DOI: 10.1021/ic901174p Supporting Info

Synthesis and Sulfur Oxygenation of a (N3S)Ni Complex Related to Nickel-Containing Superoxide Dismutase Christopher S. Mullins, Craig A. Grapperhaus, Brian C. Frye, Larry H. Wood, Amy J. Hay, Robert M. Buchanan and Mark S. Mashuta pp 9974–9976 DOI: 10.1021/ic901246w Supporting Info

Effect of Counterions on the Structure and Stability of Aqueous Uranyl(VI) Complexes. A First-Principles Molecular Dynamics Study Michael Bhl, Georg Schreckenbach, Nicolas Sieffert and Georges Wipff pp 9977–9979 DOI: 10.1021/ic901298q Supporting Info

Discrimination of Small Gas Molecules through Adsorption: Reverse Selectivity for Hydrogen in a Flexible Metal−Organic Framework Hyungphil Chun and Jinwoo Seo pp 9980–9982 DOI: 10.1021/ic901456k Supporting Info

Does [I3]+ Act as an “[I]+” Donor to CH3CN and N2O? Structure of [H3CCN-I-NCCH3]+[AsF6]− Margaret-Jane Crawford, Michael Gbel, Konstantin Karaghiosoff, Thomas M. Klaptke and Jan M. Welch pp 9983–9985 DOI: 10.1021/ic9015492 Supporting Info

Nitric Oxide Chemisorption in a Postsynthetically Modified Metal−Organic Framework Michael J. Ingleson, Romain Heck, Jamie A. Gould and Matthew J. Rosseinsky pp 9986–9988 DOI: 10.1021/ic9015977 Supporting Info

Valence-Tautomeric Ionic Liquid Composed of a Cobalt Bis(dioxolene) Complex Dianion Yukihiro Yoshida, Hirofusa Tanaka, Gunzi Saito, Lahcne Ouahab, Hiroyuki Yoshida and Naoki Sato pp 9989–9991 DOI: 10.1021/ic901591p Supporting Info

Temperature-Controlled Syntheses of Substituted 1,2,4-Triazolelead(II) Complexes: Active Lone Pair and N−H···X (X = Cl, Br, I) Hydrogen Bonds Jian-Kai Cheng, Jian Zhang, Pei-Xiu Yin, Qi-Pu Lin, Zhao-Ji Li and Yuan-Gen Yao pp 9992–9994 DOI: 10.1021/ic901653y Supporting Info

Facile Preparation of 3,4-Diarylpyrroles and Hydrogen by a Platinum(II) Terpyridyl Complex Deng-Hui Wang, Ming-Li Peng, Yong Han, Bin Chen, Chen-Ho Tung and Li-Zhu Wu pp 9995–9997 DOI: 10.1021/ic901666j Supporting Info

H2-Driven Deoxygenation of Epoxides and Diols to Alkenes Catalyzed by Methyltrioxorhenium Jeanette E. Ziegler, Michael J. Zdilla, Andrew J. Evans and Mahdi M. Abu-Omar pp 9998–10000 DOI: 10.1021/ic901792b Supporting Info

Chemistry of Personalized Solar Energy Daniel G. Nocera pp 10001–10017 DOI: 10.1021/ic901328v

Chirality- and Threefold-Symmetry-Directed Assembly of Homochiral Octupolar Metal−Organoboron Frameworks Yan Liu, Weimin Xuan, Hui Zhang and Yong Cui pp 10018–10023 DOI: 10.1021/ic9002675 Supporting Info

A Hydrogen-Bond Facilitated Cycle for Oxygen Reduction by an Acid- and Base-Compatible Iron Platform Han Sen Soo, Alexis C. Komor, Anthony T. Iavarone and Christopher J. Chang pp 10024–10035 DOI: 10.1021/ic9006668 Supporting Info

Structural and Catalytic Characterization of a Heterovalent Mn(II)Mn(III) Complex That Mimics Purple Acid Phosphatases Sarah J. Smith, Mark J. Riley, Christopher J. Noble, Graeme R. Hanson, Robert Stranger, Vidura Jayaratne, Germn Cavigliasso, Gerhard Schenk and Lawrence R. Gahan pp 10036–10048 DOI: 10.1021/ic9005086 Supporting Info

Oligonuclear Homoleptic Copper(I) Pyrazolates with Multinucleating Ligand Scaffolds: High Structural Diversity in Solid-State and Solution Michael Stollenz, Michael John, Henrike Gehring, Sebastian Dechert, Christian Grosse and Franc Meyer pp 10049–10059 DOI: 10.1021/ic900727h Supporting Info

Ab Initio Search for Global Minimum Structures of the Novel B3Hy (y=4−7) Neutral and Anionic Clusters Jared K. Olson and Alexander I. Boldyrev pp 10060–10067 DOI: 10.1021/ic900905h

Organo-Ruthenium Supported Heteropolytungstates: Synthesis, Structure, Electrochemistry, and Oxidation Catalysis Li-Hua Bi, Ghada Al-Kadamany, Elena V. Chubarova, Michael H. Dickman, Lifang Chen, Divakara S. Gopala, Ryan M. Richards, Bineta Keita, Louis Nadjo, Helge Jaensch, Georges Mathys and Ulrich Kortz pp 10068–10077 DOI: 10.1021/ic9009306 Supporting Info

Crystallization Behavior and Controlling Mechanism of Iron-Containing Si−C−N Ceramics Adel Francis, Emanuel Ionescu, Claudia Fasel and Ralf Riedel pp 10078–10083 DOI: 10.1021/ic900934u

Redox Effects on the Coordination Geometry and Heme Conformation of Bis(N-methylimidazole) Complexes of Superstructured Fe-Porphyrins. A Spectroscopic Study Carole Le Moigne, Thierry Picaud, Alain Boussac, Bernard Loock, Michel Momenteau and Alain Desbois pp 10084–10092 DOI: 10.1021/ic9010604

One-Pot, Template Syntheses of a New Class of Metallomacrocycles with a Tetraoxime Cyclic Skeleton Shohei Tashiro, Ai Minoda, Mihoko Yamada and Mitsuhiko Shionoya pp 10093–10101 DOI: 10.1021/ic900993j Supporting Info

Phosphorus−Nitrogen Compounds. 18. Syntheses, Stereogenic Properties, Structural and Electrochemical Investigations, Biological Activities, and DNA Interactions of New Spirocyclic Mono- and Bisferrocenylphosphazene Derivatives Nuran Asmafiliz, Zeynel Kılı, Aslı ztrk, Tuncer Hkelek, L. Yasemin Ko, Leyla Aık, zgl Kısa, Ali Albay, Zafer stnda and Ali Osman Solak pp 10102–10116 DOI: 10.1021/ic901039k Supporting Info

From closo to isocloso Structures and Beyond in Cobaltaboranes with 9 to 12 Vertices R. Bruce King, Ioan Silaghi-Dumitrescu and Ioana ovago pp 10117–10125 DOI: 10.1021/ic901070m Supporting Info

Experimental and TDDFT Characterization of the Light-Induced Cluster-to-Iron Charge Transfer in the (Ferrocenylethynyl)-Substituted Trinuclear Platinum Derivative [Pt3(μ-PBut2)3(CO)2(C≡C−Fc)]+ Fabrizia Fabrizi de Biani, Gabriele Manca, Lorella Marchetti, Piero Leoni, Samantha Bruzzone, Carla Guidotti, Andrea Atrei, Alberto Albinati and Silvia Rizzato pp 10126–10137 DOI: 10.1021/ic901046f Supporting Info

Quantitative Photochemical Formation of [Ru(tpy)(bpy)H]+ Yasuo Matsubara, Hideo Konno, Atsuo Kobayashi and Osamu Ishitani pp 10138–10145 DOI: 10.1021/ic901080r Supporting Info

Magneto−Structural Correlation in a Metamagnetic Cobalt(II)-Based Pillared Trilayer Motif Constructed by Mixed Pyridyl-Type Carboxylate Ligands Yan-Ling Zhou, Mei-Chun Wu, Ming-Hua Zeng and Hong Liang pp 10146–10150 DOI: 10.1021/ic901085p Supporting Info

Structural Anomalies Associated with Antiferromagnetic Transition of Single-Component Molecular Metal [Au(tmdt)2] Biao Zhou, Akiko Kobayashi, Yoshinori Okano, HengBo Cui, David Graf, James S. Brooks, Takeshi Nakashima, Shinobu Aoyagi, Eiji Nishibori, Makoto Sakata and Hayao Kobayashi pp 10151–10157 DOI: 10.1021/ic901172u Supporting Info

Thermodynamics, Optical Properties, and Coordination Modes of Np(V) with Dipicolinic Acid Guoxin Tian, Linfeng Rao and Simon J. Teat pp 10158–10164 DOI: 10.1021/ic9011185 Supporting Info

Synthesis, Structure, and Magnetic Characterization of a C3-Symmetric MnIII3CrIII Assembly: Molecular Recognition Between a Trinuclear MnIII Triplesalen Complex and a fac-Triscyano CrIII Complex Carl-Georg Freiherr von Richthofen, Anja Stammler, Hartmut Bgge, Marty W. DeGroot, Jeffrey R. Long and Thorsten Glaser pp 10165–10176 DOI: 10.1021/ic901148q Supporting Info

One-Dimensional Homochiral Cyano-Bridged Heterometallic Chain Coordination Polymers with Metamagnetic or Ferroelectric Properties He-Rui Wen, Yun-Zhi Tang, Cai-Ming Liu, Jing-Lin Chen and Chang-Lin Yu pp 10177–10185 DOI: 10.1021/ic901224f Supporting Info

Solid-State NMR Study of Dehydration of Layered α-Niobium Phosphate Jianfeng Zhu and Yining Huang pp 10186–10192 DOI: 10.1021/ic9011668 Supporting Info

Facile Chemical Conversion Synthesis and Luminescence Properties of Uniform Ln3+ (Ln = Eu, Tb)-Doped NaLuF4 Nanowires and LuBO3 Microdisks Guang Jia, Hongpeng You, Yanhua Song, Junjiao Jia, Yuhua Zheng, Lihui Zhang, Kai Liu and Hongjie Zhang pp 10193–10201 DOI: 10.1021/ic901655m Supporting Info

Luminescence Vapochromism of a Platinum(II) Complex for Detection of Low Molecular Weight Halohydrocarbon Jun Ni, Yu-Hui Wu, Xu Zhang, Bin Li, Li-Yi Zhang and Zhong-Ning Chen pp 10202–10210 DOI: 10.1021/ic9011982 Supporting Info

Molybdenum(VI) Dioxo Complexes with Tridentate Phenolate Ligands Martina E. Judmaier, Andreas Wallner, Gregor N. Stipicic, Karl Kirchner, Judith Baumgartner, Ferdinand Belaj and Nadia C. Msch-Zanetti pp 10211–10221 DOI: 10.1021/ic901201s Supporting Info

Morphology-Controlled Synthesis of Inorganic Nanocrystals via Surface Reconstruction of Nuclei Guolei Xiang, Jing Zhuang and Xun Wang pp 10222–10230 DOI: 10.1021/ic901217k Supporting Info

Halogenoids as Ligands in Superhalogen Anions Sylwia Smuczyska and Piotr Skurski pp 10231–10238 DOI: 10.1021/ic901253r Supporting Info

Structural Investigation of Lanthanoid Coordination: a Combined XANES and Molecular Dynamics Study Paola D’Angelo, Andrea Zitolo, Valentina Migliorati, Giordano Mancini, Ingmar Persson and Giovanni Chillemi pp 10239–10248 DOI: 10.1021/ic901264e Supporting Info

Full- or Half-Encapsulation of Sulfate Anion by a Tris(3-pyridylurea) Receptor: Effect of the Secondary Coordination Sphere Fuyu Zhuge, Biao Wu, Jianjun Liang, Jin Yang, Yanyan Liu, Chuandong Jia, Christoph Janiak, Ning Tang and Xiao-Juan Yang pp 10249–10256 DOI: 10.1021/ic9012685 Supporting Info

H2 Activation by a (PNP)Ir(C6H5) Complex via the Dearomatization/Aromatization Process of the PNP Ligand: A Computational Study Guixiang Zeng, Yong Guo and Shuhua Li pp 10257–10263 DOI: 10.1021/ic9013587 Supporting Info

Building Multistate Redox-Active Architectures Using Metal-Complex Functionalized Perylene Bis-imides Gudrun Goretzki, E. Stephen Davies, Stephen P. Argent, John E. Warren, Alexander J. Blake and Neil R. Champness pp 10264–10274 DOI: 10.1021/ic901379d Supporting Info

AsMo7O27-Bridged Dinuclear Sandwich-Type Heteropolymolybdates of Cr(III) and Fe(III): Magnetism of [MM′(AsMo7O27)2]12− with MM′ = FeFe, CrFe, and CrCr Haisheng Xu, Lili Li, Bin Liu, Ganglin Xue, Huaiming Hu, Feng Fu and Jiwu Wang pp 10275–10280 DOI: 10.1021/ic901416m Supporting Info

Trinuclear Terpyridine Frustrated Spin System with a MnIV3O4 Core: Synthesis, Physical Characterization, and Quantum Chemical Modeling of Its Magnetic Properties Carole Baffert, Maylis Orio, Dimitrios A. Pantazis, Carole Duboc, Allan G. Blackman, Genevive Blondin, Frank Neese, Alain Deronzier and Marie-Nolle Collomb pp 10281–10288 DOI: 10.1021/ic901409y Supporting Info

Systematic Thermodynamics of Magnli-Phase and Other Transition Metal Oxides Leslie Glasser pp 10289–10294 DOI: 10.1021/ic901395z Supporting Info

Probing Metal-Ion Purine Interactions at DNA Minor-Groove Sites Miguel A. Galindo, David Amantia, Alberto Martinez Martinez, William Clegg, Ross W. Harrington, Virtudes Moreno Martinez and Andrew Houlton pp 10295–10303 DOI: 10.1021/ic9013448 Supporting Info

Mercury(II) Recognition and Fluorescence Imaging in Vitro through a 3D-Complexation Structure Mei-Lin Ho, Kew-Yu Chen, Gene-Hsiang Lee, Yu-Chun Chen, Chih-Chieh Wang, Jyh-Fu Lee, Wen-Chun Chung and Pi-Tai Chou pp 10304–10311 DOI: 10.1021/ic901613s Supporting Info

Facile Synthesis of Bismuth(III) and Antimony(III) Complexes Supported by Silylated Calix[5]arenes. Daniel Mendoza-Espinosa and Tracy A. Hanna pp 10312–10325 DOI: 10.1021/ic9014477 Supporting Info

Biomineralization and Superhydrophobicity of BaCO3 Complex Nanostructures Shuisheng Wu, Huaqiang Cao, Shuangfeng Yin, Xinrong Zhang and Victoria Chernow pp 10326–10329 DOI: 10.1021/ic9014724 Supporting Info

Halide-Capped Tellurium-Containing Macrocycles Vadapalli Chandrasekhar and Ramalingam Thirumoorthi pp 10330–10337 DOI: 10.1021/ic901479z Supporting Info

Effect of the Regiochemistry of Butyl Amide Substituents on the Solution-State Structures of Lanthanide(III) DOTA-Tetraamide Complexes Tomoyasu Mani, Gyula Tircs, Piyu Zhao, A. Dean Sherry and Mark Woods pp 10338–10345 DOI: 10.1021/ic9017008 Supporting Info

6-Azahemiporphycene: A New Member of the Porphyrinoid Family Federica Mandoj, Sara Nardis, Giuseppe Pomarico, Manuela Stefanelli, Luca Schiaffino, Gianfranco Ercolani, Luca Prodi, Damiano Genovese, Nelsi Zaccheroni, Frank R. Fronczek, Kevin M. Smith, Xiao Xiao, Jing Shen, Karl M. Kadish and Roberto Paolesse pp 10346–10357 DOI: 10.1021/ic9014866 Supporting Info

Concerning the Reaction Pathway of the Metathesis Reaction involving WW and CN Triple Bonds: A Theoretical Study Shentan Chen and Malcolm H. Chisholm pp 10358–10363 DOI: 10.1021/ic901528c Supporting Info

Gd5Si4-xBix Structures: Novel Slab Sequences Achieved by Turning off the Directionality of Nearest-Slab Interactions Volodymyr Svitlyk, Branton J. Campbell and Yurij Mozharivskyj pp 10364–10370 DOI: 10.1021/ic901582j Supporting Info

Guided Ion Beam and Theoretical Studies of the Reactions of Pd+ with CS2: Thermochemistry of PdS+ and PdCS+ P. B. Armentrout, Ilona Kretzschmar pp 10371–10382 DOI: 10.1021/ic9015959

Composition and Structure of Polynuclear Chromium(III) Hydroxo Complexes Natallia Torapava, Artsiom Radkevich, Dmitri Davydov, Andrei Titov and Ingmar Persson pp 10383–10388 DOI: 10.1021/ic901539g Supporting Info

Oxidation of Cyclohexane by High-Valent Iron Bispidine Complexes: Tetradentate versus Pentadentate Ligands Peter Comba, Martin Maurer and Prabha Vadivelu pp 10389–10396 DOI: 10.1021/ic901702s Supporting Info

Tight-Contact Ion Pairs Involving Pt(II) Dithiooxamide Complexes: the Acid−Base Reactions between Hydrohalogenated Ion-Paired Complexes and Pyridine Antonino Giannetto, Fausto Puntoriero, Anna Barattucci, Santo Lanza and Sebastiano Campagna pp 10397–10404 DOI: 10.1021/ic900875b Supporting Info

Metal Loading Capacity of Aβ N-Terminus: a Combined Potentiometric and Spectroscopic Study of Zinc(II) Complexes with Aβ(1−16), Its Short or Mutated Peptide Fragments and Its Polyethylene Glycol−ylated Analogue Chiara A. Damante, Katalin sz, Zoltn Nagy, Giuseppe Pappalardo, Giulia Grasso, Giuseppe Impellizzeri, Enrico Rizzarelli and Imre Svg pp 10405–10415 DOI: 10.1021/ic9012334 Supporting Info

Macrocycle-Based Spin-Crossover Materials Fatima El Hajj, Ghania Sebki, Vronique Patinec, Mathieu Marchivie, Smail Triki, Henri Handel, Said Yefsah, Raphal Tripier, Carlos J. Gmez-Garca and Eugenio Coronado pp 10416–10423 DOI: 10.1021/ic9012476

Polynuclear Complexes: Two Amino−Phenol Macrocycles Spaced by Several Linear Polyamines; Synthesis, Binding Properties, and Crystal Structure Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Eleonora Macedi, Mauro Micheloni, Paola Paoli and Patrizia Rossi pp 10424–10434 DOI: 10.1021/ic901459b Supporting Info

Effects of Ionic Liquids on the Characteristics of Synthesized Nano Fe(0) Particles Yang Zhao, Guirong Cui, Jianji Wang and Maohong Fan pp 10435–10441 DOI: 10.1021/ic901559y

Sulfonamide-Supported Group 4 Catalysts for the Ring-Opening Polymerization of ε-Caprolactone and rac-Lactide Andrew D. Schwarz, Amber L. Thompson and Philip Mountford pp 10442–10454 DOI: 10.1021/ic901524s Supporting Info

Elucidation of the Structure of a Highly Active Catalytic System for CO2/Epoxide Copolymerization: A salen-Cobaltate Complex of an Unusual Binding Mode Sung Jae Na, Sujith S, Anish Cyriac, Bo Eun Kim, Jina Yoo, Youn K. Kang, Su Jung Han, Chongmok Lee and Bun Yeoul Lee pp 10455–10465 DOI: 10.1021/ic901584u Supporting Info

From Classical Adducts to Frustrated Lewis Pairs: Steric Effects in the Interactions of Pyridines and B(C6F5)3 Stephen J. Geier, Austin L. Gille, Thomas M. Gilbert and Douglas W. Stephan pp 10466–10474 DOI: 10.1021/ic901726b Supporting Info

Aminoethylglycine-Functionalized Ru(bpy)32+ with Pendant Bipyridines Self-Assemble Multimetallic Complexes by Copper and Zinc Coordination Carl P. Myers, Brian P. Gilmartin and Mary Elizabeth Williams p 10475 DOI: 10.1021/ic901852s

Correction to Chiral Synthesis of a Mononuclear Nickel(II) Complex Formed from an Achiral Tripodal Amine Ligand: Spontaneous Resolution A. Srinivasa Rao, Abhijit Pal, Rajarshi Ghosh and Samar K. Das p 10476 DOI: 10.1021/ic9018635

Issue 22

Catalytic Alkenylation of Phenylpyridines with Terminal Alkynes by a [12]Metallacrown-6 Ruthenium(II) Compound Ming-Hua Xie, Miao Wang and Chuan-De Wu pp 10477–10479 DOI: 10.1021/ic901309b Supporting Info

Extremely Efficient Alkane Oxidation by a New Catalytic Reagent H2O2/Os3(CO)12/Pyridine Georgiy B. Shul’pin, Yuriy N. Kozlov, Lidia S. Shul’pina, Alexander R. Kudinov and Dalmo Mandelli pp 10480–10482 DOI: 10.1021/ic901576r Supporting Info

Salen-Based Infinite Coordination Polymers of Nickel and Copper Asamanjoy Bhunia, Peter W. Roesky, Yanhua Lan, George E. Kostakis and Annie K. Powell pp 10483–10485 DOI: 10.1021/ic9017097 Supporting Info

On the Origin of Magnetic Anisotropy in Cyanide-Bridged Co9M6 (M = MoV or WV) Systems: A DFT Study Yi-Quan Zhang and Cheng-Lin Luo pp 10486–10488 DOI: 10.1021/ic9014527 Supporting Info

Hybrid Spin-Crossover Conductor Exhibiting Unusual Variable-Temperature Electrical Conductivity Brandon Djukic and Martin T. Lemaire pp 10489–10491 DOI: 10.1021/ic9015542 Supporting Info

White OLED with a Single-Component Europium Complex Ga-Lai Law, Ka-Leung Wong, Hoi-Lam Tam, Kok-Wai Cheah and Wing-Tak Wong pp 10492–10494 DOI: 10.1021/ic9018037 Supporting Info

Nonconventional Behavior of NCN-Chelated Organoantimony(III) Sulfide and Isolation of Cyclic Organoantimony(III) Bis(pentasulfide) Libor Dostl, Roman Jambor, Ale Rika, Robert Jirsko, Vclav Locha, Ludvk Bene and Frank de Proft pp 10495–10497 DOI: 10.1021/ic901873k Supporting Info

Structure−Activity Correlations Among Iridium(III) Photosensitizers in a Robust Water-Reducing System Peter N. Curtin, Leonard L. Tinker, Christine M. Burgess, Eric D. Cline and Stefan Bernhard pp 10498–10506 DOI: 10.1021/ic9007763 Supporting Info

Photon-Driven Catalytic Proton Reduction with a Robust Homoleptic Iridium(III) 6-Phenyl-2,2′-bipyridine Complex ([Ir(C/\N/\N)2]+) Leonard L. Tinker and Stefan Bernhard pp 10507–10511 DOI: 10.1021/ic900777g

Preparation of an Isocyano-β-diketone via its Metal Complexes, by Use of Metal Ions as Protecting Groups Yixun Zhang and Andrew W. Maverick pp 10512–10518 DOI: 10.1021/ic900202e Supporting Info

Facile Route to Nitrides: Transformation from Single Element to Binary and Ternary Nitrides at Moderate Temperature through a New Modified Solid-State Metathesis Bo Song, Xiaolong Chen, Jiecai Han, Jikang Jian, Wanyan Wang, Hongbo Zuo, Xinghong Zhang and Songhe Meng pp 10519–10527 DOI: 10.1021/ic901861c

Inhibition of Electrocatalytic O2 Reduction of Functional CcO Models by Competitive, Non-Competitive, and Mixed Inhibitors James P. Collman, Abhishek Dey, Christopher J. Barile, Somdatta Ghosh and Richard A. Decrau pp 10528–10534 DOI: 10.1021/ic900825y Supporting Info

Multitopic Ligand Design: A Concept for Single-Source Precursors Fabienne Gschwind, Olha Sereda and Katharina M. Fromm pp 10535–10547 DOI: 10.1021/ic9009064 Supporting Info

Self-Template Synthesis of CdIn2O4 Hollow Spheres and Effects of Cd/In Molar Ratios on Its Morphologies Jiaoxian Yu, Baibiao Huang, Zeyan Wang, Xiaoyan Qin, Xiaoyang Zhang and Peng Wang pp 10548–10552 DOI: 10.1021/ic901389v

In Situ Powder X-ray Diffraction, Synthesis, and Magnetic Properties of the Defect Zircon Structure ScVO4−x Shahid P. Shafi, Matthew W. Kotyk, Lachlan M. D. Cranswick, Vladimir K. Michaelis, Scott Kroeker and Mario Bieringer pp 10553–10559 DOI: 10.1021/ic900927j

Metallopeptide Based Mimics with Substituted Histidines Approximate a Key Hydrogen Bonding Network in the Metalloenzyme Nickel Superoxide Dismutase Jason Shearer, Kosh P. Neupane and Paige E. Callan pp 10560–10571 DOI: 10.1021/ic9010407 Supporting Info

A Multiconfigurational ab Initio Study of the Zero-Field Splitting in the Di- and Trivalent Hexaquo−Chromium Complexes Dimitrios G. Liakos, Dmitry Ganyushin and Frank Neese pp 10572–10580 DOI: 10.1021/ic901063y

Dioxomolybdenum(VI) Complexes with Ene-1,2-dithiolate Ligands: Synthesis, Spectroscopy, and Oxygen Atom Transfer Reactivity Hideki Sugimoto, Susumu Tatemoto, Koichiro Suyama, Hiroyuki Miyake, Shinobu Itoh, Chao Dong, Jing Yang and Martin L. Kirk pp 10581–10590 DOI: 10.1021/ic901112s Supporting Info

Synthesis, Structures, and Properties of 1,2,4,5-Benzenetetrathiolate Linked Group 10 Metal Complexes Kuppuswamy Arumugam, Mohamed C. Shaw, P. Chandrasekaran, Dino Villagrn, Thomas G. Gray, Joel T. Mague and James P. Donahue pp 10591–10607 DOI: 10.1021/ic901257s Supporting Info

Topological Dependence of the Magnetic Exchange Coupling in Arylethynyl-Bridged Organometallic Diradicals Containing [(η2-dppe)(η5-C5Me5)FeIII]+ Fragments Frdric Paul, Arnaud Bondon, Grgory da Costa, Floriane Malvolti, Sourisak Sinbandhit, Olivier Cador, Karine Costuas, Loic Toupet and Marie-Laure Boillot pp 10608–10624 DOI: 10.1021/ic9011026 Supporting Info

Investigation of the Coordination Interactions of S-(Pyridin-2-ylmethyl)-l-Cysteine Ligands with M(CO)3+ (M = Re, 99mTc) Haiyang He, Jennifer E. Morley, Brendan Twamley, Ryan H. Groeneman, Dejan-Kreimir Buar, Leonard R. MacGillivray and Paul D. Benny pp 10625–10634 DOI: 10.1021/ic901159r Supporting Info

Reaction Sequence and Kinetics of Uranium Nitride Decomposition G. W. Chinthaka Silva, Charles B. Yeamans, Alfred P. Sattelberger, Thomas Hartmann, Gary S. Cerefice and Kenneth R. Czerwinski pp 10635–10642 DOI: 10.1021/ic901165j

A Mixed-Valent Pentanuclear CuII4CuI Compound Containing a Radical-Anion Ligand Tiddo J. Mooibroek, Guillem Arom, Manuel Quesada, Olivier Roubeau, Patrick Gamez, Serena DeBeer George, Joris van Slageren, Shadi Yasin, Eliseo Ruiz and Jan Reedijk pp 10643–10651 DOI: 10.1021/ic901337r Supporting Info

Theoretical Study of the Pseudo-Jahn−Teller Effect in the Edge-Sharing Bioctahedral Complex Mo2(DXylF)2(O2CCH3)2(μ2-O)2 Justyna M. urek and Martin J. Paterson pp 10652–10657 DOI: 10.1021/ic901285f Supporting Info

Monofluoride Bridged, Binuclear Metallacycles of First Row Transition Metals Supported by Third Generation Bis(1-pyrazolyl)methane Ligands: Unusual Magnetic Properties Daniel L. Reger, Elizabeth A. Foley, Russell P. Watson, Perry J. Pellechia and Mark D. Smith, Fernande Grandjean, Gary J. Long pp 10658–10669 DOI: 10.1021/ic901352p Supporting Info

Multiple Folding Structures Mediated by Metal Coordination of Acyclic Multidentate Ligand Shigehisa Akine, Yoko Morita, Fumihiko Utsuno and Tatsuya Nabeshima pp 10670–10678 DOI: 10.1021/ic901372k Supporting Info

Planar Hepta-, Octa-, Nona-, and Decacoordinate First Row d-Block Metals Enclosed by Boron Rings Zhifeng Pu, Keigo Ito, Paul v. R. Schleyer and Qian-Shu Li pp 10679–10686 DOI: 10.1021/ic901377h Supporting Info

Luminescent Lanthanide Helicates Self-Assembled from Ditopic Ligands Bearing Phosphonic Acid or Phosphoester Units Anne-Sophie Chauvin, Steve Comby, Matthias Baud, Cyntia De Piano, Cline Duhot and Jean-Claude G. Bnzli pp 10687–10696 DOI: 10.1021/ic901424w Supporting Info

Ag/AgBr/WO3·H2O: Visible-Light Photocatalyst for Bacteria Destruction Peng Wang, Baibiao Huang, Xiaoyan Qin, Xiaoyang Zhang, Ying Dai and Myung-Hwan Whangbo pp 10697–10702 DOI: 10.1021/ic9014652

Twin Salphen: Asymmetric Heterodinuclear Complexes {MaMbL | Ma, Mb = Ni, Cu, Zn} of a Symmetrically Fused Salphen Ligand Hirohiko Houjou, Muneyuki Ito and Koji Araki pp 10703–10707 DOI: 10.1021/ic901937p Supporting Info

2-Phenoxypyridyl Dinucleating Ligands for Assembly of Diiron(II) Complexes: Efficient Reactivity with O2 To Form (μ-Oxo)diiron(III) Units Loi H. Do and Stephen J. Lippard pp 10708–10719 DOI: 10.1021/ic901711c Supporting Info

Electronic Structure and Spectroscopy of [Ru(tpy)2]2+, [Ru(tpy)(bpy)(H2O)]2+, and [Ru(tpy)(bpy)(Cl)]+ Elena Jakubikova, Weizhong Chen, Dana M. Dattelbaum, Francisca N. Rein, Reginaldo C. Rocha, Richard L. Martin and Enrique R. Batista pp 10720–10725 DOI: 10.1021/ic901477m Supporting Info

Consecutive Irreversible Single-Crystal to Single-Crystal and Reversible Single-Crystal to Glass Transformations and Associated Magnetism of the Coordination Polymer, [MnII(rac-pnH)(H2O)CrIII(CN)6]·H2O Yusuke Yoshida, Katsuya Inoue and Mohamedally Kurmoo pp 10726–10736 DOI: 10.1021/ic901615e Supporting Info

[OsIVCl5(Hazole)]− Complexes: Synthesis, Structure, Spectroscopic Properties, and Antiproliferative Activity Gabriel E. Bchel, Iryna N. Stepanenko, Michaela Hejl, Michael A. Jakupec, Vladimir B. Arion and Bernhard K. Keppler pp 10737–10747 DOI: 10.1021/ic901671j Supporting Info

High Energy Resolution X-ray Absorption Spectroscopy of Environmentally Relevant Lead(II) Compounds Janine C. Swarbrick, Ulf Skyllberg, Torbjrn Karlsson and Pieter Glatzel pp 10748–10756 DOI: 10.1021/ic9015299

Copper Halide-Incorporated Tellurium−Iron Carbonyl Complexes: Transformation, Electrochemical Properties, and Theoretical Calculations Bo-Gaun Chen, Chia-Hua Ho, Chang-Ju Lee and Minghuey Shieh pp 10757–10768 DOI: 10.1021/ic901647n Supporting Info

Titanium(IV) Complexes with N,N′-Dialkyl-2,3-dihydroxyterephthalamides and 1-Hydroxy-2(1H)-pyridinone as Siderophore and Tunichrome Analogues Ritika Uppal, Hayley P. Israel, Christopher D. Incarvito and Ann M. Valentine pp 10769–10779 DOI: 10.1021/ic901177c Supporting Info

Calcium Complexation by Corticosteroids Melanie R. Hauser and Kenneth M. Doxsee, Håkon Hope pp 10780–10788 DOI: 10.1021/ic901670r Supporting Info

Intermetallic Communication in Titanium(IV) Ferrocenyldiketonates Lea T. Dulatas, Seth N. Brown, Edema Ojomo, Bruce C. Noll, Matthew J. Cavo, Paul B. Holt and Matthew M. Wopperer pp 10789–10799 DOI: 10.1021/ic901683c Supporting Info

Solution Behavior of Amidine Complexes: An Unexpected cis/trans Isomerization and Formation of Di- and Trinuclear Platinum(III) and Platinum(II) Species Daniele Cornacchia, Raffaella Zoe Pellicani, Francesco Paolo Intini, Concetta Pacifico and Giovanni Natile pp 10800–10810 DOI: 10.1021/ic9011372 Supporting Info

Parametric Analysis of the Crystal Field Splitting Pattern of Sm(η5-C5Me5)3 Derived on the Basis of Absorption Spectra of Pellets or Solutions and Electronic Raman Spectra of Oriented Single Crystals Hanns-Dieter Amberger, Hauke Reddmann and William J. Evans pp 10811–10818 DOI: 10.1021/ic901443x

Predicting the Cis−Trans Dichloro Configuration of Group 15−16 Chelated Ruthenium Olefin Metathesis Complexes: A DFT and Experimental Study Charles E. Diesendruck, Eyal Tzur, Amos Ben-Asuly, Israel Goldberg, Bernd F. Straub and N. Gabriel Lemcoff pp 10819–10825 DOI: 10.1021/ic901444c Supporting Info

Ligand-Solvent Interactions in a Highly Reduced Metal Chelate Complex: Medium Dependence of the One-Electron Reduction of the bis(Maleonitriledithiolato)Gold Dianion Robert J. LeSuer and William E. Geiger pp 10826–10836 DOI: 10.1021/ic901547f Supporting Info

Differing Coordination Environments in Transition Metal Derivatives of 1,8-Bis(silylamido)naphthalene Ligands Alexander J. Blake, Nicola L. Gillibrand, Graeme J. Moxey and Deborah L. Kays pp 10837–10844 DOI: 10.1021/ic901745v Supporting Info

Parametrization of the Contribution of Mono- and Bidentate Ligands on the Symmetric C≡O Stretching Frequency of fac-[Re(CO)3]+ Complexes Fabio Zobi pp 10845–10855 DOI: 10.1021/ic901223t Supporting Info

Correction to Highly Monodisperse Colloidal Magnesium Nanoparticles by Room Temperature Digestive Ripening Suresh Babu Kalidindi and Balaji R. Jagirdar p 10856 DOI: 10.1021/ic901983m

Issue 23

Synthesis and Size Control of Cobalt Phosphate Rosettes Using Surfactant-Templated Synthesis John B. Nelson, Aaron M. Davis and Dawn M. Wellman pp 10857–10858 DOI: 10.1021/ic9016245

Ag(I)-Mediated In situ Dehydrogenative Coupling of 3-Amino-1,2,4-triazole into 3,3′-Azobis(1,2,4-triazole) in Cd(II) Coordination Polymers Pei-Xiu Yin, Jian-Kai Cheng, Zhao-Ji Li, Lei Zhang, Ye-Yan Qin, Jian Zhang and Yuan-Gen Yao pp 10859–10861 DOI: 10.1021/ic9007813 Supporting Info

Unprecedent Isolation of a Mixture of Conformational and Linkage Isomers in a Thiosemicarbazone Cobalt Mesocate Rosa Pedrido, Mara J. Romero, Ana M. Gonzlez-Noya, Manuel R. Bermejo, Miguel Martnez-Calvo and Guillermo Zaragoza pp 10862–10864 DOI: 10.1021/ic901657z Supporting Info

Thermochromic Absorption and Photoluminescence in [Pt(ppy)(μ-Ph2pz)]2 Aaron A. Rachford and Felix N. Castellano pp 10865–10867 DOI: 10.1021/ic901156z Supporting Info

Using the Antenna Effect as a Spectroscopic Tool: Photophysics and Solution Thermodynamics of the Model Luminescent Hydroxypyridonate Complex [EuIII(3,4,3-LI(1,2-HOPO))]− Rebecca J. Abergel, Anthony D’Alo, Clara Ng Pak Leung, David K. Shuh and Kenneth N. Raymond pp 10868–10870 DOI: 10.1021/ic9013703 Supporting Info

New Reversible Crystal-to-Crystal Conversion of a Mixed-Ligand Lead(II) Coordination Polymer by De- and Rehydration Homa Sadeghzadeh and Ali Morsali pp 10871–10873 DOI: 10.1021/ic901532x Supporting Info

Binding of 2-Hydroxypyridine-N-oxide on Dicopper(II) Centers: Insights into Tyrosinase Inhibition Mechanism by Transition-State Analogs Eugnie Peyroux, Wadih Ghattas, Renaud Hardr, Michel Giorgi, Bruno Faure, A. Jalila Simaan, Catherine Belle and Marius Rglier pp 10874–10876 DOI: 10.1021/ic901593x Supporting Info

Nitrate and Perchlorate Complexes of Uranium(IV) Margaret-Jane Crawford, Arkady Ellern, Konstantin Karaghiosoff and Peter Mayer pp 10877–10879 DOI: 10.1021/ic901386y Supporting Info

Self-Assembly of a Pd6−Molecular Double-Square and a Cu3-Trigonalbipyramidal Cage via a New Tripodal Flexible Ligand Arun Kumar Bar, Rajesh Chakrabarty and Partha Sarathi Mukherjee pp 10880–10882 DOI: 10.1021/ic901633g Supporting Info

(I,0) Mixed-Valence State of a Diiron Complex with Pertinence to the [FeFe]-Hydrogenase Active Site: An IR, EPR, and Computational Study Pradyumna S. Singh, Hans Christian Rudbeck, Ping Huang, Salah Ezzaher, Lars Eriksson, Matthias Stein, Sascha Ott and Reiner Lomoth pp 10883–10885 DOI: 10.1021/ic9016454 Supporting Info

Guest-Induced Irreversible Sliding in a Flexible 2D Rectangular Grid with Selective Sorption Characteristics K. L. Gurunatha and Tapas Kumar Maji pp 10886–10888 DOI: 10.1021/ic901804a Supporting Info

A New Ni12 Cluster Based on Polyoxometalate Ligands Hong-Mei Zhang, Yang-Guang Li, Ying Lu, Rodolphe Clrac, Zhi-Ming Zhang, Qiong Wu, Xiao-Jia Feng and En-Bo Wang pp 10889–10891 DOI: 10.1021/ic901552f Supporting Info

Structure Investigations of Dichloroaluminum Benzoates: An Unprecedented Example of a Monomeric Aluminum Complex with a Chelating Carboxylate Ligand Zbigniew Florjaczyk, Wojciech Bury, Ewa Zygadło-Monikowska, Iwona Justyniak, Robert Balawender and Janusz Lewiski pp 10892–10894 DOI: 10.1021/ic9016307 Supporting Info

A New 2D Hybrid Indate-Germanate Based on the Linkages of Ge4O10F2 Clusters and {In2O6} Dimers Jian Zhou, Zhi-Wu Yu, Wei-hui Fang, Feng Deng and Guo-Yu Yang pp 10895–10897 DOI: 10.1021/ic901894m Supporting Info

Three-Dimensional Frameworks of Cubic (NH4)5Ga4SbS10, (NH4)4Ga4SbS9(OH)·H2O, and (NH4)3Ga4SbS9(OH2)·2H2O Joshua L. Mertz, Nan Ding and Mercouri G. Kanatzidis pp 10898–10900 DOI: 10.1021/ic901927r Supporting Info

Catalytic Aerobic Oxidation by a Trianionic Pincer CrIII/CrV Couple Matthew O’Reilly, Joseph M. Falkowski, Vasanth Ramachandran, Mekhala Pati, Khalil A. Abboud, Naresh S. Dalal, Thomas G. Gray and Adam S. Veige pp 10901–10903 DOI: 10.1021/ic9019469 Supporting Info

Systematic Method for the Incorporation of the {(η6-Arene)Fe} Fragment into Carborane Cages via [(η6-Arene)Fe]2+ Dications. A Series of [3-(η6-Arene)-closo-3,1,2-FeC2B9H11] Complexes. Reliable Synthesis of Polymethylated [(η6-Arene)2Fe]2+ Cations B. tbr, M. Bakardjiev, Josef Holub, Ale Rika and Magdalena Kvalov pp 10904–10906 DOI: 10.1021/ic901982q Supporting Info

Crown and Bowl-Shaped Clusters of Uranyl Polyhedra Ginger E. Sigmon, Brittany Weaver, Karrie-Ann Kubatko and Peter C. Burns pp 10907–10909 DOI: 10.1021/ic9020355 Supporting Info

{[Ga(en)3]2(Ge2Te15)}n: A Polymeric Semiconducting Polytelluride with Boat-Shaped Te84− Rings and Cross-Shaped Te56− Units Qichun Zhang, Christos D. Malliakas and Mercouri G. Kanatzidis pp 10910–10912 DOI: 10.1021/ic9019074 Supporting Info

Square Planar Bis{3,6-bis(trimethylsilyl)benzene-1,2-dithiolato}metal Complexes of CrII, CoIII, and RhII: An Experimental and Density Functional Theoretical Study Flvio Luiz Benedito, Taras Petrenko, Eckhard Bill, Thomas Weyhermller and Karl Wieghardt pp 10913–10925 DOI: 10.1021/ic9008976 Supporting Info

Characterization and Electronic Structures of Five Members of the Electron Transfer Series [Re(benzene-1,2-dithiolato)3]z (z = 1+, 0, 1−, 2−, 3−): A Spectroscopic and Density Functional Theoretical Study Stephen Sproules, Flvio Luiz Benedito, Eckhard Bill, Thomas Weyhermller, Serena DeBeer George and Karl Wieghardt pp 10926–10941 DOI: 10.1021/ic9010532 Supporting Info

Reduction of Ferricytochrome c Catalyzed by Optically Active Chromium(III) Complexes Ulrich Scholten, Cline Diserens, Helen Stoeckli-Evans, Klaus Bernauer, Michel Meyer, Ludovic Stuppfler and Dominique Lucas pp 10942–10953 DOI: 10.1021/ic900330q Supporting Info

Oxalate Bridged MM (MM = Mo2, MoW, and W2) Quadruply Bonded Complexes As Test Beds for Current Mixed Valence Theory: Looking beyond the Intervalence Charge Transfer Transition Benjamin J. Lear and Malcolm H. Chisholm pp 10954–10971 DOI: 10.1021/ic900995u Supporting Info

Measuring Self-Diffusion Coefficients up to 1500 K: A Powerful Tool to Investigate the Dynamics and the Local Structure of Inorganic Melts Anne-Laure Rollet, Vincent Sarou-Kanian and Catherine Bessada pp 10972–10975 DOI: 10.1021/ic9010086 Supporting Info

Selective Chelation of Cd(II) and Pb(II) versus Ca(II) and Zn(II) by Using Octadentate Ligands Containing Pyridinecarboxylate and Pyridyl Pendants Raquel Ferreirs-Martnez, David Esteban-Gmez, Carlos Platas-Iglesias, Andrs de Blas and Teresa Rodrguez-Blas pp 10976–10987 DOI: 10.1021/ic900838j Supporting Info

Oxidizing Ru(II) Complexes as Irreversible and Specific Photo-Cross-Linking Agents of Oligonucleotide Duplexes Liana Ghizdavu, Frdric Pierard, Stphane Rickling, Sabrina Aury, Mathieu Surin, David Beljonne, Roberto Lazzaroni, Pierre Murat, Eric Defrancq, Ccile Moucheron and Andre Kirsch-De Mesmaeker pp 10988–10994 DOI: 10.1021/ic901007w Supporting Info

Does Iodate Incorporate into Layered Uranyl Phosphates Under Hydrothermal Conditions? Jie Ling, Shijun Wu, Fanrong Chen, Antonio Simonetti, John T. Shafer and Thomas E. Albrecht-Schmitt pp 10995–11001 DOI: 10.1021/ic9011247 Supporting Info

Bismuth Aryloxides Xiaodi Kou, Xiaoyu Wang, Daniel Mendoza-Espinosa, Lev N. Zakharov, Arnold L. Rheingold, William H. Watson, Kimberly A. Brien, L. Kasun Jayarathna and Tracy A. Hanna pp 11002–11016 DOI: 10.1021/ic901134t Supporting Info

Kinetic Control of Intralayer Cobalt Coordination in Layered Hydroxides: Co1−0.5xoctCoxtet(OH)2(Cl)x(H2O)n James R. Neilson, Birgit Schwenzer, Ram Seshadri and Daniel E. Morse pp 11017–11023 DOI: 10.1021/ic901167u Supporting Info

Do the Structural Changes Defined by the Electron Density Topology Necessarily Affect the Picture of the Bonding? Robert Ponec, Carlo Gatti pp 11024–11031 DOI: 10.1021/ic901197b Supporting Info

Synthesis and Optical Properties of Guanosine 5′-Monophosphate-Mediated CdS Nanostructures: An Analysis of their Structure, Morphology, and Electronic Properties Anil Kumar and Vinit Kumar pp 11032–11037 DOI: 10.1021/ic901205c Supporting Info

Reactivities of Fe(IV) Complexes with Oxo, Hydroxo, and Alkylperoxo Ligands: An Experimental and Computational Study Adam T. Fiedler and Lawrence Que, Jr. pp 11038–11047 DOI: 10.1021/ic901391y Supporting Info

Synthesis, Structures, and Luminescent and Magnetic Properties of Ln−Ag Heterometal−Organic Frameworks Xiao-Qing Zhao, Bin Zhao, Shi Wei and Peng Cheng pp 11048–11057 DOI: 10.1021/ic901291b Supporting Info

Synthesis of Oxorhenium(V) Complexes with Diamido Amine Ancillary Ligands and Their Role in Oxygen Atom Transfer Catalysis Yuee Feng, Joel Aponte, Paul J. Houseworth, Paul D. Boyle and Elon A. Ison pp 11058–11066 DOI: 10.1021/ic901434u Supporting Info

Self-Assembly of Metal-Organic Coordination Polymers Constructed from a Bent Dicarboxylate Ligand: Diversity of Coordination Modes, Structures, and Gas Adsorption Wenbin Yang, Xiang Lin, Alexander J. Blake, Claire Wilson, Peter Hubberstey, Neil R. Champness and Martin Schrder pp 11067–11078 DOI: 10.1021/ic901429u Supporting Info

Phosphonoacetate as a Ligand for Constructing Layered and Framework Alkali Metal Uranyl Compounds Andrea N. Alsobrook and Thomas E. Albrecht-Schmitt pp 11079–11084 DOI: 10.1021/ic9014493 Supporting Info

Reactions of Pd(II) with Chelate-Tethered 2,6-Diaminopurine Derivatives: N3-Coordination and Reaction of the Purine System Miguel A. Galindo, David Amantia, Alberto Martinez-Martinez, William Clegg, Ross W. Harrington, Virtudes Moreno Martinez and Andrew Houlton pp 11085–11091 DOI: 10.1021/ic901475y Supporting Info

Direct Synthesis, Crystal Structure, High-Field EPR, and Magnetic Studies on an Octanuclear Heterometallic Cu(II)/Cd Complex of Triethanolamine Elena A. Buvaylo, Vladimir N. Kokozay, Olga Yu. Vassilyeva, Brian W. Skelton, Igor L. Eremenko, Julia Jezierska and Andrew Ozarowski pp 11092–11097 DOI: 10.1021/ic901466h Supporting Info

DNA-Cleavage Induced by New Macrocyclic Schiff base Dinuclear Cu(I) Complexes Containing Pyridyl Pendant Arms Arnau Arbuse, Marc Font, Ma Angeles Martnez, Xavier Fontrodona, Ma Jos Prieto, Virtudes Moreno, Xavier Sala and Antoni Llobet pp 11098–11107 DOI: 10.1021/ic901488j Supporting Info

Synthesis, Structure, and Bonding in K12Au21Sn4. A Polar Intermetallic Compound with Dense Au20 and Open AuSn4 Layers Bin Li, Sung-Jin Kim, Gordon J. Miller and John D. Corbett pp 11108–11113 DOI: 10.1021/ic901493j Supporting Info

Multifaceted Coordination of Naphthyridine−Functionalized N-Heterocyclic Carbene: A Novel “IrIII(CN)(CC)” Compound and Its Evaluation as Transfer Hydrogenation Catalyst Arup Sinha, S. M. Wahidur Rahaman, Mithun Sarkar, Biswajit Saha, Prosenjit Daw and Jitendra K. Bera pp 11114–11122 DOI: 10.1021/ic901502n Supporting Info

Theoretical Study of Structure and Electronic Absorption Spectra of Some Schiff Bases and Their Zinc Complexes Kseniya G. Vladimirova, Alexandra Ya. Freidzon, Oxana V. Kotova, Andrei A. Vaschenko, Leonid S. Lepnev, Alexander A. Bagatur’yants, Alexei G. Vitukhnovskiy, Nickolai F. Stepanov and Michael V. Alfimov pp 11123–11130 DOI: 10.1021/ic9015004 Supporting Info

Palladium Motion in Cyclomeric Compounds: A Theoretical Study Antonio J. Mota and Alain Dedieu pp 11131–11141 DOI: 10.1021/ic901506v Supporting Info

Luminescence Properties of Lanthanide and Transition Metal Ion-Doped Ba2LaNbO6: Detection of MnO68− and CrO69− Clusters Peter A. Tanner and Zaifa Pan pp 11142–11146 DOI: 10.1021/ic9015178 Supporting Info

Synthesis of Copper(I) Complexes Containing Enantiopure Pybox Ligands. First Assays on Enantioselective Synthesis of Propargylamines Catalyzed by Isolated Copper(I) Complexes Mara Panera, Josefina Dez, Isabel Merino, Eduardo Rubio and M. Pilar Gamasa pp 11147–11160 DOI: 10.1021/ic901527x Supporting Info

Controlling Electron Transfer through the Manipulation of Structure and Ligand-Based Torsional Motions: A Computational Exploration of Ruthenium Donor−Acceptor Systems using Density Functional Theory Heather A. Meylemans and Niels H. Damrauer pp 11161–11175 DOI: 10.1021/ic901637b Supporting Info

Synthesis, Structure, and Photophysical Characterization of Blue-Green Luminescent Zinc Complexes Containing 2-Iminophenanthropyrrolyl Ligands Clara S. B. Gomes, Pedro T. Gomes, M. Teresa Duarte, Roberto E. Di Paolo, Antnio L. Maanita and Maria Jos Calhorda pp 11176–11186 DOI: 10.1021/ic901519s Supporting Info

2-Thienylcarboxylato and 2-Thienylthiocarboxylato Ligands Bonded to MM Quadruple Bonds (M = Mo or W): A Comparison of Ground State, Spectroscopic and Photoexcited State Properties Brian G. Alberding, Malcolm H. Chisholm, Yi-Hsuan Chou, Yagnaseni Ghosh, Terry L. Gustafson, Yao Liu and Claudia Turro pp 11187–11195 DOI: 10.1021/ic901607u Supporting Info

Structures, Metal Ion Affinities, and Fluorescence Properties of Soluble Derivatives of Tris((6-phenyl-2-pyridyl)methyl)amine Jian Liang, Jing Zhang, Lei Zhu, Alexander Duarandin, Victor G. Young, , Jr., Nicholas Geacintov and James W. Canary pp 11196–11208 DOI: 10.1021/ic901662z Supporting Info

Fe5O5[B6O10(OH)3]·nH2O: Wave-Layered Iron Borate and Frustrated Antiferromagnetism Tao Yang, Junliang Sun, Guobao Li, Yingxia Wang, Jeppe Christensen, Zhanbing He, Kirsten E. Christensen, Xiaodong Zou, Fuhui Liao and Jianhua Lin pp 11209–11214 DOI: 10.1021/ic9016867 Supporting Info

Hydrogen-Bond Directed Cyanide-Bridged Molecular Magnets Derived from Polycyanidemetalates and Schiff Base Manganese(III) Compounds: Synthesis, Structures, and Magnetic Properties Daopeng Zhang, Hailong Wang, Yuting Chen, Zhong-Hai Ni, Laijin Tian and Jianzhuang Jiang pp 11215–11225 DOI: 10.1021/ic901530p Supporting Info

From Monomers to Geometry-Constrained Molecules: One Step Further Toward Cyanide Bridged Wires Pablo Albors, Leonardo D. Slep, Livia S. Eberlin, Yuri E. Corilo, Marcos N. Eberlin, Guillermo Bentez, Maria E. Vela, Roberto C. Salvarezza and Luis M. Baraldo pp 11226–11235 DOI: 10.1021/ic901710x Supporting Info

Six-Coordinate Nitro Complexes of Iron(III) Porphyrins with trans S-Donor Ligands. Oxo-Transfer Reactivity in the Solid State Tigran S. Kurtikyan, Astghik A. Hovhannisyan, Alexei V. Iretskii and Peter C. Ford pp 11236–11241 DOI: 10.1021/ic901722g Supporting Info

Circularly Polarized Luminescence of Eu(III) Complexes with Point- and Axis-Chiral Ligands Dependent on Coordination Structures Takashi Harada, Yoko Nakano, Michiya Fujiki, Masanobu Naito, Tsuyoshi Kawai and Yasuchika Hasegawa pp 11242–11250 DOI: 10.1021/ic901663w Supporting Info

Syntheses, Characterization, and Computational Study of WSF4 and WSF4·CH3CN Jared Nieboer, William Hillary, Xin Yu, Hlne P. A. Mercier and Michael Gerken pp 11251–11258 DOI: 10.1021/ic901752w Supporting Info

Peculiar Binding Modes of a Ligand with Two Adjacent β-Diiminato Binding Sites in Alkali and Alkaline-Earth Metal Chemistry Dirk F.-J. Piesik, Peter Haack, Sjoerd Harder and Christian Limberg pp 11259–11264 DOI: 10.1021/ic9017536 Supporting Info

Ligand-Based Modification of the Structures and Optical Properties of New Silver(I)-Rhenate(VII) Oxide/Organic Hybrid Solids Haisheng Lin, Xiaomeng Wu and Paul A. Maggard pp 11265–11276 DOI: 10.1021/ic901749r Supporting Info

Noncentrosymmetry in New Templated Gallium Fluorophosphates Sarah J. Choyke, Samuel M. Blau, Abigail A. Larner, Amy Narducci Sarjeant, Jeongho Yeon, P. Shiv Halasyamani and Alexander J. Norquist pp 11277–11282 DOI: 10.1021/ic901770e Supporting Info

Synthesis and Mssbauer Characterization of Octahedral Iron(II) Carbonyl Complexes FeI2(CO)3L and FeI2(CO)2L2: Developing Models of the [Fe]-H2ase Active Site Bin Li, Tianbiao Liu, Codrina V. Popescu, Andrey Bilko and Marcetta Y. Darensbourg pp 11283–11289 DOI: 10.1021/ic9017882 Supporting Info

An Efficient Method for the Preparation of Oxo Molybdenum Salalen Complexes and Their Unusual Use as Hydrosilylation Catalysts Jeanette E. Ziegler, Guodong Du, Philip E. Fanwick and Mahdi M. Abu-Omar pp 11290–11296 DOI: 10.1021/ic901794h Supporting Info

Copper(I)/O2 Chemistry with Imidazole Containing Tripodal Tetradentate Ligands Leading to μ-1,2-Peroxo−Dicopper(II) Species Yunho Lee, Ga Young Park, Heather R. Lucas, Peter L. Vajda, Kaliappan Kamaraj, Michael A. Vance, Ashley E. Milligan, Julia S. Woertink, Maxime A. Siegler, Amy A. Narducci Sarjeant, Lev N. Zakharov, Arnold L. Rheingold, Edward I. Solomon and Kenneth D. Karlin pp 11297–11309 DOI: 10.1021/ic9017695 Supporting Info

Water Exchange Mechanism in the First Excited State of Hydrated Uranyl(VI) Pernilla Whlin, Valrie Vallet, Ulf Wahlgren and Ingmar Grenthe pp 11310–11313 DOI: 10.1021/ic9017689 Supporting Info

Molecular Conductors Based on the Mixed-Valence Polyoxometalates [SMo12O40]n− (n = 3 and 4) and the Organic Donors Bis(ethylenedithio)tetrathiafulvalene and Bis(ethylenedithio)tetraselenafulvalene Eugenio Coronado, Simona Curreli, Carlos Gimnez-Saiz, Carlos J. Gmez-Garca, Antonio Alberola and Enric Canadell pp 11314–11324 DOI: 10.1021/ic9018103 Supporting Info

CuII-Azide Polymers of Cu3 and Cu6 Building Units: Synthesis, Structures, and Magnetic Exchange Mechanism Sandip Mukherjee, Bappaditya Gole, Rajesh Chakrabarty and Partha Sarathi Mukherjee pp 11325–11334 DOI: 10.1021/ic901844j Supporting Info

Copper(I), Silver(I), and Palladium(II) Complexes of a Thiaoxamacrocycle Displaying Unusual Topologies So Young Lee, Sunhong Park and Shim Sung Lee pp 11335–11341 DOI: 10.1021/ic901902t Supporting Info

Study of the Influence of the Bridge on the Magnetic Coupling in Cobalt(II) Complexes Oscar Fabelo, Laura Caadillas-Delgado, Jorge Pasn, Fernando S. Delgado, Francesc Lloret, Joan Cano, Miguel Julve and Catalina Ruiz-Prez pp 11342–11351 DOI: 10.1021/ic901843r

Thioester Hydrolysis Reactivity of an Fe(III)Zn(II) Complex James J. Danford, Piotr Dobrowolski and Lisa M. Berreau pp 11352–11361 DOI: 10.1021/ic901890d Supporting Info

Luminescent Copper(I) Halide Butterfly Dimers Coordinated to [Au(CH3imCH2py)2]BF4 and [Au(CH3imCH2quin)2]BF4 Vincent J. Catalano, Adam L. Moore, Jason Shearer and Jineun Kim pp 11362–11375 DOI: 10.1021/ic901914n Supporting Info

Synthetic and Structural Studies on l-Cysteinyl Group-Containing Diiron/Triiron Azadithiolates as Active Site Models of [FeFe]-Hydrogenases Li-Cheng Song, Jing Yan, Yu-Long Li, De-Fu Wang and Qing-Mei Hu pp 11376–11381 DOI: 10.1021/ic9006179 Supporting Info

Visible-Light Excitable Europium(III) Complexes with 2,7-Positional Substituted Carbazole Group-Containing Ligands P. He, H. H. Wang, S. G. Liu, J. X. Shi, G. Wang and M. L. Gong pp 11382–11387 DOI: 10.1021/ic901210c

Syntheses, Structures, and Magnetic Properties of Tetramanganese(III) and Hexamanganese(III) Complexes Containing Derivative of Biguanidate Ligand: Ferromagnetic Interaction via Imino Nitrogen Asako Igashira-Kamiyama, Takashi Kajiwara, Motohiro Nakano, Takumi Konno and Tasuku Ito pp 11388–11393 DOI: 10.1021/ic901219f Supporting Info

Organoplatinum Complex Promoted the Asymmetric Endo Stereochemically Controlled Diels−Alder Reaction between 3-Diphenylphosphinofuran and Diphenylvinylphosphine Fengli Liu, Sumod A. Pullarkat, Kien-Wee Tan, Yongxin Li and Pak-Hing Leung pp 11394–11398 DOI: 10.1021/ic9014543 Supporting Info

Photogeneration of Nitrosyl Linkage Isomers in Octahedrally Coordinated Platinum Complexes in the Red Spectral Range Dominik Schaniel, Theo Woike, Norwid-R. Behrnd, Jrg Hauser, Karl W. Krmer, Teodora Todorova and Bernard Delley pp 11399–11406 DOI: 10.1021/ic901392q Supporting Info

Probing the Excited State Properties of the Highly Phosphorescent Pt(dpyb)Cl Compound by High-Resolution Optical Spectroscopy Andreas F. Rausch, Lisa Murphy, J. A. Gareth Williams and Hartmut Yersin pp 11407–11414 DOI: 10.1021/ic901523u

Structure and Reactivity of New Iridium Complexes with Bis(Oxazoline)-Phosphonito Ligands Riccardo Peloso, Roberto Pattacini, Catherine S. J. Cazin and Pierre Braunstein pp 11415–11424 DOI: 10.1021/ic901579u Supporting Info

Investigation of the Effect of Oxy Bridging Groups in Dinuclear Zn(II) Complexes that Catalyze the Cleavage of a Simple Phosphate Diester RNA Analogue Mark F. Mohamed, Alexei A. Neverov and R. Stan Brown pp 11425–11433 DOI: 10.1021/ic9015965 Supporting Info

Density Functional Theory Study of the Mechanisms of Oxidation of Ethylene by Chromyl Chloride Richard Tia and Evans Adei pp 11434–11443 DOI: 10.1021/ic901648y Supporting Info

Varied Reactions of [M(L)]3 with HgCl2, FeBr2, CeCl3, AgOTf; Ligand Transfer, Nucleophilic Attack with Recombination and/or Fragmentation [M = Li or Na; L = N(SiMe3){C(H)N}3SiMe3] W. Marco Boesveld, Peter B. Hitchcock and Michael F. Lappert pp 11444–11450 DOI: 10.1021/ic901687a Supporting Info

Vibrioferrin, an Unusual Marine Siderophore: Iron Binding, Photochemistry, and Biological Implications Shady A. Amin, David H. Green, Frithjof C. Kpper and Carl J. Carrano pp 11451–11458 DOI: 10.1021/ic9016883 Supporting Info

Heavy Alkali Metal Amides: Role of Secondary Interactions in Metal Stabilization Ana Torvisco, Katharina Decker, Frank Uhlig and Karin Ruhlandt-Senge pp 11459–11465 DOI: 10.1021/ic901767c

Ferric Stability Constants of Representative Marine Siderophores: Marinobactins, Aquachelins, and Petrobactin Guangping Zhang, Shady A. Amin, Frithjof C. Kpper, Pamela D. Holt, Carl J. Carrano and Alison Butler pp 11466–11473 DOI: 10.1021/ic901739m Supporting Info

Synthesis, Structure, and Stability of Adducts between Phosphide and Amide Anions and the Lewis Acids Borane, Tris(pentafluorophenyl)borane, and Tris(pentafluorophenyl)alane Anna-Marie Fuller, Andrew J. Mountford, Matthew L. Scott, Simon J. Coles, Peter N. Horton, David L. Hughes, Michael B. Hursthouse and Simon J. Lancaster pp 11474–11482 DOI: 10.1021/ic901799q Supporting Info

Issue 24

Visible Chromophore Phosphines as Functional Elements of Luminescent Metallopolymers Eleanor G. Tennyson and Rhett C. Smith pp 11483–11485 DOI: 10.1021/ic901155v Supporting Info

“Amorphous Nickel Sulfide” Is Hydrated Nanocrystalline NiS with a Core−Shell Structure Shanshan Huang, Kenneth D. M. Harris, Elisa Lopez-Capel, David A. C. Manning and David Rickard pp 11486–11488 DOI: 10.1021/ic901512z Supporting Info

Designing the Ideal Uranyl Ligand: a Sterically Induced Speciation Change in Complexes with Thiophene-Bridged Bis(3-hydroxy-N-methylpyridin-2-one) Gza Szigethy and Kenneth N. Raymond pp 11489–11491 DOI: 10.1021/ic901815b Supporting Info

Concerning the Possibility of Hidden One-Dimensional Fermi Surfaces for the K0.25WO3 Hexagonal Bronze Roberta Poloni, Enric Canadell and Jean-Paul Pouget pp 11492–11494 DOI: 10.1021/ic901725f

Observation of Slow Magnetic Relaxation in Discrete Dysprosium Cubane Yajie Gao, Gong-Feng Xu, Lang Zhao, Jinkui Tang and Zhiliang Liu pp 11495–11497 DOI: 10.1021/ic901806g Supporting Info

Direct Solid-State Synthesis at High Pressures of New Mixed-Metal Oxynitrides: RZrO2N (R = Pr, Nd, and Sm) Minghui Yang, Jennifer A. Rodgers, Lawrence C. Middler, Judith Or-Sol, A. Beln Jorge, Amparo Fuertes and J. Paul Attfield pp 11498–11500 DOI: 10.1021/ic902020r Supporting Info

Molecular and Electronic Structure of a Nonheme Iron(II) Model Complex Containing an Iron−Carbon Bond Partha Halder, Abhishek Dey and Tapan Kanti Paine pp 11501–11503 DOI: 10.1021/ic901841w Supporting Info

The Side-On Copper(I) Nitrosyl Geometry in Copper Nitrite Reductase Is Due to Steric Interactions with Isoleucine-257 Anna C. Merkle and Nicolai Lehnert pp 11504–11506 DOI: 10.1021/ic9018376 Supporting Info

A Twofold Interpenetrating Porous Metal−Organic Framework with High Hydrothermal Stability: Structure and Gas Sorption Behavior Xinfang Liu, Mira Park, Seunghee Hong, Minhak Oh, Ji Woong Yoon, Jong-San Chang and Myoung Soo Lah pp 11507–11509 DOI: 10.1021/ic901924z Supporting Info

Photochemical Stereospecific Hydrogenation of a Ru Complex with an NAD+/NADH-Type Ligand Takashi Fukushima, Etsuko Fujita, James T. Muckerman, Dmitry E. Polyansky, Tohru Wada and Koji Tanaka pp 11510–11512 DOI: 10.1021/ic901935u Supporting Info

Quaternary Neptunium Compounds: Syntheses and Characterization of KCuNpS3, RbCuNpS3, CsCuNpS3, KAgNpS3, and CsAgNpS3 Daniel M. Wells, Geng Bang Jin, S. Skanthakumar, Richard G. Haire, L. Soderholm and James A. Ibers pp 11513–11517 DOI: 10.1021/ic901229d Supporting Info

Syntheses, Crystal and Electronic Structures, and Physical Properties of Two Quaternary Chalcogenides: La4FeSb2Q10 (Q = S, Se) Hua-Jun Zhao, Long-Hua Li, Li-Ming Wu and Ling Chen pp 11518–11524 DOI: 10.1021/ic900784t Supporting Info

Luminescence Properties and Energy Transfer of Site-Sensitive Ca6−x−yMgx−z(PO4)4:Euy2+,Mnz2+ Phosphors and Their Application to Near-UV LED-Based White LEDs Ki Hyuk Kwon, Won Bin Im, Ho Seong Jang, Hyoung Sun Yoo and Duk Young Jeon pp 11525–11532 DOI: 10.1021/ic900809b Supporting Info

Photophysics in Platinum(II) Bipyridylacetylides Maria L. Muro, Stphane Diring, Xianghuai Wang, Raymond Ziessel and Felix N. Castellano pp 11533–11542 DOI: 10.1021/ic901036a Supporting Info

Cerium(IV)−Lanthanide(III)−Pyridine-2,6-dicarboxylic Acid System: Coordination Salts, Chains, and Rings T. K. Prasad and M. V. Rajasekharan pp 11543–11550 DOI: 10.1021/ic901066v Supporting Info

Preparation, Facile Deprotonation, and Rapid H/D Exchange of the μ-Hydride Diiron Model Complexes of the [FeFe]-Hydrogenase Containing a Pendant Amine in a Chelating Diphosphine Ligand Ning Wang, Mei Wang, Jihong Liu, Kun Jin, Lin Chen and Licheng Sun pp 11551–11558 DOI: 10.1021/ic901154m Supporting Info

Hydrothermal Synthesis and Luminescent Properties of Novel Ordered Sphere CePO4 Hierarchical Architectures Mei Yang, Hongpeng You, Yuhua Zheng, Kai Liu, Guang Jia, Yanhua Song, Yeju Huang, Lihui Zhang and Hongjie Zhang pp 11559–11565 DOI: 10.1021/ic901829v Supporting Info

A Selective Redox and Chromogenic Probe for Hg(II) in Aqueous Environment Based on a Ferrocene−Azaquinoxaline Dyad Fabiola Zapata, Antonio Caballero, Arturo Espinosa, Alberto Trraga and Pedro Molina pp 11566–11575 DOI: 10.1021/ic901234d Supporting Info

Aryl-Containing Chelates and Amine Debenzylation to Afford 1,3-Di-2-pyridyl-2-azaallyl (smif): Structures of {κ-C,N,Npy2-(2-pyridylmethyl)2N(CH2(4-tBu-phenyl-2-yl))}FeBr and (smif)CrN(TMS)2 Brenda A. Frazier, Peter T. Wolczanski and Emil B. Lobkovsky pp 11576–11585 DOI: 10.1021/ic901329z Supporting Info

Anti-Mackay Polyicosahedral Clusters in La−Ni−Mg Ternary Compounds: Synthesis and Crystal Structure of the La43Ni17Mg5 New Intermetallic Phase Pavlo Solokha, Serena De Negri, Volodymyr Pavlyuk and Adriana Saccone pp 11586–11593 DOI: 10.1021/ic901422v Supporting Info

Synthesis, Characterization, and Magnetism of Divalent Aryl Transition-Metal Complexes of the Simplest Dialkylamide, NMe2: Rare T-Shaped Coordination at Chromium Chengbao Ni, Gary J. Long, Fernande Grandjean and Philip P. Power pp 11594–11600 DOI: 10.1021/ic901462t Supporting Info

New 3D Coordination Polymers Constructed from Pillared Metal−Formate Kagom Layers Exhibiting Spin Canting Only in the Nickel(II) Complex Zuo-Xi Li, Jiong-Peng Zhao, E. C. Saudo, Hong Ma, Zhong-Da Pan, Yong-Fei Zeng and Xian-He Bu pp 11601–11607 DOI: 10.1021/ic901564y Supporting Info

Oxorhenium(V) Complexes with Ketiminato Ligands: Coordination Chemistry and Epoxidation of Cyclooctene Albert Schrckeneder, Pedro Traar, Georg Raber, Judith Baumgartner, Ferdinand Belaj and Nadia C. Msch-Zanetti pp 11608–11614 DOI: 10.1021/ic901455g Supporting Info

Oxidative Addition to U(V)−U(V) Dimers: Facile Routes to Uranium(VI) Bis(imido) Complexes Liam P. Spencer, Ping Yang, Brian L. Scott, Enrique R. Batista and James M. Boncella pp 11615–11623 DOI: 10.1021/ic901581r Supporting Info

Facile Room Temperature Ion-Exchange Synthesis of Sn2+ Incorporated Pyrochlore-Type Oxides and Their Photocatalytic Activities S. Uma, Jyoti Singh and Vaishali Thakral pp 11624–11630 DOI: 10.1021/ic901658w Supporting Info

First-Principle Calculation-Assisted Structural Study on the Nanoscale Phase Transition of Si for Li-Ion Secondary Batteries Yong-Mook Kang, Seung-Bum Suh and Yang-Soo Kim pp 11631–11635 DOI: 10.1021/ic901674s Supporting Info

Wheel-Shaped Cu20-Tungstophosphate [Cu20X(OH)24(H2O)12(P8W48O184)]25− Ion (X = Cl, Br, I) and the Role of the Halide Guest Sib Sankar Mal, Bassem S. Bassil, Masooma Ibrahim, Saritha Nellutla, Johan van Tol, Naresh S. Dalal, Jorge A. Fernndez, Xavier Lpez, Josep M. Poblet, Rosa Ngo Biboum, Bineta Keita and Ulrich Kortz pp 11636–11645 DOI: 10.1021/ic901641f Supporting Info

Structure of Bayerite-Based Lithium−Aluminum Layered Double Hydroxides (LDHs): Observation of Monoclinic Symmetry Sylvia Britto and P. Vishnu Kamath pp 11646–11654 DOI: 10.1021/ic9016728 Supporting Info

Formation of Hydrides in (Ti1−xZrx)Co2.00 (0 < x < 1) Pseudobinary Alloys H. T. Kuo, R. S. Liu, S. M. Filipek, R. Wierzbicki, R. Sato, C. L. Chan, H. D. Yang and J.-F. Lee pp 11655–11659 DOI: 10.1021/ic901760j

Amino Acid Based MOFs: Synthesis, Structure, Single Crystal to Single Crystal Transformation, Magnetic and Related Studies in a Family of Cobalt and Nickel Aminoisophthales Debajit Sarma, K. V. Ramanujachary, S. E. Lofland, Travis Magdaleno and Srinivasan Natarajan pp 11660–11676 DOI: 10.1021/ic901678c Supporting Info

Terphenyl Derivatives as “Turn On” Fluorescent Sensors for Mercury Vandana Bhalla, Ruchi Tejpal, Manoj Kumar and Amandeep Sethi pp 11677–11684 DOI: 10.1021/ic9016933 Supporting Info

Selective Complexation and Reactivity of Metallic Nitride and Oxometallic Fullerenes with Lewis Acids and Use as an Effective Purification Method Steven Stevenson, Mary A. Mackey, Jane E. Pickens, Melissa A. Stuart, Bridget S. Confait and J. Paige Phillips pp 11685–11690 DOI: 10.1021/ic9017147 Supporting Info

La1−xCexCrO3 (0.0 ≤ x ≤ 1.0): A New Series of Solid Solutions with Tunable Magnetic and Optical Properties Rakesh Shukla, Jayappa Manjanna, Anup K. Bera, Seikh M. Yusuf and Avesh K. Tyagi pp 11691–11696 DOI: 10.1021/ic901735d Supporting Info

Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium Padmini Ramaswamy, Nayana N. Hegde, Ramanath Prabhu, V. M. Vidya, Ayan Datta and Srinivasan Natarajan pp 11697–11711 DOI: 10.1021/ic901744m Supporting Info

Hydration and Hydrolysis of Thorium(IV) in Aqueous Solution and the Structures of Two Crystalline Thorium(IV) Hydrates Natallia Torapava, Ingmar Persson, Lars Eriksson and Daniel Lundberg pp 11712–11723 DOI: 10.1021/ic901763s Supporting Info

Complexation of Mercury(I) and Mercury(II) by 18-Crown-6: Hydrothermal Synthesis of the Mercuric Nitrite Complex Neil J. Williams, Robert D. Hancock, Joseph H. Riebenspies, Manuel Fernandes and Alvaro S. de Sousa pp 11724–11733 DOI: 10.1021/ic9017618 Supporting Info

Redox Processes in the Iron(III)/9,10-Phenanthraquinone System Petr Milko and Jana Roithov pp 11734–11742 DOI: 10.1021/ic901789h Supporting Info

Thiacalix[4]arene-Supported Planar Ln4 (Ln = TbIII, DyIII) Clusters: Toward Luminescent and Magnetic Bifunctional Materials Yanfeng Bi, Xiu-Teng Wang, Wuping Liao, Xinwu Wang, Ruiping Deng, Hongjie Zhang and Song Gao pp 11743–11747 DOI: 10.1021/ic9017807 Supporting Info

Two-Dimensional Networks of Lanthanide Cubane-Shaped Dumbbells Didier Savard, Po-Heng Lin, Tara J. Burchell, Ilia Korobkov, Wolfgang Wernsdorfer, Rodolphe Clrac and Muralee Murugesu pp 11748–11754 DOI: 10.1021/ic901807k Supporting Info

Influence of Bonding Mode of the Linkers in the Electronic Communication of Molecular Pairs Having Dimolybdenum Units Linked by Pseudohalides F. Albert Cotton, Carlos A. Murillo and Qinliang Zhao pp 11755–11766 DOI: 10.1021/ic901826y Supporting Info

Solid State and Solution Dynamics of Pyridine Based Tetraaza-Macrocyclic Lanthanide Chelates Possessing Phosphonate Ligating Functionality (Ln-PCTMB): Effect on Relaxometry and Optical Properties Garry E. Kiefer and Mark Woods pp 11767–11778 DOI: 10.1021/ic901779k Supporting Info

Neptunium Carbonato Complexes in Aqueous Solution: An Electrochemical, Spectroscopic, and Quantum Chemical Study Atsushi Ikeda-Ohno, Satoru Tsushima, Koichiro Takao, Andr Rossberg, Harald Funke, Andreas C. Scheinost, Gert Bernhard, Tsuyoshi Yaita and Christoph Hennig pp 11779–11787 DOI: 10.1021/ic901838r Supporting Info

Structural and Spectroscopic Studies of the PCP-Bridged Heavy Chalcogen-Centered Monoanions [HC(PPh2E)(PPh2)]− (E = Se, Te) and [HC(PR2E)2]− (E = Se, Te, R = Ph; E = Se, R = iPr): Homoleptic Group 12 Complexes and One-Electron Oxidation of [HC(PR2Se)2]− Jari Konu, Heikki M. Tuononen and Tristram Chivers pp 11788–11798 DOI: 10.1021/ic901878h Supporting Info

Coordination of N-Donor Ligands to a Uranyl(V) β-Diketiminate Complex Michael F. Schettini, Guang Wu and Trevor W. Hayton pp 11799–11808 DOI: 10.1021/ic9018508 Supporting Info

Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites Su-Yun Zhang, Hai-Long Jiang, Chuan-Fu Sun and Jiang-Gao Mao pp 11809–11820 DOI: 10.1021/ic901855x Supporting Info

Eight-Coordinate Zn(II), Cd(II), and Pb(II) Complexes Based on a 1,7-Diaza-12-crown-4 Platform Endowed with a Remarkable Selectivity over Ca(II) Raquel Ferreirs-Martnez, David Esteban-Gmez, Andrs de Blas, Carlos Platas-Iglesias and Teresa Rodrguez-Blas pp 11821–11831 DOI: 10.1021/ic901883h Supporting Info

Highly Fluorous Complexes of Ruthenium and Osmium and Their Solubility in Supercritical Carbon Dioxide Bradley M. Berven, George A. Koutsantonis, Brian W. Skelton, Robert D. Trengove and Allan H. White pp 11832–11842 DOI: 10.1021/ic901880f

Reliable Method for Determining the Oxidation State in Chromium Oxides ngel M. Arvalo-Lpez and Miguel . Alario-Franco pp 11843–11846 DOI: 10.1021/ic901887y Supporting Info

Evidence of Disruption of Conjugation Involving Delta Bonds in Intramolecular Electronic Coupling F. Albert Cotton, Zhong Li and Carlos A. Murillo pp 11847–11852 DOI: 10.1021/ic9018647 Supporting Info

The Semiquinone−Ruthenium Combination as a Remarkably Invariant Feature in the Redox and Substitution Series [Ru(Q)n(acac)3−n]m, n = 1−3; m = (−2), −1, 0, +1, (+2); Q = 4,6-Di-tert-butyl-N-phenyl-o-iminobenzoquinone Dipanwita Das, Atanu Kumar Das, Biprajit Sarkar, Tapan Kumar Mondal, Shaikh M. Mobin, Jan Fiedler, Stanislav Zli, Francisco A. Urbanos, Reyes Jimnez-Aparicio, Wolfgang Kaim and Goutam Kumar Lahiri pp 11853–11864 DOI: 10.1021/ic901900g Supporting Info

Photochemical Activation of an Azido Manganese-Monosubstituted Keggin Polyoxometalate: On the Road to a Mn(V)−Nitrido Derivative G. Izzet, E. Ishow, J. Delaire, C. Afonso, J.-C. Tabet and A. Proust pp 11865–11870 DOI: 10.1021/ic902046t Supporting Info

Cubes, Squares, and Books: A Simple Transition Metal/Bridging Ligand Combination Can Lead to a Surprising Range of Structural Types with the Same Metal/Ligand Proportions Adel M. Najar, Ian S. Tidmarsh, Harry Adams and Michael D. Ward pp 11871–11881 DOI: 10.1021/ic901892y Supporting Info

The First Organic-Templated Vanadyl(IV) Gallophosphates with Ambient 51V Hyperfine Structure, {V2Ga2O14} Cluster or Heterometal 12-Ring Channels Li-Hsun Huang, Yi-Chun Lai, Hui-Chun Lai, Yun-Wei Chiang, Jin-Hua Huang and Sue-Lein Wang pp 11882–11888 DOI: 10.1021/ic901943e Supporting Info

Oxidation Chemistry of Axially Protected Mo2 and W2 Quadruply Bonded Compounds Michael Nippe, Eric Victor and John F. Berry pp 11889–11895 DOI: 10.1021/ic901965b Supporting Info

New Strategy for Synthesis of Mercaptoundecahydrododecaborate Derivatives via Click Chemistry: Possible Boron Carriers and Visualization in Cells for Neutron Capture Therapy Mohamed E. El-Zaria and Hiroyuki Nakamura pp 11896–11902 DOI: 10.1021/ic902033c Supporting Info

Ligand-Controlled Magnetic Interactions in Mn4 Clusters Erik Kampert, Femke F. B. J. Janssen, Danil W. Boukhvalov, Jaap C. Russcher, Jan M. M. Smits, Ren de Gelder, Bas de Bruin, Peter C. M. Christianen, Uli Zeitler, Mikhail I. Katsnelson, Jan C. Maan and Alan E. Rowan pp 11903–11908 DOI: 10.1021/ic901930w Supporting Info

Activation of the C−H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy)2+/2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System Carine Michel, Paola Belanzoni, Patrick Gamez, Jan Reedijk and Evert Jan Baerends pp 11909–11920 DOI: 10.1021/ic902155m

Asymmetric Twisting and Chirality Probing Properties of Quadruple-Stranded Helicates: Coordination Versatility and Chirality Response of Na+, Ca2+, and La3+ Complexes with Octadentate Cyclen Ligand Hitomi Misaki, Hiroyuki Miyake, Satoshi Shinoda and Hiroshi Tsukube pp 11921–11928 DOI: 10.1021/ic901496s Supporting Info

Synthesis, Crystal Structure, and Vibrational Spectroscopy of K2Ca4Si8O21—An Unusual Single-Layer Silicate Containing Q2 and Q3 Units E. Arroyabe, R. Kaindl, D.M. Tbbens and V. Kahlenberg pp 11929–11934 DOI: 10.1021/ic901762u Supporting Info

Redox Reactions of Pu(IV) and Pu(III) in the Presence of Acetohydroxamic Acid in HNO3 Solutions Peter Tkac, Martin Precek and Alena Paulenova pp 11935–11944 DOI: 10.1021/ic901081j Supporting Info

Efficient Transfer of Either One or Two Dithiolene Ligands from Nickel to Ruthenium: Synthesis and Crystal Structures of [Ru(SCR═CPhS)2(PPh3)] and [RuCl2(SCR═CPhS)(PPh3)2] (R = Ph, H) Harry Adams, Anna M. Coffey, Michael J. Morris and Sarah A. Morris pp 11945–11953 DOI: 10.1021/ic9018458 Supporting Info

Tridentate Assembling Ligands Based on Oxazoline and Phosphorus Donors in Dinuclear Pd(I)−Pd(I) Complexes Jing Zhang, Roberto Pattacini and Pierre Braunstein pp 11954–11962 DOI: 10.1021/ic9018579 Supporting Info

Functionalization of Methyl (R)-Phenylglycinate Through Orthopalladation: C−Hal, C−O, C−N, and C−C Bond Coupling Sonia Nieto, Palmira Arnau, Elena Serrano, Rafael Navarro, Tatiana Soler, Carlos Cativiela and Esteban P. Urriolabeitia pp 11963–11975 DOI: 10.1021/ic901941s Supporting Info

Formation of a 3-D Porous Ferric Arsenate Containing Novel Cubane-like Fe4F4 Building Units Zhihui Yi, Chao Yang, Wujiong Xia, Xianzhu Xu and Xiao Zhang p 11976 DOI: 10.1021/ic902137b